{"meta":{"page":1,"per_page":50,"max_per_page":100,"total":285,"total_is_capped":false,"direct_labels_cover":0,"predictions_cover":285,"direct_label_status":"direct model label, unvalidated","prediction_status":"machine_predicted_unvalidated (Codex and Gemma teacher distillation)","score_status":"score_only:v0-immature-baseline (scores rank; they never assert a category)","snapshot":{"source":"OpenAlex, pinned release, all 482 partitions","release":"2026-06-24","frame_built":"2026-07-12","author_layer_release":"2026-06-26"},"query_hash":"0dd2738ae1a0","filters":{"topic":"Metal-Catalyzed Oxygenation Mechanisms"}},"results":[{"id":"W3048799828","doi":"10.1126/science.abc3183","title":"Using nature’s blueprint to expand catalysis with Earth-abundant metals","year":2020,"lang":"en","type":"review","venue":"Science","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":581,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto; Dow Chemical (Canada)","funders":"Basic Energy Sciences; National Institute of General Medical Sciences; Office of Science; National Institutes of Health; U.S. Department of Energy","keywords":"Rhodium; Blueprint; Catalysis; Palladium; Chemistry; Precious metal; Platinum; Nanotechnology; Materials science; Organic chemistry; Engineering","authors":[{"name":"R. Morris Bullock","is_ca":false},{"name":"Jingguang G. Chen","is_ca":false},{"name":"Laura Gagliardi","is_ca":false},{"name":"Paul J. Chirik","is_ca":false},{"name":"Omar K. Farha","is_ca":false},{"name":"Christopher H. Hendon","is_ca":false},{"name":"Christopher W. Jones","is_ca":false},{"name":"John A. Keith","is_ca":false},{"name":"Jerzy Klosin","is_ca":true},{"name":"Shelley D. Minteer","is_ca":false},{"name":"Robert H. Morris","is_ca":true},{"name":"Alexander T. Radosevich","is_ca":false},{"name":"Thomas B. Rauchfuss","is_ca":false},{"name":"Neil A. Strotman","is_ca":false},{"name":"Aleksandra Vojvodić","is_ca":false},{"name":"Thomas R. Ward","is_ca":false},{"name":"Jenny Y. Yang","is_ca":false},{"name":"Yogesh Surendranath","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.07726088697468013,"gpt":0.3670354417633401,"spread":0.2897745547886599,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008991297,0.0005511566,0.001478706,0.0004139433,0.0003243354,0.0003630947,0.001858503,0.000265515,0.0006313002],"category_scores_gemma":[0.0005809884,0.0004018159,0.0003390065,0.002971691,0.0002853178,0.0002966659,0.0006930312,0.0007549631,0.00046928],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002979923,"about_ca_system_score_gemma":0.001643275,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001629622,"about_ca_topic_score_gemma":0.00001242283,"domain_scores_codex":[0.995672,0.00004349045,0.0006180784,0.001529541,0.001546069,0.0005908473],"domain_scores_gemma":[0.9973217,0.00007887092,0.0004807711,0.001316455,0.0002251589,0.0005770968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000009714993,0.00009416328,0.000001107748,0.009784226,0.00045044,0.0002600231,0.0005058856,0.0001132047,0.06710251,0.001836555,0.00002335155,0.9198188],"study_design_scores_gemma":[0.00009588908,0.0000156911,2.913061e-7,0.002881942,0.0007676039,0.00014929,0.00006731258,0.0001353951,0.06675073,0.00004525365,0.9283795,0.000711108],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0004089552,0.9930636,0.003551991,0.00003828197,0.000331094,0.0004566415,0.00009327319,0.0001298564,0.001926291],"genre_scores_gemma":[0.0007472564,0.9435256,0.05307407,0.0002189403,0.0003307016,0.0001711216,0.0001251522,0.0001616232,0.001645527],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9283562,"threshold_uncertainty_score":0.9998434,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2020551149","doi":"10.1080/10409230600817422","title":"The Ins and Outs of Ring-Cleaving Dioxygenases","year":2006,"lang":"en","type":"review","venue":"Critical Reviews in Biochemistry and Molecular Biology","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":435,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"","keywords":"Cleave; Chemistry; Enzyme; Dioxygenase; Stereochemistry; Heme; Cleavage (geology); Divalent; Biochemistry; Combinatorial chemistry; Organic chemistry; Biology","authors":[{"name":"Frédéric H. Vaillancourt","is_ca":false},{"name":"Jeffrey T. Bolin","is_ca":false},{"name":"Lindsay D. Eltis","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.03722343333840272,"gpt":0.3719753099183863,"spread":0.3347518765799836,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006558497,0.0004511726,0.001589428,0.00005076314,0.00008969852,0.00003363465,0.0003794295,0.0006474546,0.00004955805],"category_scores_gemma":[0.003830484,0.0003104822,0.000301605,0.0001523903,0.0006632882,0.00001764233,0.0003241264,0.0004896456,0.000005329302],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003913771,"about_ca_system_score_gemma":0.00008044496,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006458683,"about_ca_topic_score_gemma":0.000001991752,"domain_scores_codex":[0.9974842,0.0002046961,0.001168095,0.0006544491,0.0001064037,0.0003821692],"domain_scores_gemma":[0.9981802,0.0007210362,0.0002997526,0.0006155173,0.00005477132,0.0001287678],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000004159131,0.00006186301,0.000002964725,0.05052152,0.00005769976,0.00003099912,0.000005542936,1.559154e-8,0.04929827,0.01450103,0.00008548443,0.8854305],"study_design_scores_gemma":[0.00012681,0.00001404171,2.188836e-7,0.007917721,0.0002866474,0.00008844071,0.000009298686,0.000002465892,0.03606626,0.00169405,0.9534289,0.0003651025],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0002290779,0.9972166,0.0002888954,0.0000442661,0.00006145341,0.000210885,0.00009402166,0.00001375039,0.001841092],"genre_scores_gemma":[0.0007463419,0.997946,0.0006299721,0.00003758212,0.00007466668,0.0001392791,0.0002249115,0.00003291626,0.0001683937],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9533435,"threshold_uncertainty_score":0.9999347,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1654652909","doi":"10.1073/pnas.0504412102","title":"SyrB2 in syringomycin E biosynthesis is a nonheme Fe <sup>II</sup> α-ketoglutarate- and O <sub>2</sub> -dependent halogenase","year":2005,"lang":"en","type":"article","venue":"Proceedings of the National Academy of Sciences","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":334,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada; National Institutes of Health; Helen Hay Whitney