{"meta":{"query_hash":"a613c1dfa034","filters":{"venue":"Heteroatom Chemistry"},"cohort_total":21,"direct_labels_cover":0,"predictions_cover":21,"exported":21,"export_cap":100000,"truncated":false,"label_status":"direct model label, unvalidated","prediction_status":"machine_predicted_unvalidated (Codex and Gemma teacher distillation)","score_status":"score_only:v0-immature-baseline","snapshot":{"source":"OpenAlex, pinned release, all 482 partitions","release":"2026-06-24","frame_built":"2026-07-12"},"permalink":"https://metacan.xera.ac/q/a613c1dfa034","api":"https://metacan.xera.ac/api/v1/cohort?venue=Heteroatom+Chemistry"},"results":[{"id":"W1528265144","doi":"10.1002/hc.21141","title":"Heterocyclic Aminoboron Compounds as Antituberculosis Agents","year":2014,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"","keywords":"Antimycobacterial; Chemistry; Pinacol; Mycobacterium tuberculosis; Boron; Stereochemistry; Organic chemistry; Combinatorial chemistry; Medicinal chemistry; Tuberculosis; Catalysis","score_opus":0.010078826956418936,"score_gpt":0.23845418549964414,"score_spread":0.22837535854322522,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W1528265144","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.91164744,0.00016030883,0.000014730664,0.0003172974,0.0001617455,0.000052819218,0.000034860765,0.0005920399,0.08701874],"genre_scores_gemma":[0.99453455,0.00008285947,0.00011428787,0.0011317779,0.00072999886,0.000034193305,0.00023657545,0.0001430393,0.00299269],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99672735,0.000025347941,0.00065808854,0.0010565794,0.0006340812,0.00089853443],"domain_scores_gemma":[0.99757695,0.00009718298,0.00024942344,0.001420678,0.00008254766,0.00057319785],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00011337928,0.0006798746,0.000601412,0.000035277906,0.0002625355,0.00019502938,0.0008715394,0.00060471427,0.009434065],"category_scores_gemma":[0.00012810733,0.00073888403,0.00034626812,0.00017316108,0.0002391894,0.00019633934,0.00030198862,0.0006163026,0.0007668058],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000030452095,0.00021922609,0.012150144,0.00062513794,0.000088360895,0.000023359808,0.00008041353,0.0000034401294,0.98091257,0.000010050068,0.004752691,0.0011041397],"study_design_scores_gemma":[0.001222744,0.000013876714,0.0006601061,0.000112816706,0.00006335708,0.00019555396,0.000079798316,0.00027220274,0.95045996,0.00006032827,0.046089493,0.0007697892],"about_ca_topic_score_codex":0.000049866245,"about_ca_topic_score_gemma":0.0000039568804,"teacher_disagreement_score":0.08402605,"about_ca_system_score_codex":0.00024136147,"about_ca_system_score_gemma":0.000034105582,"threshold_uncertainty_score":0.99950624},"labels":[],"label_agreement":null},{"id":"W1567089479","doi":"10.1002/hc.21193","title":"Structural Changes Upon Oxidation of (PtBu2)2 and 1,4‐(CH2)2(PtBu)4: Transannular P–P Interactions in Cations of the 1,4‐C2P4 Ring","year":2014,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Lethbridge; University of Calgary","funders":"","keywords":"Chemistry; Crystallography","score_opus":0.012217188149722119,"score_gpt":0.21664509362423043,"score_spread":0.20442790547450831,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W1567089479","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9887527,0.0019780025,0.0006726804,0.0012889579,0.0008010646,0.0023724942,0.0024255228,0.0010909518,0.00061760127],"genre_scores_gemma":[0.98831415,0.0030578359,0.00017199948,0.0004518619,0.0021585529,0.0013663177,0.0032075122,0.0012282124,0.0000435497],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9766609,0.0012780976,0.006689837,0.006175,0.004274595,0.0049215523],"domain_scores_gemma":[0.98239857,0.0021216583,0.004530081,0.006967447,0.0017410332,0.0022411954],"candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.002603964,0.0050993133,0.0055478048,0.0018391262,0.002303944,0.0011469097,0.0042243437,0.002982559,0.00038512758],"category_scores_gemma":[0.0016237055,0.005409777,0.0033463037,0.0044108992,0.0022202262,0.0026701626,0.0020350616,0.0048456863,0.00030825028],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00066010066,0.001467698,0.0019479101,0.003709302,0.0019049492,0.00009258475,0.0039035955,0.0031623866,0.93455863,0.000060860988,0.00061858405,0.04791338],"study_design_scores_gemma":[0.0052212626,0.00024274003,0.0034776214,0.0023390544,0.0025276053,0.00068811857,0.0030561853,0.012429249,0.96374,0.00051927066,0.00085673394,0.004902192],"about_ca_topic_score_codex":0.00017091563,"about_ca_topic_score_gemma":0.0012391614,"teacher_disagreement_score":0.04301119,"about_ca_system_score_codex":0.0022057835,"about_ca_system_score_gemma":0.001029747,"threshold_uncertainty_score":0.99988997},"labels":[],"label_agreement":null},{"id":"W1638511010","doi":"10.1002/hc.21072","title":"Synthesis and Biological Activities of Arylspiroborates Derived from 2,3‐Dihydroxynaphthalene","year":2013,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"","keywords":"Chemistry; Antimycobacterial; Tetramethylammonium; Heteroatom; Antifungal; Salt (chemistry); Elemental analysis; Calcium; Nuclear magnetic resonance spectroscopy; Combinatorial chemistry; Stereochemistry; Organic chemistry; Ring (chemistry)","score_opus":0.012857963104413627,"score_gpt":0.20820155195817533,"score_spread":0.1953435888537617,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W1638511010","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9965417,0.0007930174,0.000004121542,0.0001935522,0.000025114368,0.000049240487,0.0001563864,0.00015844904,0.002078417],"genre_scores_gemma":[0.99895126,0.00025361654,0.00030220076,0.00007152269,0.00014770351,0.00006909743,0.00005959266,0.000043672768,0.00010134786],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99843514,0.0000147669525,0.00041560477,0.00056743925,0.00019144204,0.00037563365],"domain_scores_gemma":[0.99861044,0.00035883955,0.0002127714,0.00053924083,0.000051761053,0.00022693882],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00003981209,0.00037529133,0.00051383255,0.000017475388,0.00007307802,0.000061736806,0.00032244387,0.00045691777,0.01302163],"category_scores_gemma":[0.00014117171,0.00034218293,0.00012265118,0.00007564422,0.00043017452,0.00015411452,0.00020773319,0.0002641609,0.000027971568],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00001893916,0.00010241305,0.03326068,0.0002639704,0.00008790215,0.000007779945,0.000078463396,3.937426e-7,0.9647657,6.980794e-7,0.00017075316,0.001242258],"study_design_scores_gemma":[0.00034535467,0.0000063475536,0.003759779,0.000101391546,0.000031261934,0.00002795112,0.0005137467,0.000051501203,0.99462664,0.00010243097,0.00006681291,0.00036677727],"about_ca_topic_score_codex":0.00011152527,"about_ca_topic_score_gemma":8.7103547e-7,"teacher_disagreement_score":0.029860897,"about_ca_system_score_codex":0.00004324032,"about_ca_system_score_gemma":0.000029825473,"threshold_uncertainty_score":0.999903},"labels":[],"label_agreement":null},{"id":"W1961085279","doi":"10.1002/hc.20032","title":"Synthesis, spectroscopic exploration, biocidal activities, and crystal structures of 3‐(3‐fluorophenyl)‐2‐phenylpropenoic acid and trimethyltin(IV) complex","year":2004,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Triclinic crystal system; Ligand (biochemistry); Crystallography; Monoclinic crystal system; Carboxylate; Trigonal bipyramidal molecular geometry; Crystal structure; Tin; Stereochemistry; Organic chemistry","score_opus":0.01716035594442913,"score_gpt":0.2239251661528161,"score_spread":0.20676481020838697,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W1961085279","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9975721,0.0005603787,0.00024043178,0.0001774167,0.000030136795,0.000085110536,0.000091377944,0.00008321245,0.0011597889],"genre_scores_gemma":[0.9982284,0.00019197898,0.0010756731,0.000030090781,0.0001799784,0.000027918402,0.00008730506,0.00004920575,0.0001295011],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9984544,0.000020702153,0.0004590533,0.0005026543,0.00026673256,0.00029647592],"domain_scores_gemma":[0.9990587,0.0000683776,0.00028795883,0.00039736857,0.00004437495,0.0001431679],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000079068544,0.0003444343,0.00048727164,0.00004297035,0.0001561046,0.0001246912,0.00019122077,0.00018704927,0.0013636969],"category_scores_gemma":[0.000067688685,0.00033764812,0.00007851861,0.0001054527,0.00027173318,0.00028791744,0.00014162925,0.00018175296,0.0000014819987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000056618654,0.0000864787,0.0009931633,0.00060044904,0.000072693394,0.0000036352092,0.00027001862,0.0000015167415,0.9962723,0.000037369653,0.000012903561,0.001592828],"study_design_scores_gemma":[0.00070658367,0.000019861898,0.0021301722,0.00009452319,0.00006437139,0.000041925185,0.00039195616,0.000018454637,0.99505997,0.0005199451,0.00062950567,0.00032276326],"about_ca_topic_score_codex":0.000029537303,"about_ca_topic_score_gemma":0.0000030510346,"teacher_disagreement_score":0.0013622149,"about_ca_system_score_codex":0.0000862529,"about_ca_system_score_gemma":0.00006705265,"threshold_uncertainty_score":0.99990755},"labels":[],"label_agreement":null},{"id":"W1981651520","doi":"10.1002/hc.20119","title":"The thermodynamic stability of P8, A CBS‐Q study","year":2005,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Heteroatom; Cubane; Phosphorus; Crystallography; Chemical stability; Physical chemistry; Crystal structure; Ring (chemistry); Organic chemistry","score_opus":0.012234223108594,"score_gpt":0.21528545106684366,"score_spread":0.20305122795824965,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W1981651520","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.99559104,0.0001255844,0.00002120788,0.0002449011,0.000043704164,0.00010652824,0.000035805137,0.00011145612,0.00371979],"genre_scores_gemma":[0.9994268,0.000047075322,0.000015300604,0.00003848792,0.00021291956,0.000044893688,0.000022576758,0.000049060436,0.00014292417],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9981015,0.000031009662,0.00065760105,0.00044567828,0.0004191982,0.00034506273],"domain_scores_gemma":[0.99812645,0.0002194248,0.00031868523,0.0011001026,0.00012531175,0.00011001508],"candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002712206,0.00029099738,0.0003380882,0.000014739812,0.00020630083,0.000079631645,0.0006272047,0.00013456053,0.001319108],"category_scores_gemma":[0.00010637633,0.00023062817,0.00018496031,0.00015311036,0.00016787232,0.00010117088,0.0001861677,0.00024964465,0.00002449253],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000039035665,0.00068038976,0.005741393,0.00007783729,0.00011367543,0.0000015235679,0.00031029107,0.0000011584154,0.9855441,0.000003354679,0.000029464216,0.0074577737],"study_design_scores_gemma":[0.00046308112,0.000012114616,0.0039548953,0.000022310443,0.00004201919,0.000011982383,0.0007613075,0.00038767795,0.9923015,0.000018596345,0.0017844955,0.00023999783],"about_ca_topic_score_codex":0.0000045796764,"about_ca_topic_score_gemma":0.000010795881,"teacher_disagreement_score":0.0072177756,"about_ca_system_score_codex":0.0001493855,"about_ca_system_score_gemma":0.0000622319,"threshold_uncertainty_score":0.9995938},"labels":[],"label_agreement":null},{"id":"W1998400766","doi":"10.1002/hc.20606","title":"Synthesis of functional phosphines with ortho‐substituted aryl groups: 2‐RC6H4PH2 and 2‐RC6H4P(SiMe3)2 (R = 2‐i‐Pr‐ or 2‐t‐Bu‐)","year":2010,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Heteroatom; Aryl; Medicinal chemistry; Stereochemistry; Characterization (materials science); Nanotechnology; Organic chemistry; Ring (chemistry)","score_opus":0.009105088669417854,"score_gpt":0.19012435109393525,"score_spread":0.18101926242451738,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W1998400766","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9856038,0.001439511,0.00062268873,0.00097112637,0.002408513,0.0021611429,0.003175163,0.0025149903,0.0011030745],"genre_scores_gemma":[0.98002964,0.0056924378,0.0002705113,0.0017180839,0.0046494436,0.0016101955,0.003873481,0.002075756,0.00008043546],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.972586,0.00050929666,0.007181283,0.008056428,0.0057438267,0.005923179],"domain_scores_gemma":[0.97770876,0.0030948545,0.005817662,0.006796913,0.0027467962,0.0038350234],"candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.0022246933,0.0070654196,0.00671653,0.0013228835,0.0027346981,0.0019863844,0.004294395,0.0050764177,0.00063619384],"category_scores_gemma":[0.0023150805,0.007291761,0.0029412447,0.004573357,0.0034828722,0.003436195,0.0024993299,0.0058981325,0.000772654],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.0031946509,0.0040328344,0.005753301,0.0036133241,0.0033612966,0.0007451222,0.00060034386,0.00012116779,0.9554103,0.000055943645,0.004059167,0.019052532],"study_design_scores_gemma":[0.0072523453,0.00035327103,0.007438412,0.0023973016,0.0027669843,0.0022595467,0.0007384472,0.0006199002,0.9657497,0.0002584236,0.002353784,0.007811893],"about_ca_topic_score_codex":0.000045830013,"about_ca_topic_score_gemma":0.00047185642,"teacher_disagreement_score":0.011240638,"about_ca_system_score_codex":0.0015653906,"about_ca_system_score_gemma":0.0025143935,"threshold_uncertainty_score":0.9992291},"labels":[],"label_agreement":null},{"id":"W2005638533","doi":"10.1002/hc.20402","title":"Synthesis, characterization, and biological effects of diorganotin(IV) derivatives of substituted germyl propionic acid and crystal structure of 3‐triphenylgermyl‐3‐P‐fluorophenyl propionic acid","year":2008,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Heteroatom; Cytotoxicity; Crystal structure; Mass spectrometry; Elemental analysis; Single crystal; Stereochemistry; Medicinal chemistry; Nuclear chemistry; Crystallography; Organic chemistry; In vitro; Ring (chemistry)","score_opus":0.008107795691597907,"score_gpt":0.18799545621394692,"score_spread":0.179887660522349,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2005638533","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9983371,0.00089173776,0.00019584618,0.00003837267,0.000040060007,0.00020639999,0.00020086832,0.000059098315,0.0000305418],"genre_scores_gemma":[0.9985325,0.00082493277,0.00024777572,0.0000090436115,0.00008664616,0.000024522857,0.00019349548,0.000043083255,0.000038037328],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99798644,0.000054339962,0.00080653746,0.0005489842,0.00030709166,0.0002966201],"domain_scores_gemma":[0.99828917,0.00015700443,0.00078405294,0.00045721687,0.00018468675,0.00012787283],"candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00005801889,0.00040964416,0.00084306527,0.00006149454,0.00012454431,0.000020659438,0.00025353933,0.00035654425,0.0004460481],"category_scores_gemma":[0.0003089731,0.00035066175,0.00011992242,0.00024199628,0.00071503693,0.00019124807,0.0001772296,0.00020445572,2.9973387e-7],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000101499434,0.0002017749,0.026775118,0.0031327496,0.00013313568,0.000006521658,0.0004153064,2.2553071e-7,0.9683948,0.000007653283,0.000001549175,0.0008296214],"study_design_scores_gemma":[0.00057177275,0.00003492246,0.057406917,0.00036779162,0.000075335614,0.000106414926,0.000040009145,0.000023644609,0.94097495,0.00002066271,0.000071826,0.00030573847],"about_ca_topic_score_codex":0.0000034635225,"about_ca_topic_score_gemma":3.2544153e-7,"teacher_disagreement_score":0.0306318,"about_ca_system_score_codex":0.000039153154,"about_ca_system_score_gemma":0.00009363377,"threshold_uncertainty_score":0.99989456},"labels":[],"label_agreement":null},{"id":"W2038123846","doi":"10.1002/hc.10057","title":"Synthesis, characterization, and biological studies of tri‐ and diorganotin(IV) complexes with 2′,4′‐difluoro‐4‐hydroxy‐[1,1′]‐biphenyle‐3‐carbolic acid: Crystal structure of [(CH3)3Sn(C13H7O3F2)]","year":2002,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Calgary","funders":"RIKEN; Alexander von Humboldt-Stiftung","keywords":"Chemistry; Orthorhombic crystal system; Heteroatom; Trigonal bipyramidal molecular geometry; Crystal structure; Tin; Crystallography; Stereochemistry; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Antifungal; Crystal (programming language); Organic chemistry; Ring (chemistry)","score_opus":0.014681000322174452,"score_gpt":0.20103939338925397,"score_spread":0.18635839306707952,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2038123846","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.99046403,0.003114267,0.00021652384,0.00042465283,0.00038893922,0.00132362,0.0031360528,0.0007998986,0.00013202222],"genre_scores_gemma":[0.9841413,0.010789345,0.00010689213,0.00027949637,0.0014306383,0.00035429688,0.002175647,0.0007070535,0.000015331547],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9855683,0.00058648264,0.0043268106,0.0042464784,0.002364742,0.0029072212],"domain_scores_gemma":[0.98944354,0.0011777338,0.0038310217,0.0029504225,0.0012055354,0.0013917299],"candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0007909601,0.0037149822,0.0050716787,0.000638945,0.0012374803,0.00069797214,0.0017502205,0.0024506585,0.00019162147],"category_scores_gemma":[0.0010082722,0.0035740011,0.0011007375,0.0017907612,0.0027427848,0.0012991121,0.0014748608,0.0020508156,0.00003864265],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.0007992394,0.0013619948,0.00810821,0.0038018506,0.0019650783,0.00012857585,0.0013482607,0.000018870338,0.96829593,0.000013772182,0.0002581655,0.013900078],"study_design_scores_gemma":[0.003769687,0.0003307193,0.01648991,0.0016623322,0.0013132694,0.0007037376,0.00082519464,0.00047921741,0.9704687,0.00014953816,0.00027284145,0.0035348816],"about_ca_topic_score_codex":0.000011202447,"about_ca_topic_score_gemma":0.00005360615,"teacher_disagreement_score":0.0103651965,"about_ca_system_score_codex":0.00070226117,"about_ca_system_score_gemma":0.00034110984,"threshold_uncertainty_score":0.99997115},"labels":[],"label_agreement":null},{"id":"W2064222581","doi":"10.1002/hc.20287","title":"A