Foundation","keywords":"Halogenation; Chemistry; Biosynthesis; Enzyme; Moiety; Stereochemistry; Residue (chemistry); Thioesterase; Derivatization; Biochemistry; Organic chemistry; High-performance liquid chromatography","authors":[{"name":"Frédéric H. Vaillancourt","is_ca":false},{"name":"Jun Yin","is_ca":false},{"name":"Christopher T. Walsh","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02914501616028375,"gpt":0.2629141736321043,"spread":0.2337691574718206,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001720602,0.0002128264,0.0002888055,0.0003645211,0.00026757,0.0000502701,0.0009413055,0.0001939429,0.0001019772],"category_scores_gemma":[0.000771304,0.0001525181,0.0000992275,0.0007678828,0.0004912483,0.0006740371,0.0003565603,0.0002750366,0.000009577572],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001129216,"about_ca_system_score_gemma":0.00005760145,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001016049,"about_ca_topic_score_gemma":6.023367e-7,"domain_scores_codex":[0.9969451,0.000008022917,0.0006286812,0.0005323419,0.001581559,0.0003043236],"domain_scores_gemma":[0.9989558,0.0001541987,0.0005330752,0.00002603401,0.0002403262,0.00009051757],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001963082,0.00009044162,0.0007191346,0.0001137321,0.00002189982,3.538194e-8,0.0006307424,0.0002166444,0.9900705,0.006182396,0.0001367222,0.001798171],"study_design_scores_gemma":[0.0003301848,0.0000142745,0.00102747,0.0001337376,0.00001913473,0.00002158258,0.0003547817,0.008528453,0.9814941,0.007698435,0.000205406,0.0001724447],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927631,0.00017117,0.00000131259,0.004389327,0.000007525433,0.0001492197,0.00006292354,0.00002424961,0.002431161],"genre_scores_gemma":[0.9975514,0.0001055401,0.001576647,0.0003890433,0.00009654678,0.00002693768,5.32202e-7,0.00001223008,0.0002410888],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008576355,"threshold_uncertainty_score":0.6219507,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2009723401","doi":"10.3389/fpls.2014.00524","title":"Functional diversity of 2-oxoglutarate/Fe(II)-dependent dioxygenases in plant metabolism","year":2014,"lang":"en","type":"review","venue":"Frontiers in Plant Science","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":213,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Calgary","funders":"","keywords":"Odds; Biology; Biochemistry; Enzyme; Chemistry; Medicine; Internal medicine","authors":[{"name":"Scott C. Farrow","is_ca":true},{"name":"Peter J. Facchini","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.03515951679778409,"gpt":0.2546271080085568,"spread":0.2194675912107727,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.002017908,0.0005576696,0.002048787,0.001368465,0.0003412671,0.00005140358,0.001933837,0.0003814934,0.000304066],"category_scores_gemma":[0.0003602412,0.000491404,0.0003061283,0.001218142,0.0004522179,0.0003686572,0.001294086,0.000690205,0.00003560507],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005374905,"about_ca_system_score_gemma":0.0007705929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001565934,"about_ca_topic_score_gemma":0.00004685069,"domain_scores_codex":[0.9951708,0.0001230274,0.001142847,0.001158987,0.001701693,0.0007026411],"domain_scores_gemma":[0.9979334,0.0001481514,0.0008413833,0.0007665661,0.00008995904,0.0002204646],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0007700936,0.003357118,0.003787051,0.07249589,0.001518772,0.001506571,0.003893045,0.001918276,0.009944596,0.02428431,0.05877372,0.8177506],"study_design_scores_gemma":[0.001698811,0.00004319247,0.0002313533,0.00885076,0.0006503836,0.0002731016,0.0003796239,0.002024328,0.009916559,0.001340034,0.9725128,0.002078984],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.001947609,0.9842324,0.00323773,0.00001155524,0.004345054,0.0005130056,0.004163265,0.00006717409,0.001482229],"genre_scores_gemma":[0.001684389,0.992584,0.003062542,0.00002781622,0.0001896175,0.00007246457,0.001248627,0.00004021759,0.001090258],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9137391,"threshold_uncertainty_score":0.9997538,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2598146353","doi":"10.1038/ncomms14839","title":"Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex","year":2017,"lang":"en","type":"article","venue":"Nature Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":205,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Division of Chemistry; National Institute of General Medical Sciences; Japan Society for the Promotion of Science; National Research Council Canada; Canadian Light Source; Natural Sciences and Engineering Research Council of Canada; National Science Foundation; Canadian Institutes of Health Research; Institute for Basic Science; Western Economic Diversification Canada; Korea Science and Engineering Foundation; National Institutes of Health; Ministry of Science, ICT and Future Planning; Deutsche Forschungsgemeinschaft; University of Saskatchewan","keywords":"Reactivity (psychology); Cobalt; Chemistry; Catalysis; Photochemistry; Olefin fiber; Oxygen; Raman spectroscopy; Inorganic chemistry; Organic chemistry","authors":[{"name":"Bin Wang","is_ca":false},{"name":"Yong‐Min Lee","is_ca":false},{"name":"Woon-Young Tcho","is_ca":false},{"name":"Samat Tussupbayev","is_ca":false},{"name":"Seoung‐Tae Kim","is_ca":false},{"name":"Yujeong Kim","is_ca":false},{"name":"Mi Sook Seo","is_ca":false},{"name":"Kyung‐Bin Cho","is_ca":false},{"name":"Yavuz Dede","is_ca":false},{"name":"Brenna C. Keegan","is_ca":false},{"name":"Takashi Ogura","is_ca":false},{"name":"Sun Hee Kim","is_ca":false},{"name":"Takehiro Ohta","is_ca":false},{"name":"Mu‐Hyun Baik","is_ca":false},{"name":"Kallol Ray","is_ca":false},{"name":"Jason Shearer","is_ca":false},{"name":"Wonwoo Nam","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.04863529797268627,"gpt":0.3213217803576678,"spread":0.2726864823849816,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003451772,0.0001580832,0.0002976953,0.00006577017,0.0007617899,0.00008599708,0.001992707,0.0003347761,0.0002461737],"category_scores_gemma":[0.001251442,0.0001629826,0.00008871072,0.00007067779,0.0003366773,0.0002318391,0.0009505008,0.0007242576,0.00002454053],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004540598,"about_ca_system_score_gemma":0.00004768954,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000137569,"about_ca_topic_score_gemma":0.0002836762,"domain_scores_codex":[0.9990444,0.00006041433,0.0002726696,0.0002384263,0.0002250892,0.0001589821],"domain_scores_gemma":[0.9938885,0.000502814,0.0004909908,0.004820924,0.0002024534,0.00009431349],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003905125,0.0003711374,0.001719689,0.0001293733,0.0001743159,0.000001945207,0.0003728635,0.000001906383,0.9474259,0.02966346,0.002474345,0.01762599],"study_design_scores_gemma":[0.001377802,0.00002687178,0.07956001,0.0002806215,0.0003689036,0.00004750652,0.0006440893,0.009524137,0.7889283,0.004813919,0.1135815,0.0008463396],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.797741,0.001627379,0.0004010206,0.007862123,0.0001523112,0.000371279,0.0006845896,0.0001896819,0.1909706],"genre_scores_gemma":[0.983836,0.0004643296,0.01521722,0.00006469203,0.00002878684,0.00003842964,0.00007479869,0.00002796528,0.0002477638],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1907229,"threshold_uncertainty_score":0.6646239,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1980770514","doi":"10.1021/ja068090g","title":"Lone Pair−π and π−π Interactions Play an Important Role in Proton-Coupled Electron Transfer Reactions","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":201,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"National Institute for Nanotechnology; Queen's University","funders":"University of Alberta; Western Canada Research Grid","keywords":"Chemistry; Proton-coupled electron transfer; Electron transfer; Lone pair; Stacking; Proton; Chemical physics; Hydrogen atom; Computational chemistry; Molecule; Photochemistry; Organic chemistry","authors":[{"name":"Gino A. DiLabio","is_ca":true},{"name":"Erin R. Johnson","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.009096427029211164,"gpt":0.2683117090043293,"spread":0.2592152819751182,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007305389,0.0001545998,0.0003121253,0.00003672383,0.00008364259,0.00002710617,0.000268472,0.0000696754,0.0001277556],"category_scores_gemma":[0.0001071399,0.000113248,0.0003049222,0.0003365836,0.0001563256,0.0002024227,0.00003515742,0.0008749629,9.180683e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002931655,"about_ca_system_score_gemma":0.00008175091,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001039829,"about_ca_topic_score_gemma":0.00002746078,"domain_scores_codex":[0.99845,0.00002653571,0.0007018159,0.0001800677,0.0003532779,0.0002883418],"domain_scores_gemma":[0.998898,0.0001373316,0.0004668879,0.0002319333,0.0000977749,0.0001681189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001097572,0.0002098144,0.001912281,0.00001552723,0.00007653933,0.000003328366,0.0005745259,0.000007664339,0.9964018,0.00003096803,0.0000616332,0.0005961939],"study_design_scores_gemma":[0.0005489494,0.00004370535,0.0010677,0.00003362686,0.00005160705,0.000225693,0.001525727,0.0007344103,0.9934751,0.0003813507,0.00177496,0.0001371968],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980481,0.00005310518,0.0009140296,0.0006794889,0.00004677426,0.0001071445,0.000005930583,0.00001815571,0.0001272797],"genre_scores_gemma":[0.9973813,0.00007023035,0.001997738,0.0002202837,0.0001943607,0.00001042109,0.000005246634,0.00002368723,0.00009677847],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002926694,"threshold_uncertainty_score":0.461812,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2060435849","doi":"10.1186/1471-2091-8-23","title":"The FTO (fat mass and obesity associated) gene codes for a novel member of the non-heme dioxygenase superfamily","year":2007,"lang":"en","type":"article","venue":"BMC Biochemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":198,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Ottawa","funders":"","keywords":"Dioxygenase; SUPERFAMILY; Heme; Gene; Biochemistry; Chemistry; Biology; Genetics; Enzyme","authors":[{"name":"Luis Sánchez‐Pulido","is_ca":false},{"name":"Miguel A. Andrade‐Navarro","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02120104498015099,"gpt":0.2509352368519321,"spread":0.2297341918717812,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009597834,0.0002844204,0.0002876106,0.00001809093,0.0003483678,0.00005302878,0.0005871625,0.0003452403,0.00006594579],"category_scores_gemma":[0.0008804444,0.0001964182,0.0002333586,0.0001751073,0.0002105784,0.00004724469,0.0001981339,0.0002204312,0.000003272095],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001220642,"about_ca_system_score_gemma":0.000124935,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002551273,"about_ca_topic_score_gemma":0.00004782089,"domain_scores_codex":[0.9981263,0.00001462193,0.0005067927,0.0004387119,0.0004580922,0.0004554573],"domain_scores_gemma":[0.9979173,0.0005252364,0.0003353234,0.0008238112,0.0002571022,0.0001412614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006166005,0.0001054054,0.002399005,0.000253915,0.00009108995,7.349865e-7,0.00005229978,0.000004370248,0.9963944,0.0001045689,0.0004635937,0.0000689642],"study_design_scores_gemma":[0.001082927,0.000006980818,0.001399195,0.00004969987,0.00007450853,0.000009333837,0.0003784106,0.0005127491,0.9954641,0.0002847589,0.0004942057,0.0002430814],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892016,0.0005069187,0.007700368,0.00006205142,0.0001299231,0.0002336386,0.000494473,0.00004321044,0.001627807],"genre_scores_gemma":[0.9899783,0.00003143595,0.004966683,0.00006607209,0.0001982123,0.00004829795,0.0001199711,0.00004403943,0.004546992],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002919185,"threshold_uncertainty_score":0.8009702,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2084600364","doi":"10.1039/c4dt00591k","title":"The chemistry and applications of multimetallic salen complexes","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":166,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Magnetism; Catalysis; Combinatorial chemistry; Schiff base; Ligand (biochemistry); Metal; Coordination complex; Nanotechnology; Polymer chemistry; Materials science; Organic chemistry; Physics","authors":[{"name":"Ryan M. Clarke","is_ca":true},{"name":"Tim