report on the “new frontiers in group 13 chemistry” symposium from the 88th Canadian Society for Chemistry Conference and Exhibition","year":2007,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":true,"route_ca_venue":false,"route_about_ca":true,"ca_institutions":"Acadia University; Mount Allison University","funders":"American Chemical Society Petroleum Research Fund; University of Akron; University of Windsor; University of Pennsylvania","keywords":"Exhibition; Chemistry; Heteroatom; Library science; Engineering physics; Art history; Organic chemistry; Engineering; History; Computer science","score_opus":0.011837743981512086,"score_gpt":0.20423678758153455,"score_spread":0.19239904360002247,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2064222581","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.981266,0.0004743215,0.0004625008,0.0038169713,0.00005955912,0.00018367734,0.00027547847,0.00006834218,0.013393114],"genre_scores_gemma":[0.9932645,0.00009318602,0.00032572806,0.00049999997,0.0006650729,0.000091439215,0.00066426065,0.000061490195,0.004334318],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9974568,0.000008767945,0.0005983172,0.0008732723,0.00036371505,0.0006991289],"domain_scores_gemma":[0.997786,0.00036398866,0.00027978446,0.0011030041,0.00006225698,0.0004049772],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005464553,0.00044353184,0.00042194236,0.000011586731,0.00032031073,0.0001933015,0.00060597685,0.00039465204,0.004228323],"category_scores_gemma":[0.00015625218,0.0003395552,0.0003915055,0.0001872627,0.0002459951,0.00007632511,0.00011027534,0.00051121594,0.0000030938504],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000068535686,0.00008159634,0.0034714984,0.00024818798,0.0002456648,0.000044641405,0.00044087117,0.0000022774723,0.98099303,0.0000065586123,0.011839311,0.0025578449],"study_design_scores_gemma":[0.0007538666,0.0000041691073,0.00070543366,0.00018796317,0.00013594913,0.00008141334,0.0018319428,0.0004180426,0.93418896,0.00042196474,0.060727425,0.0005428942],"about_ca_topic_score_codex":0.005896225,"about_ca_topic_score_gemma":0.002012779,"teacher_disagreement_score":0.048888113,"about_ca_system_score_codex":0.0004149088,"about_ca_system_score_gemma":0.00023458186,"threshold_uncertainty_score":0.99990565},"labels":[],"label_agreement":null},{"id":"W2072980288","doi":"10.1002/hc.10067","title":"Heteroatoms and substituent effects: The importance of heteroatom hyperconjugation","year":2002,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organic and Inorganic Chemical Reactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Heteroatom; Hyperconjugation; Substituent; Carbanion; Antibonding molecular orbital; Lone pair; Atomic orbital; Computational chemistry; Crystallography; Alkoxy group; Sulfonyl; Stereochemistry; Medicinal chemistry; Alkyl; Molecule; Organic chemistry","score_opus":0.0094523328065147,"score_gpt":0.19774987584903975,"score_spread":0.18829754304252505,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2072980288","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9915183,0.0018768618,0.000034362183,0.00041035403,0.00006985235,0.00008824904,0.000024039986,0.00012303558,0.005854926],"genre_scores_gemma":[0.99838555,0.00037733014,0.00006570358,0.00027952285,0.00017330772,0.00003354596,0.000022907467,0.000045370343,0.00061678654],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9983133,0.00001376406,0.00051100657,0.0004682216,0.00032925923,0.00036441532],"domain_scores_gemma":[0.99853396,0.00023033755,0.00024821662,0.0007485836,0.000060815637,0.00017810125],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008097814,0.00031096692,0.0003415967,0.000016347834,0.00014668515,0.00004536915,0.0003334438,0.00024271742,0.0020193204],"category_scores_gemma":[0.0001651964,0.00024571925,0.00014952301,0.00015516863,0.0003137772,0.00015705434,0.00013849634,0.0004077896,0.000033389737],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000010467386,0.000121829,0.009749675,0.00044543878,0.00006919487,0.000007079575,0.00024270502,5.619343e-7,0.9871438,0.000022219992,0.0008831603,0.0013038637],"study_design_scores_gemma":[0.00064943323,0.000010423331,0.00043476518,0.00009639445,0.00007092028,0.0001475952,0.00015608597,0.00041510988,0.99307185,0.0001180008,0.0045591425,0.00027030084],"about_ca_topic_score_codex":0.000008887532,"about_ca_topic_score_gemma":0.0000031219322,"teacher_disagreement_score":0.00931491,"about_ca_system_score_codex":0.000101223304,"about_ca_system_score_gemma":0.000011349281,"threshold_uncertainty_score":0.9999995},"labels":[],"label_agreement":null},{"id":"W2101787241","doi":"10.1002/hc.20025","title":"Synthesis and reactivity of sulfonamides containing boronate esters","year":2004,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"","keywords":"Chemistry; Heteroatom; Pinacol; Sulfonyl; Aryl; Reactivity (psychology); Medicinal