Storr","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01104891424483987,"gpt":0.2357863721984265,"spread":0.2247374579535866,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001704793,0.0001145164,0.0001408975,0.00001781358,0.0003210509,0.00002759538,0.0002060231,0.00007464571,0.001059176],"category_scores_gemma":[0.00002270701,0.00009525228,0.0000748724,0.0001242888,0.0001500811,0.00005828563,0.000007714544,0.0001461886,0.00003055318],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001505716,"about_ca_system_score_gemma":0.00001901001,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003237361,"about_ca_topic_score_gemma":0.00002475295,"domain_scores_codex":[0.9991947,0.00001791706,0.0002688987,0.0002014672,0.0001713549,0.0001455923],"domain_scores_gemma":[0.9990563,0.0002446664,0.000112742,0.0004350041,0.00007013382,0.00008114776],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008853362,0.00008267959,0.00001457167,0.0001665563,0.00007644775,7.979693e-8,0.000107144,0.00008100273,0.9415361,0.003564603,0.00003149379,0.05433044],"study_design_scores_gemma":[0.0004281247,0.000005542689,0.00008124661,0.00001130289,0.00008473973,0.00001205635,0.0002306158,0.004076581,0.8709366,0.001616058,0.1223668,0.0001502803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.05853013,0.0005751723,0.9070594,0.0006143978,0.00008740088,0.000351198,0.000401713,0.0002645094,0.03211607],"genre_scores_gemma":[0.9933065,0.0001399497,0.002540229,0.0000194333,0.00006325923,0.000178407,0.00008668873,0.00002290689,0.003642691],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9347763,"threshold_uncertainty_score":0.999854,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2006309936","doi":"10.1126/science.1098419","title":"The Radical Site in Chlamydial Ribonucleotide Reductase Defines a New R2 Subclass","year":2004,"lang":"en","type":"article","venue":"Science","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":156,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Manitoba; Health Canada","funders":"","keywords":"Ribonucleotide reductase; Deoxyribonucleotides; Chemistry; Ribonucleotide; Active site; Stereochemistry; Ligand (biochemistry); Biochemistry; Enzyme; Nucleotide; Receptor; Protein subunit; Gene","authors":[{"name":"Martin Högbom","is_ca":true},{"name":"Pål Stenmark","is_ca":true},{"name":"Nina Voevodskaya","is_ca":true},{"name":"Grant McClarty","is_ca":true},{"name":"Astrid Gräslund","is_ca":true},{"name":"P. Nordlund","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01304837282999138,"gpt":0.2503665539636509,"spread":0.2373181811336595,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008129022,0.0001253652,0.0001138383,0.00009249842,0.0003271842,0.0001592838,0.0007866014,0.00005344624,0.0002098739],"category_scores_gemma":[0.001038512,0.00009371935,0.00004931813,0.0008869785,0.0006111639,0.0002776163,0.0001495605,0.0002045166,0.0002702247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001887544,"about_ca_system_score_gemma":0.000773757,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001964976,"about_ca_topic_score_gemma":0.0002796172,"domain_scores_codex":[0.9981706,0.00001338708,0.0002601844,0.0004214415,0.000674408,0.0004599767],"domain_scores_gemma":[0.9990704,0.00006843382,0.00008491529,0.0004944768,0.00005243448,0.000229353],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001743742,0.00003416841,0.0001796332,0.000005887586,0.000001871483,0.00002362727,0.0003211875,0.0001737227,0.9784126,0.01786673,0.0001745057,0.002788681],"study_design_scores_gemma":[0.001023669,0.00001227315,0.001195779,0.00003271656,0.000006515522,0.00005367629,0.0001245689,0.0003860969,0.9636837,0.02397243,0.009287116,0.0002214766],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930066,0.000162295,0.0002958902,0.002747263,0.0003212,0.00007408889,0.00000843482,0.00006205511,0.003322211],"genre_scores_gemma":[0.9949791,0.00002670068,0.003393015,0.0001616268,0.0001801118,0.000009506588,0.000007464512,0.00001230077,0.001230131],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01472887,"threshold_uncertainty_score":0.3821765,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2043758058","doi":"10.1016/j.abb.2012.01.003","title":"The monooxygenase, peroxidase, and peroxygenase properties of cytochrome P450","year":2012,"lang":"en","type":"review","venue":"Archives of Biochemistry and Biophysics","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":147,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"Canadian Institutes of Health Research","keywords":"Monooxygenase; Chemistry; Peroxidase; Catalytic cycle; Cytochrome P450; Porphyrin; Ferric; Enzyme; Stereochemistry; Photochemistry; Biochemistry; Organic chemistry","authors":[{"name":"Eugene G. Hrycay","is_ca":true},{"name":"Stelvio M. Bandiera","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.03534268117281116,"gpt":0.2515539478741984,"spread":0.2162112667013873,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001555218,0.0005599199,0.00116338,0.0000524981,0.0001950694,0.00004214705,0.000506678,0.0002627602,0.00001891385],"category_scores_gemma":[0.00007393782,0.0003627728,0.0003969149,0.0001387679,0.0009993808,0.00007478903,0.0004128751,0.0003557905,0.000002746967],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001395072,"about_ca_system_score_gemma":0.0001319949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000878584,"about_ca_topic_score_gemma":4.358057e-7,"domain_scores_codex":[0.9980066,0.00005432023,0.0007989836,0.0004888349,0.0002866074,0.0003645909],"domain_scores_gemma":[0.9978615,0.0002700052,0.0008229474,0.0007988403,0.00005511241,0.0001916113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002148702,0.00008806588,4.382008e-7,0.03417378,0.0002597157,0.000001254301,0.0001329288,3.449948e-8,0.6369897,0.0002150612,0.000007309155,0.3281102],"study_design_scores_gemma":[0.0002367988,0.00002477095,0.000002212424,0.004884321,0.0007653523,0.00004196635,0.0002149412,0.00001380307,0.9314568,0.0002866978,0.06158261,0.0004897398],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.02404537,0.974503,0.0000122744,0.00001765706,0.00002695275,0.0002146217,0.0004668974,0.00002433747,0.0006889041],"genre_scores_gemma":[0.04084007,0.9575174,0.0003089363,0.000005238516,0.000210003,0.00006619678,0.0002416999,0.00005598385,0.0007544833],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.3276205,"threshold_uncertainty_score":0.9998824,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2069929526","doi":"10.1074/jbc.m106890200","title":"The Mechanism-based Inactivation of 2,3-Dihydroxybiphenyl 1,2-Dioxygenase by Catecholic Substrates","year":2002,"lang":"en","type":"article","venue":"Journal of Biological Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":125,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval; University of British Columbia","funders":"","keywords":"Dioxygenase; Chemistry; Substrate (aquarium); Stereochemistry; Enzyme; Reaction rate constant; Enzyme kinetics; Phosphonate; Active site; Kinetics; Organic chemistry","authors":[{"name":"Frédéric H. Vaillancourt","is_ca":true},{"name":"Geneviève Labbé","is_ca":true},{"name":"Nathalie M. Drouin","is_ca":true},{"name":"Pascal D. Fortin","is_ca":true},{"name":"Lindsay D. Eltis","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02976390468978725,"gpt":0.2361653634496661,"spread":0.2064014587598788,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000588153,0.0002492314,0.0003947554,0.00003251359,0.0001443424,0.00004506256,0.0006639016,0.0003620583,0.002476829],"category_scores_gemma":[0.0007235912,0.0001553175,0.0002799957,0.0002218924,0.0001535629,0.0001011143,0.00004654538,0.0005190503,0.00001095359],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001186798,"about_ca_system_score_gemma":0.00005472086,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003507942,"about_ca_topic_score_gemma":2.9501e-7,"domain_scores_codex":[0.9979708,0.00004862283,0.0009595096,0.0002281172,0.0004889288,0.0003040567],"domain_scores_gemma":[0.9975005,0.0003774562,0.00125439,0.0003626451,0.0003281794,0.0001768537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006708391,0.0002081082,0.00003226303,0.00005480923,0.00005882187,0.00001040551,0.00001851996,0.00002077659,0.9977044,0.0001575344,0.0007218863,0.0009453759],"study_design_scores_gemma":[0.0007155848,0.00006229717,0.00001164256,0.00004006335,0.00002304733,0.00006010643,0.0001522566,0.0006515332,0.9939741,0.002160558,0.001974165,0.0001746163],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995615,0.001035847,0.0007601894,0.000461694,0.0000683545,0.00005077358,0.00005103926,0.00003414123,0.001922955],"genre_scores_gemma":[0.9984357,0.0002825534,0.0005503541,0.00006136554,0.0001579691,0.000008620434,0.0000359254,0.00001856307,0.0004488923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003730286,"threshold_uncertainty_score":0.998435,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2018800405","doi":"10.1021/ja0174682","title":"Definitive Evidence for Monoanionic Binding of 2,3-Dihydroxybiphenyl to 2,3-Dihydroxybiphenyl 1,2-Dioxygenase from UV Resonance Raman Spectroscopy, UV/Vis Absorption Spectroscopy, and Crystallography","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":124,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"National Institute of General Medical Sciences","keywords":"Chemistry; Resonance Raman spectroscopy; Protonation; Crystallography; Absorption spectroscopy; Substrate (aquarium); Raman spectroscopy; Spectroscopy; Resonance (particle physics); Photochemistry; Stereochemistry; Organic chemistry","authors":[{"name":"Frédéric H. Vaillancourt","is_ca":true},{"name":"Christopher Barbosa","is_ca":true},{"name":"Thomas G. Spiro","is_ca":true},{"name":"Jeffrey T. Bolin","is_ca":true},{"name":"Michael W. Blades","is_ca":true},{"name":"Robin F. B. Turner","is_ca":true},{"name":"Lindsay D. Eltis","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.03146037254686007,"gpt":0.27738386412685,"spread":0.2459234915799899,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006195036,0.0004333931,0.0009289256,0.00009729251,0.0002141937,0.00008617106,0.0009215339,0.0001628696,0.0002991401],"category_scores_gemma":[0.0007927815,0.0003551402,0.001105889,0.0008333115,0.0004962268,0.0003531929,0.000268273,0.0006724929,0.000006101332],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004462995,"about_ca_system_score_gemma":0.00008899644,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008705388,"about_ca_topic_score_gemma":0.000004175149,"domain_scores_codex":[0.9967412,0.00008491459,0.001105171,0.000586469,0.0008907884,0.0005914981],"domain_scores_gemma":[0.9958343,0.0008966459,0.001988744,0.0006239694,0.0003109601,0.0003454117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002454694,0.0001607807,0.0005615107,0.00008016513,0.0002529196,0.000002386078,0.0007742228,0.00002230831,0.9949036,0.00007517749,0.002404586,0.0005168744],"study_design_scores_gemma":[0.001042483,0.0002044878,0.0004200066,0.0005082946,0.000210131,0.00003432259,0.0007641419,0.001432149,0.9927011,0.001841795,0.0004627307,0.00037843],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912723,0.001865949,0.004750725,0.001300851,0.0001398976,0.0002824809,0.0002293432,0.00003826469,0.000120244],"genre_scores_gemma":[0.9317411,0.001617027,0.06557306,0.0004555648,0.0004403588,0.00003057368,0.00001130245,0.00006792691,0.00006313656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06082233,"threshold_uncertainty_score":0.99989,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W384344890","doi":"10.1007/978-3-319-16009-2_1","title":"Monooxygenase, Peroxidase and Peroxygenase Properties and Reaction Mechanisms of Cytochrome P450 Enzymes","year":2015,"lang":"en","type":"review","venue":"Advances in experimental medicine and biology","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":123,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Monooxygenase; Photochemistry; Hydrogen atom abstraction; Peroxidase; Stereochemistry; Substrate (aquarium); Radical; Redox; Hydroxylation; Medicinal chemistry; Enzyme; Cytochrome P450; Organic chemistry","authors":[{"name":"Eugene G. Hrycay","is_ca":true},{"name":"Stelvio M. Bandiera","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.1084631902794954,"gpt":0.3733414397530293,"spread":0.2648782494735339,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003525631,0.0005212845,0.001719424,0.0002799751,0.00006163252,0.000008642584,0.0001590323,0.0003901765,0.0000763627],"category_scores_gemma":[0.0001368673,0.0003503113,0.00006447799,0.0001438056,0.0006243007,0.0002268142,0.0002030998,0.0002803743,0.000001963621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009068038,"about_ca_system_score_gemma":0.00005410855,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006617535,"about_ca_topic_score_gemma":0.00001123088,"domain_scores_codex":[0.9979007,0.0001233246,0.0008168691,0.0007081647,0.0001651236,0.0002857886],"domain_scores_gemma":[0.9988829,0.0001186937,0.0004683729,0.0002917659,0.00005624897,0.0001820389],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00008273842,0.0001254493,0.000002748412,0.007462618,0.00009328487,0.00002039305,0.0008664143,4.864517e-8,0.6182008,0.003498764,0.00003120162,0.3696156],"study_design_scores_gemma":[0.003191179,0.00145555,0.000002419487,0.01067388,0.0004548242,0.0007674518,0.01034998,0.00002931162,0.2067918,0.003353714,0.7617645,0.001165374],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.008173251,0.9907814,0.0000288107,0.00004196982,0.0001344349,0.0003939061,0.00005152932,0.00003109223,0.0003636633],"genre_scores_gemma":[0.02131913,0.9773419,0.0005237252,0.0000604804,0.000145225,0.0002193026,0.0002598121,0.00004057228,0.00008981858],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.7617334,"threshold_uncertainty_score":0.9998949,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2130881567","doi":"10.1042/bj20101286","title":"The