chemistry; Nitro; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis; Alkyl","score_opus":0.012076649960439364,"score_gpt":0.21395059504079342,"score_spread":0.20187394508035406,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2101787241","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9894935,0.00035750435,0.000033083386,0.00013765687,0.000011661324,0.000023212042,0.000049006114,0.000068835085,0.009825579],"genre_scores_gemma":[0.99938667,0.0000681652,0.00021296409,0.000022443111,0.000050208484,0.000019517573,0.0000135578075,0.000031541294,0.0001949617],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9987888,0.000007990647,0.00032442267,0.000395006,0.00022078792,0.000263041],"domain_scores_gemma":[0.9989938,0.00018336312,0.00019716498,0.00046776433,0.000036619236,0.00012129021],"candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00012508508,0.00023092804,0.00042064177,0.000025081497,0.00007073546,0.000035081026,0.00019899044,0.00012882492,0.0018081884],"category_scores_gemma":[0.00014788615,0.0002339301,0.0001493358,0.00008658011,0.00018285368,0.00011662317,0.00012231356,0.00014006559,0.0000039098845],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00003958782,0.000091449074,0.002354642,0.00035852776,0.00011738443,0.0000112428015,0.00013189546,0.000008015055,0.9824374,0.00002190347,0.0000026698592,0.014425289],"study_design_scores_gemma":[0.00034292575,0.0000055823452,0.0014684388,0.00014035766,0.00009260159,0.000042760155,0.00032809118,0.000020151687,0.9959496,0.00017939761,0.0011895017,0.0002405396],"about_ca_topic_score_codex":0.00010435807,"about_ca_topic_score_gemma":0.0000063831303,"teacher_disagreement_score":0.014184749,"about_ca_system_score_codex":0.0000924566,"about_ca_system_score_gemma":0.000036606078,"threshold_uncertainty_score":0.9991043},"labels":[],"label_agreement":null},{"id":"W2159177917","doi":"10.1002/hc.20512","title":"Synthesis, structure, and antifungal activity of dihydropyridones containing boronate esters","year":2009,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":true,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"National Cancer Institute; Merck Canada; Mount Allison University; Canada Research Chairs","keywords":"Chemistry; Heteroatom; Antifungal; Catalysis; Boron; Diene; Lewis acids and bases; Organic chemistry; Lewis acid catalysis; Combinatorial chemistry; Medicinal chemistry; Ring (chemistry)","score_opus":0.007868622859866116,"score_gpt":0.2252477406351394,"score_spread":0.21737911777527327,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2159177917","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.99642956,0.00044363862,0.0000070701167,0.00018209951,0.000039983755,0.000040261468,0.00013355396,0.00015294664,0.0025708785],"genre_scores_gemma":[0.9993884,0.00008611288,0.00010635946,0.00010397597,0.00014396598,0.0000040323457,0.000022717924,0.00004170837,0.00010274316],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99825543,0.000013201973,0.00038667288,0.0005901342,0.0003078787,0.00044665486],"domain_scores_gemma":[0.9987352,0.00011941174,0.0002695997,0.00058082934,0.000054918863,0.00024004122],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007039687,0.00041395507,0.0005388269,0.000023881288,0.00010376923,0.000060201037,0.00031161853,0.00036142397,0.0010877781],"category_scores_gemma":[0.00010722806,0.00042630424,0.0001263845,0.00009384903,0.00021678042,0.00016970465,0.00010006113,0.00038309884,0.0000020334323],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.0001245017,0.00008541374,0.010053674,0.00049360807,0.000055584824,0.00002204969,0.00007592236,0.0000019737713,0.9829156,0.000003977169,0.000072905736,0.0060948017],"study_design_scores_gemma":[0.0006346285,0.000016366906,0.0035359734,0.00015188078,0.000060730934,0.0001104143,0.00007669383,0.00012583152,0.99465424,0.00005229649,0.00016107298,0.000419854],"about_ca_topic_score_codex":0.000013357909,"about_ca_topic_score_gemma":9.4295507e-7,"teacher_disagreement_score":0.011738669,"about_ca_system_score_codex":0.00007135316,"about_ca_system_score_gemma":0.000050847484,"threshold_uncertainty_score":0.99982536},"labels":[],"label_agreement":null},{"id":"W2770743128","doi":"10.1002/hc.21405","title":"Synthesis and antimicrobial properties of cyclic fluorodiamines containing boronate esters","year":2017,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":true,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Natural Sciences and Engineering Research Council of Canada; Mount Allison University","keywords":"Chemistry; Pinacol; Hydroamination; Antimicrobial; Amine gas treating; Ligand (biochemistry); Zinc; Organic chemistry; Aldimine; Metal; Boron; Schiff base; Combinatorial chemistry; Medicinal chemistry; Polymer chemistry; Catalysis","score_opus":0.017194690367323365,"score_gpt":0.22362364679809288,"score_spread":0.20642895643076953,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2770743128","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.99538004,0.000456913,0.0000012027743,0.00036727733,0.00006267801,0.00004433658,0.0000566255,0.00010967048,0.003521256],"genre_scores_gemma":[0.99901575,0.00015571798,0.00008422351,0.000067983485,0.00018864949,0.000019681365,0.000010057598,0.000062905994,0.00039504957],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99839085,0.00000830886,0.0004389875,0.0005387574,0.0002126016,0.00041051203],"domain_scores_gemma":[0.998222,0.00005025023,0.00042054188,0.0010497384,0.00007273362,0.00018477133],"candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00009351622,0.00036985805,0.0005063074,0.000017361946,0.00033620803,0.00019149133,0.0006237162,0.00030266927,0.00036950753],"category_scores_gemma":[0.00032706134,0.00036064448,0.00012957328,0.000022950308,0.0006336584,0.00022700202,0.00035190838,0.00024321275,0.000006359535],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00007982571,0.00006139333,0.02171732,0.0015715391,0.000076694945,0.000017913668,0.00016092182,3.5243033e-7,0.9743904,0.000001019685,0.00011165329,0.001811007],"study_design_scores_gemma":[0.0006754886,0.0000048950465,0.0010083762,0.0005146,0.00006568841,0.00008524891,0.00021275706,0.000033678873,0.996701,0.0000035441583,0.0003009555,0.00039379453],"about_ca_topic_score_codex":0.00006195771,"about_ca_topic_score_gemma":0.0000040598275,"teacher_disagreement_score":0.022310613,"about_ca_system_score_codex":0.000049782222,"about_ca_system_score_gemma":0.000052271454,"threshold_uncertainty_score":0.99988455},"labels":[],"label_agreement":null},{"id":"W2907538243","doi":"10.1002/hc.21474","title":"A “masked” source for the phosphaalkene MesP=CH2: Trapping, rearrangement, and