crystal structure of human GLRX5: iron–sulfur cluster co-ordination, tetrameric assembly and monomer activity","year":2010,"lang":"en","type":"article","venue":"Biochemical Journal","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":120,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Canadian Institutes of Health Research; Vetenskapsrådet; Knut och Alice Wallenbergs Stiftelse; Karolinska Institutet; Cancerfonden; Stiftelsen för Strategisk Forskning; Ontario Genomics Institute; National Institute for Health and Care Research; Ontario Genomics; Genome Canada; GlaxoSmithKline; Ontario Innovation Trust; Wellcome Trust","keywords":"Glutaredoxin; Oxidoreductase; Chemistry; Cysteine; Glutathione; Biochemistry; Iron–sulfur cluster; Dithiol; Protein structure; Stereochemistry; Enzyme","authors":[{"name":"C. Johansson","is_ca":false},{"name":"A.K. Roos","is_ca":false},{"name":"Sergio Montaño","is_ca":false},{"name":"Rajib Sengupta","is_ca":false},{"name":"P. Filippakopoulos","is_ca":false},{"name":"Kunde Guo","is_ca":false},{"name":"Arne Holmgren","is_ca":false},{"name":"Udo Oppermann","is_ca":false},{"name":"K.L. Kavanagh","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.008621941812411386,"gpt":0.2617431034726313,"spread":0.2531211616602199,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00027975,0.0001912002,0.0002121777,0.0000576421,0.0003146427,0.00013752,0.0003488447,0.0002568101,0.0006354534],"category_scores_gemma":[0.0002562143,0.0001374659,0.0001063107,0.00009626587,0.0002096397,0.0001497547,0.00008702891,0.0009820227,0.000003290704],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004242981,"about_ca_system_score_gemma":0.00006222857,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005799591,"about_ca_topic_score_gemma":0.000004347919,"domain_scores_codex":[0.9986401,0.00003637988,0.0003700747,0.000229257,0.0004634328,0.0002607702],"domain_scores_gemma":[0.9987882,0.0001301803,0.0003960759,0.0003016198,0.0001808056,0.0002031469],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003115199,0.00004233749,0.0002899707,0.00002715415,0.00003868429,0.000001539533,0.00005272152,5.635836e-7,0.9964999,0.0002014874,0.001079814,0.001734705],"study_design_scores_gemma":[0.0006002336,0.00001904501,0.0009197912,0.00001072203,0.00003149669,0.0002131867,0.0000856449,0.00007858156,0.9955386,0.001067549,0.00127236,0.00016279],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981425,0.00007881975,0.0004624143,0.0002948455,0.0001695745,0.00005671379,0.00004654458,0.00001899644,0.0007296316],"genre_scores_gemma":[0.9980814,0.00001607872,0.001182261,0.00003398562,0.0003934142,0.000002364316,0.00002110678,0.00002448207,0.0002448507],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001571915,"threshold_uncertainty_score":0.6957769,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2755783525","doi":"10.1016/j.ccr.2017.08.019","title":"Electronic structure elucidation in oxidized metal–salen complexes","year":2017,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":118,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada; Mitacs","keywords":"Chemistry; Metal salen complexes; Transition metal; Electronic structure; Metal; Ligand (biochemistry); Redox; Combinatorial chemistry; Catalysis; Computational chemistry; Inorganic chemistry; Organic chemistry","authors":[{"name":"Ryan M. Clarke","is_ca":true},{"name":"Khrystyna Herasymchuk","is_ca":true},{"name":"Tim Storr","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.03206507532054292,"gpt":0.3015109244155688,"spread":0.2694458490950259,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007461079,0.0003721796,0.0006641877,0.000061115,0.0003336231,0.0002049576,0.0009874461,0.0002558437,0.007575942],"category_scores_gemma":[0.001474276,0.0003654382,0.000202586,0.0001591269,0.00008301918,0.0005244775,0.0001585912,0.0004425153,0.0001280303],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003365828,"about_ca_system_score_gemma":0.0001023365,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001953913,"about_ca_topic_score_gemma":0.00004057013,"domain_scores_codex":[0.9976355,0.00006187285,0.0008479384,0.0006368121,0.000372559,0.0004452956],"domain_scores_gemma":[0.9971486,0.00005137406,0.001090193,0.001432613,0.000163822,0.0001133364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000121818,0.00004443672,0.0001630195,0.0004830258,0.00002561147,0.000002352828,0.00003495149,0.000004493228,0.9874686,0.000724283,0.001053048,0.009984001],"study_design_scores_gemma":[0.0010581,0.000003758325,0.0001949897,0.0001283503,0.00004979037,0.00001525419,0.00002215293,0.0004236843,0.8040164,0.002230422,0.1915095,0.0003476685],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9373407,0.01065567,0.0020191,0.002146296,0.0003558977,0.001096904,0.0001900393,0.0003108859,0.04588449],"genre_scores_gemma":[0.988712,0.001096328,0.000769424,0.00007200345,0.0002373035,0.0001508063,0.001051961,0.00004780525,0.007862332],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1904564,"threshold_uncertainty_score":0.9998798,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2074532774","doi":"10.1016/s0969-2126(00)00536-0","title":"A Cluster Exposed","year":2000,"lang":"en","type":"article","venue":"Structure","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":107,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval; University of British Columbia","funders":"National Center for Research Resources; National Institute of General Medical Sciences","keywords":"Ferredoxin; Dioxygenase; Redox; Chemistry; Histidine; Crystallography; Iron–sulfur cluster; Oxidoreductase; Cluster (spacecraft); Protein subunit; Metalloprotein; Stereochemistry; Metal; Amino acid; Biochemistry; Inorganic chemistry","authors":[{"name":"Christopher L. Colbert","is_ca":false},{"name":"Manon Couture","is_ca":true},{"name":"Lindsay D. Eltis","is_ca":true},{"name":"Jeffrey T. Bolin","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.008411205780287397,"gpt":0.2185061780664667,"spread":0.2100949722861793,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00003066071,0.0001320911,0.0001166527,0.00002515974,0.00006187873,0.00003192862,0.0001994501,0.0001406287,0.160415],"category_scores_gemma":[0.00001947429,0.0001142776,0.00005853839,0.00008447233,0.00001992696,0.00007340677,0.0000198909,0.0001640214,0.0003205167],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002535969,"about_ca_system_score_gemma":0.00001892237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003892108,"about_ca_topic_score_gemma":0.000007384551,"domain_scores_codex":[0.9992105,0.00001079368,0.000150952,0.0002292726,0.000211863,0.000186643],"domain_scores_gemma":[0.9994668,0.00001500948,0.0000375768,0.0003802557,0.00002470159,0.00007562654],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004743689,0.00001273173,0.00004170301,0.00005320741,0.00004080868,0.00001295183,0.0004894017,0.00008298225,0.9396905,0.001148744,0.004284442,0.05409515],"study_design_scores_gemma":[0.0009107379,0.000006894081,0.0001138415,0.00001216735,0.00002196148,0.00005524551,0.00006774026,0.0003230936,0.884553,0.01116208,0.1025024,0.000270897],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9410444,0.00005392857,0.00007678843,0.0001629333,0.0001146306,0.00004990454,0.00009432928,0.0001329544,0.05827006],"genre_scores_gemma":[0.9765402,0.000004219382,0.002418972,0.0004254141,0.0002537501,0.000005230402,0.0001433654,0.00002598771,0.02018286],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1600944,"threshold_uncertainty_score":0.8403525,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2028840626","doi":"10.1021/ic100846b","title":"Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":105,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Concordia University","funders":"National Institute of General Medical Sciences","keywords":"Chemistry; Electron paramagnetic resonance; Crystallography; Azide; Ligand (biochemistry); Solvent; Extended X-ray absorption fine structure; Stereochemistry; Absorption spectroscopy; Nuclear magnetic resonance; Organic chemistry","authors":[{"name":"Ryan E. Cowley","is_ca":false},{"name":"Nathan J. DeYonker","is_ca":false},{"name":"N.A. Eckert","is_ca":false},{"name":"Thomas R. Cundari","is_ca":false},{"name":"Serena DeBeer","is_ca":false},{"name":"Eckhard Bill","is_ca":false},{"name":"Xavier Ottenwaelder","is_ca":true},{"name":"C.J. Flaschenriem","is_ca":false},{"name":"Patrick L. Holland","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.00804141791541739,"gpt":0.2234289515624602,"spread":0.2153875336470428,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001449516,0.000322578,0.0003712149,0.00004412566,0.0001232008,0.00005760222,0.0004358728,0.0003379568,0.007781574],"category_scores_gemma":[0.0000874644,0.0003294146,0.00008216525,0.0001427159,0.0001357178,0.0002303974,0.0001987351,0.0005681427,0.00001339594],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006575655,"about_ca_system_score_gemma":0.00007600575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004485583,"about_ca_topic_score_gemma":0.00007135501,"domain_scores_codex":[0.9982861,0.000005724618,0.0005485637,0.0004264907,0.0003930207,0.0003401522],"domain_scores_gemma":[0.9985735,0.00004905625,0.0004224764,0.0006671661,0.0001227983,0.0001649794],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002238511,0.00003621752,0.00006141709,0.0004124487,0.00002998426,0.00000672817,0.0001320199,2.829976e-7,0.9966886,0.002080777,0.00008370322,0.0004454527],"study_design_scores_gemma":[0.0009223081,0.000009825073,0.00007729481,0.00003149525,0.00005983086,0.0003871541,0.0001628078,0.0006850697,0.9809439,0.01624085,0.000170255,0.0003091942],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926535,0.00004705198,0.003548984,0.00006090178,0.000144376,0.00009874194,0.0001805488,0.0001148846,0.003151045],"genre_scores_gemma":[0.9953731,0.000009685758,0.003854282,0.00002544037,0.0002168957,0.000009079592,0.0002337775,0.00004745461,0.0002303419],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01574467,"threshold_uncertainty_score":0.9999158,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2330225447","doi":"10.1021/ar500242c","title":"Highly Selective but Multifunctional Oxygenases in Secondary Metabolism","year":2014,"lang":"en","type":"review","venue":"Accounts of Chemical Research","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":95,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Oxygenase; Monooxygenase; Dioxygenase; Chemistry; Enzyme; Substrate (aquarium); Oxidase test; Cytochrome P450; Biochemistry; Combinatorial chemistry; Stereochemistry; Biology","authors":[{"name":"Rachel V. K. Cochrane","is_ca":true},{"name":"John C. Vederas","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.08468150863882948,"gpt":0.3912722125194454,"spread":0.3065907038806159,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00218581,0.0006421134,0.002533358,0.0007448037,0.00007796063,0.0000818715,0.001656955,0.001214662,0.003828729],"category_scores_gemma":[0.006065933,0.0005701165,0.0006557276,0.001261348,0.0003632842,0.0002576443,0.0007039819,0.003238338,0.0005654171],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006569541,"about_ca_system_score_gemma":0.001692371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002098475,"about_ca_topic_score_gemma":0.0000105836,"domain_scores_codex":[0.9933006,0.0003213706,0.001573904,0.001211942,0.002581236,0.001010976],"domain_scores_gemma":[0.993565,0.003038216,0.0005442344,0.001092174,0.001471448,0.0002889161],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001291746,0.0005822212,0.000002337671,0.03359211,0.0006412671,0.00003103591,0.00005645657,4.863099e-7,0.08457619,0.002056004,0.007663384,0.8706693],"study_design_scores_gemma":[0.0006621746,0.00001037552,0.000002579862,0.002833113,0.0001380026,0.00002265958,0.00003047952,0.00001349991,0.1494684,0.001190476,0.8451411,0.0004871348],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.002556302,0.9818374,0.00001069298,0.00003410384,0.0001935637,0.0005735077,0.0007958908,0.00006676971,0.0139318],"genre_scores_gemma":[0.004097458,0.9891279,0.0006136551,0.00003648886,0.0008817358,0.0007064624,0.001782276,0.0001979658,0.002556029],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8701822,"threshold_uncertainty_score":0.999675,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2019283301","doi":"10.1021/ja0557785","title":"A