oligomerization","year":2018,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":true,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Trapping; Stereochemistry; Medicinal chemistry","score_opus":0.013482260854749508,"score_gpt":0.21631205042350443,"score_spread":0.20282978956875491,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2907538243","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.99136,0.00044229825,0.004485157,0.00037472055,0.00013225997,0.0001796133,0.000065939756,0.00020917282,0.0027508258],"genre_scores_gemma":[0.995541,0.0003565974,0.00010776007,0.00046131955,0.0010239303,0.00014330352,0.00014775996,0.00010423402,0.0021141456],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9980946,0.000013601244,0.00047546256,0.00062254944,0.00030901554,0.0004847812],"domain_scores_gemma":[0.9983505,0.00032772758,0.00032256704,0.0006520065,0.00017190678,0.00017526807],"candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00019386531,0.00038611778,0.00033699514,0.000032094522,0.00046233874,0.0002284981,0.0004215182,0.00023890064,0.00047697857],"category_scores_gemma":[0.00023278664,0.00033998495,0.00016159192,0.00021847828,0.00027327216,0.00014416699,0.00014556799,0.00017431023,0.0000220176],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000018483888,0.00008404124,0.00059923064,0.00022684985,0.0001719006,8.71449e-7,0.00048043492,0.0000010622776,0.98915505,0.0000095399155,0.0012709544,0.007981561],"study_design_scores_gemma":[0.0006685865,0.000017748358,0.00057330413,0.00006465325,0.00009926341,0.000029981375,0.00032092663,0.00085156655,0.85419166,0.000030391853,0.14298044,0.00017148216],"about_ca_topic_score_codex":0.0000040401183,"about_ca_topic_score_gemma":0.0000014747255,"teacher_disagreement_score":0.14170948,"about_ca_system_score_codex":0.000066233246,"about_ca_system_score_gemma":0.000043910903,"threshold_uncertainty_score":0.9999052},"labels":[],"label_agreement":null},{"id":"W2910326173","doi":"10.1155/2019/7680264","title":"A Thermochemical Parameters and Theoretical Study of the Chlorinated Compounds of Thiophene","year":2019,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"Memorial University of Newfoundland","funders":"National Cancer Institute; National Computational Infrastructure","keywords":"Thiophene; Chemistry; Enthalpy; Standard enthalpy of formation; Standard enthalpy change of formation; Gibbs free energy; Thermodynamics; Sequence (biology); Reactivity (psychology); Computational chemistry; Selectivity; Physical chemistry; Organic chemistry","score_opus":0.0034610722789946554,"score_gpt":0.19322996060717176,"score_spread":0.18976888832817712,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2910326173","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.994392,0.000053509368,0.0000010786341,0.000032321608,0.000032641354,0.0001204715,0.000013500518,0.000021152699,0.0053333747],"genre_scores_gemma":[0.99981797,0.000004853151,0.000036399084,0.000027200735,0.000015185667,0.000008650222,0.000008699937,0.000027887121,0.0000531361],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9987918,0.00001587367,0.00034002113,0.00034063502,0.00030771698,0.00020396317],"domain_scores_gemma":[0.9988696,0.000082414954,0.00017850853,0.00073743943,0.00005607203,0.00007594595],"candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000060809274,0.00021524057,0.00036629025,0.000008556391,0.00002778147,0.000012302734,0.00041398546,0.00020143762,0.00029575787],"category_scores_gemma":[0.000038902403,0.0001531386,0.00014184123,0.0001022692,0.0003725693,0.00001650692,0.00030165707,0.00033094198,5.305866e-7],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00010345931,0.00021049756,0.007750399,0.0002991173,0.000106926615,0.0000020341674,0.00021409536,0.0000055453597,0.99097574,0.00022574374,0.0000044496533,0.00010201677],"study_design_scores_gemma":[0.001196416,0.000024695073,0.00075095193,0.00007897697,0.000051455856,0.0000261275,0.00031634766,0.00044045312,0.99572194,0.0012131899,0.000015575633,0.00016387661],"about_ca_topic_score_codex":0.00000985731,"about_ca_topic_score_gemma":2.504e-7,"teacher_disagreement_score":0.006999447,"about_ca_system_score_codex":0.000027349386,"about_ca_system_score_gemma":0.00001612061,"threshold_uncertainty_score":0.624481},"labels":[],"label_agreement":null},{"id":"W2940199875","doi":"10.1155/2019/8124696","title":"Host-Guest Complexations of Amine Boranes and Isoelectronic/Isostructural Quaternary Alkylammonium Cations by Cucurbit[7]uril in Aqueous Solution","year":2019,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":4,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":true,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Aqueous solution; Chemistry; Amine gas treating; Physical chemistry; Organic chemistry","score_opus":0.0063108756764698294,"score_gpt":0.2426920766942727,"score_spread":0.23638120101780288,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2940199875","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.99493474,0.0022460178,0.000018291852,0.0011071541,0.00012484676,0.00026992577,0.00011477451,0.00007108444,0.0011131943],"genre_scores_gemma":[0.99775076,0.00013317191,0.0003290542,0.00009021606,0.00013667757,0.000029149505,0.00056106737,0.0000380099,0.00093188346],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9983817,0.000020444648,0.00050450914,0.00044098604,0.0002703908,0.00038199322],"domain_scores_gemma":[0.99892086,0.00008170524,0.00021414727,0.00053659413,0.00011313071,0.00013356771],"candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000086391214,0.00026307412,0.00043303485,0.00004570602,0.00005292292,0.000020981493,0.00016193508,0.000222526,0.00014619406],"category_scores_gemma":[0.00004376857,0.0002784661,0.00007705536,0.00017352284,0.0001736172,0.00011319741,0.00008810614,0.0004037247,0.000009801138],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000086008644,0.00013915983,0.06758508,0.0005947582,0.000040329975,0.000007992789,0.0001253573,0.0000027096671,0.9300164,0.0000034814702,0.0012739548,0.00012474967],"study_design_scores_gemma":[0.0019384195,0.00009183458,0.008041559,0.00021522085,0.000055378765,0.00047934958,0.000120190176,0.0025626142,0.98414433,0.000045161247,0.0020061848,0.0002997644],"about_ca_topic_score_codex":0.00025133905,"about_ca_topic_score_gemma":0.000047603477,"teacher_disagreement_score":0.05954352,"about_ca_system_score_codex":0.00022659973,"about_ca_system_score_gemma":0.00010992022,"threshold_uncertainty_score":0.99996674},"labels":[],"label_agreement":null},{"id":"W2950959656","doi":"10.1002/hc.20341","title":"Fascinating organosulfur functionalities: Polychalcogens as diatomic sulfur sources","year":2007,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"McGill University","funders":"","keywords":"Organosulfur compounds; Chemistry; Sulfur; Diatomic molecule; Organic chemistry; Computational chemistry; Molecule","score_opus":0.010290231196798472,"score_gpt":0.2435454392771969,"score_spread":0.23325520808039843,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2950959656","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9462606,0.0005125113,0.00028728455,0.00018865065,0.00011386756,0.00008184669,0.00006294246,0.0013424593,0.051149864],"genre_scores_gemma":[0.99239194,0.000024702784,0.00062654284,0.0005188143,0.0009177225,0.000053943717,0.00010316405,0.00015924362,0.0052039004],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99645114,0.000022812315,0.0008172167,0.0009026128,0.00077267596,0.0010335337],"domain_scores_gemma":[0.99739975,0.0006679888,0.00036862923,0.0010079091,0.0001675218,0.00038820403],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000585959,0.00059969514,0.00048482014,0.000106025924,0.00031726545,0.00013146049,0.0006680538,0.0005669171,0.0069347257],"category_scores_gemma":[0.0005178263,0.00065256795,0.0003510069,0.00028814934,0.00024455084,0.00020002143,0.00021345777,0.0006030901,0.00022757072],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.000078631834,0.00013132997,0.011859425,0.00033373781,0.00011740532,0.00008863043,0.0003204635,0.0000016009799,0.9842462,0.00003509998,0.00091729756,0.00187017],"study_design_scores_gemma":[0.0004957145,0.000011831267,0.00022895513,0.000153002,0.000059112885,0.00024582216,0.0016877572,0.000017944198,0.9826357,0.00035216816,0.013427392,0.00068463426],"about_ca_topic_score_codex":0.00011445695,"about_ca_topic_score_gemma":0.000009113668,"teacher_disagreement_score":0.046131395,"about_ca_system_score_codex":0.00047394854,"about_ca_system_score_gemma":0.00014349294,"threshold_uncertainty_score":0.99959254},"labels":[],"label_agreement":null},{"id":"W2951271740","doi":"10.1002/hc.20595","title":"Dimethylsilylaminophosphane heterocyclization of isothiocyanates to diazaphosphole‐thiones through zwitterionic intermediates","year":2010,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Medicinal chemistry","score_opus":0.006335521766648418,"score_gpt":0.2238562269380801,"score_spread":0.21752070517143168,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2951271740","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9964774,0.0001329774,0.00028136635,0.00035771524,0.00037776757,0.00009319688,0.000072373514,0.00018080183,0.002026385],"genre_scores_gemma":[0.99731284,0.00008040991,0.0007889338,0.000334303,0.0003038011,0.00005652659,0.00017916672,0.00008748227,0.0008565243],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.99774516,0.0000117017635,0.0007790012,0.0006277315,0.00040416597,0.0004322706],"domain_scores_gemma":[0.9982218,0.00015108593,0.00035590536,0.0008679467,0.00018892769,0.00021431976],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00010686217,0.00042268474,0.00051979744,0.00005314356,0.00011441925,0.000099245524,0.00066853355,0.00034170822,0.009058955],"category_scores_gemma":[0.00024304581,0.00042761583,0.00020568076,0.0003139103,0.00015986006,0.00024232687,0.0002624572,0.00037147253,0.000074345524],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00004138498,0.00024067624,0.009459,0.00026214708,0.000070271104,0.0000044210547,0.00057640416,0.0000022140362,0.98735595,0.000021261485,0.00015593339,0.0018103499],"study_design_scores_gemma":[0.0004120169,0.000017385764,0.0027124782,0.00010979226,0.000038511505,0.00003267792,0.00017086664,0.000062432446,0.98783416,0.00012961103,0.0080398815,0.00044017582],"about_ca_topic_score_codex":0.00003388218,"about_ca_topic_score_gemma":0.0000061441983,"teacher_disagreement_score":0.0089846095,"about_ca_system_score_codex":0.00005809565,"about_ca_system_score_gemma":0.000044402612,"threshold_uncertainty_score":0.99981755},"labels":[],"label_agreement":null},{"id":"W2951835811","doi":"10.1002/hc.20033","title":"Heterocyclizations of hydroxyketones with two‐coordinated (trimethylsilylamino)phosphines, (Me3Si)2NPESiMe3","year":2004,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":true,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Heteroatom; Phosphine; Medicinal chemistry; Yield (engineering); Alkyl; Phosphorus; Organic chemistry; Stereochemistry; Catalysis","score_opus":0.007843721868363436,"score_gpt":0.20391737922485617,"score_spread":0.19607365735649274,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2951835811","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9953181,0.00049759954,0.0010839349,0.00035983336,0.00021058643,0.00033615044,0.00030798663,0.00068634446,0.0011994718],"genre_scores_gemma":[0.9968381,0.00040467893,0.00018766345,0.00027059045,0.0005244953,0.00014486995,0.0011308084,0.00039298862,0.000105796615],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9937188,0.00006383746,0.0019100555,0.0017945216,0.0011935477,0.0013192435],"domain_scores_gemma":[0.9949918,0.00032633045,0.0013671418,0.0020260466,0.00062987435,0.000658842],"candidate_categories":["metaepi_narrow"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0002765422,0.0014725354,0.0015738519,0.00025119047,0.0005031627,0.00028796264,0.0012602953,0.00082565175,0.00034245916],"category_scores_gemma":[0.00027361247,0.001506439,0.00060243614,0.0014138047,0.00058493525,0.0006135294,0.0004491355,0.0008619349,0.00011591513],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00019227891,0.0011206485,0.0044408715,0.0008176028,0.00053244206,0.00007588143,0.00023548266,0.0002632784,0.9906714,0.00002419572,0.00014818211,0.0014777341],"study_design_scores_gemma":[0.003597658,0.00007300099,0.0027053808,0.0006255714,0.0003618797,0.00031187478,0.00015343442,0.0002064826,0.98974234,0.00018398213,0.0004054511,0.0016329207],"about_ca_topic_score_codex":0.00003185325,"about_ca_topic_score_gemma":0.000024300909,"teacher_disagreement_score":0.003405379,"about_ca_system_score_codex":0.0005565917,"about_ca_system_score_gemma":0.00040120893,"threshold_uncertainty_score":0.9998024},"labels":[],"label_agreement":null},{"id":"W2952053495","doi":"10.1002/(sici)1098-1071(2000)11:3<182::aid-hc3>3.0.co;2-x","title":"Crystallographic characterization of a stable 7-phosphanorbornadiene-7-oxide: 2,3-benzo-1,4,5,6,7-pentaphenyl-7-phosphabicyclo[2.2.1] hepta-2,5-diene-7-oxide","year":2000,"lang":"en","type":"article","venue":"Heteroatom Chemistry","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"McMaster University; Lakehead University","funders":"","keywords":"Chemistry; Heteroatom; Aryne; Diene; Yield (engineering); Oxide; Derivative (finance); Characterization (materials science); Medicinal chemistry; Stereochemistry; Organic chemistry; Ring (chemistry); Nanotechnology","score_opus":0.0063219921047798,"score_gpt":0.1996473483435456,"score_spread":0.19332535623876582,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W2952053495","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.97316855,0.00062927464,0.000035188234,0.00011567274,0.0001262909,0.00017550387,0.00038206007,0.00037689687,0.024990562],"genre_scores_gemma":[0.9845582,0.0013402888,0.00032126065,0.00016632912,0.0001610999,0.00012032338,0.00060869247,0.00013954191,0.012584236],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9960606,0.000028134651,0.0011740199,0.0010191955,0.0006581087,0.0010599443],"domain_scores_gemma":[0.9973442,0.00008759774,0.00052170624,0.0013431379,0.00019603116,0.00050731254],"candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00018939629,0.0007202301,0.0008251504,0.000118414886,0.00034910828,0.000121205405,0.00078031997,0.0005059339,0.011171608],"category_scores_gemma":[0.000033913202,0.0007556399,0.000557015,0.00065972167,0.00035258848,0.0005519529,0.00013532898,0.00061047747,0.00008386987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.00017584034,0.0005314847,0.0080365315,0.00046181554,0.0002174378,0.00004043268,0.00016338566,0.000044537708,0.98738474,0.000027207469,0.00033403264,0.0025825277],"study_design_scores_gemma":[0.0011272104,0.00002134454,0.0038538454,0.00025665967,0.000109329274,0.000121947945,0.00009463205,0.00024538493,0.89235455,0.00011448904,0.10095238,0.00074821734],"about_ca_topic_score_codex":0.00029973075,"about_ca_topic_score_gemma":0.000023162054,"teacher_disagreement_score":0.10061835,"about_ca_system_score_codex":0.00021980329,"about_ca_system_score_gemma":0.00013467578,"threshold_uncertainty_score":0.9994895},"labels":[],"label_agreement":null},{"id":"W4233358083","doi":"10.1002/hc.20619","title":"Erratum: Synthesis of functional phosphines with ortho‐substituted aryl groups: 2‐RC6H4PH2 and 2‐RC6H4P(SiMe3)2 (R = i‐Pr‐ or t‐Bu)","year":2010,"lang":"en","type":"erratum","venue":"Heteroatom Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"route_ca_aff":true,"route_ca_fund":false,"route_ca_venue":false,"route_about_ca":false,"ca_institutions":"University of British Columbia","funders":"","keywords":"Heteroatom; Chemistry; Aryl; Medicinal chemistry; Stereochemistry; Organic chemistry","score_opus":0.010006073294632415,"score_gpt":0.19323071470135497,"score_spread":0.18322464140672257,"validation_status":"score_only:v0-immature-baseline","prediction":{"id":"W4233358083","genre_codex":"empirical","genre_gemma":"empirical","domain_codex":null,"domain_gemma":null,"model_version":"codex-gemma-dda1882f352a","genre_candidate":"empirical","genre_consensus":"empirical","domain_candidate":null,"domain_consensus":null,"prediction_status":"machine_predicted_unvalidated","genre_scores_codex":[0.9680006,0.004081248,0.000481261,0.00097322493,0.010016153,0.0029770285,0.007039618,0.0031710179,0.0032598504],"genre_scores_gemma":[0.9451166,0.018008564,0.00021332254,0.0021008216,0.011117434,0.0025951492,0.016334536,0.0038593237,0.00065428886],"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","domain_scores_codex":[0.9613134,0.0007572111,0.010029294,0.011803163,0.008260499,0.007836389],"domain_scores_gemma":[0.96793884,0.003274946,0.010085578,0.009727955,0.004013253,0.004959441],"candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.0026158178,0.01160492,0.011077269,0.0020663494,0.0034287004,0.0030120367,0.0065727886,0.011744386,0.0006953213],"category_scores_gemma":[0.002732961,0.012089191,0.0047060745,0.0058306977,0.0047647455,0.0037505338,0.003752585,0.012715299,0.0008577511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_system_candidate":false,"about_ca_system_consensus":false,"study_design_scores_codex":[0.0036073662,0.00425768,0.0013768326,0.00809865,0.0055962848,0.0012440685,0.00053236994,0.00008362177,0.8909496,0.000028919208,0.07295551,0.011269088],"study_design_scores_gemma":[0.0074419538,0.00045966782,0.0023109892,0.0062645935,0.0051997644,0.0032147549,0.0006986721,0.0004430249,0.948444,0.00025320385,0.013110142,0.012159239],"about_ca_topic_score_codex":0.000056241377,"about_ca_topic_score_gemma":0.0005843957,"teacher_disagreement_score":0.059845373,"about_ca_system_score_codex":0.002623829,"about_ca_system_score_gemma":0.0053385966,"threshold_uncertainty_score":0.9999202},"labels":[],"label_agreement":null}]}