Cobalt(III)−Salen Complex with an Axial Substituent in the Diamine Backbone:  Stereoselective Recognition of Amino Alcohols","year":2005,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":93,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Substituent; Diamine; Stereoselectivity; Cobalt; Steric effects; Stereochemistry; Polymer chemistry; Organic chemistry; Catalysis","authors":[{"name":"Hae-Jo Kim","is_ca":true},{"name":"Woo‐Sung Kim","is_ca":true},{"name":"Alan J. Lough","is_ca":true},{"name":"Byeong Moon Kim","is_ca":true},{"name":"Jik Chin","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.030154171204204,"gpt":0.2733144002375678,"spread":0.2431602290333638,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005794142,0.0001965761,0.0004665703,0.00002619367,0.00006411764,0.00002811479,0.0006998598,0.000069076,0.0001823179],"category_scores_gemma":[0.0001015992,0.0001126698,0.0003368713,0.0004774874,0.0004148545,0.0001792166,0.00006675664,0.0005953303,0.000003034983],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002816883,"about_ca_system_score_gemma":0.0001025285,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007720517,"about_ca_topic_score_gemma":0.00002514511,"domain_scores_codex":[0.9980583,0.0001155872,0.0006301781,0.0001948479,0.0007414737,0.0002596688],"domain_scores_gemma":[0.9977497,0.0002217454,0.001329216,0.0003317257,0.0002695114,0.00009807876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003604229,0.0004428594,0.0006160952,0.00002418456,0.0001594352,0.000002634057,0.001625055,0.00003363674,0.9907201,0.000017461,0.0006538107,0.005344299],"study_design_scores_gemma":[0.002411597,0.0001843705,0.003728233,0.00009509634,0.0001712021,0.000217172,0.003758673,0.0006240236,0.9877248,0.000306718,0.0005400982,0.0002379602],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998111,0.0000316676,0.0003456537,0.0009850434,0.00002639781,0.00012034,0.00004039049,0.000009488168,0.0003299957],"genre_scores_gemma":[0.989977,0.00004061694,0.008851431,0.0006800542,0.0003673035,0.000009259873,0.00002706362,0.00002108023,0.00002618493],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008505778,"threshold_uncertainty_score":0.4594543,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2084933460","doi":"10.1021/ja302072f","title":"PhnY and PhnZ Comprise a New Oxidative Pathway for Enzymatic Cleavage of a Carbon–Phosphorus Bond","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":91,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Gordon and Betty Moore Foundation","keywords":"Chemistry; Cleave; Enzyme; Dioxygenase; Bond cleavage; Phosphate; Hydrolysis; Cleavage (geology); Stereochemistry; Oxidative phosphorylation; Phosphorus; Histidine; Glycine; Amino acid; Carbon fibers; Biochemistry; Organic chemistry; Catalysis","authors":[{"name":"Fern R. McSorley","is_ca":true},{"name":"Peter B. Wyatt","is_ca":false},{"name":"Asunción Martínez Martínez","is_ca":false},{"name":"Edward F. DeLong","is_ca":false},{"name":"Bjarne Hove‐Jensen","is_ca":true},{"name":"David L. Zechel","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01628270265412805,"gpt":0.2516077532243815,"spread":0.2353250505702535,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004092305,0.0001825497,0.0005493034,0.000014436,0.00005131793,0.00001546262,0.0003802304,0.00007576183,0.00002549485],"category_scores_gemma":[0.0003357152,0.0001267467,0.0005223393,0.0001972196,0.0002579322,0.0001010871,0.0001432094,0.0003440506,6.547571e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001333361,"about_ca_system_score_gemma":0.0001144284,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003685761,"about_ca_topic_score_gemma":2.209811e-7,"domain_scores_codex":[0.9985824,0.00002492934,0.0005597648,0.0001298319,0.0004094126,0.0002936482],"domain_scores_gemma":[0.9975234,0.0003347393,0.001496272,0.0002671087,0.0001261127,0.0002524101],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000766048,0.0001312438,0.0004152341,0.00007373439,0.0002178936,2.540159e-7,0.001686081,5.373734e-7,0.9902107,0.00007941656,0.004926763,0.00218161],"study_design_scores_gemma":[0.0009125222,0.00003925047,0.0001586805,0.00006006672,0.0001500863,0.00003807563,0.001764346,0.0001489602,0.9943719,0.0006665162,0.001548137,0.0001414581],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975061,0.000693795,0.0008201825,0.0004029741,0.00008466352,0.0001008458,0.00003001044,0.00001001862,0.0003513826],"genre_scores_gemma":[0.9764624,0.0000749735,0.02267214,0.0002935296,0.0003049673,0.0000052399,0.000002771589,0.00002847527,0.0001554863],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02185196,"threshold_uncertainty_score":0.516858,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2097283231","doi":"10.1186/1471-2121-8-13","title":"The OXR domain defines a conserved family of eukaryotic oxidation resistance proteins","year":2007,"lang":"en","type":"article","venue":"BMC Cell Biology","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":90,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université du Québec à Trois-Rivières","funders":"National Cancer Institute; National Institutes of Health; Dana-Farber/Harvard Cancer Center","keywords":"Biology; Gene; Gene duplication; Phenotype; Oxidative stress; Mitochondrion; Function (biology); Oxidative phosphorylation; Cell biology; Genetics; Molecular biology; Biochemistry","authors":[{"name":"Mathieu Durand","is_ca":true},{"name":"Adrianne Kolpak","is_ca":false},{"name":"Timothy Farrell","is_ca":false},{"name":"Nathan A Elliott","is_ca":false},{"name":"Wenlin Shao","is_ca":false},{"name":"Myles Brown","is_ca":false},{"name":"Michael R. Volkert","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02183814724061749,"gpt":0.2444350439005617,"spread":0.2225968966599443,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009151963,0.000143673,0.0001945575,0.00005138571,0.0001247746,0.00001103655,0.0003154729,0.0001825846,0.0001375553],"category_scores_gemma":[0.0002812777,0.0001070686,0.00008124296,0.0001641931,0.0001656819,0.0000284678,0.00005913929,0.0001118216,0.00005329008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004043374,"about_ca_system_score_gemma":0.00009024575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003788143,"about_ca_topic_score_gemma":0.0005900607,"domain_scores_codex":[0.998729,0.00009168503,0.0004907153,0.0002711943,0.0001272959,0.0002901422],"domain_scores_gemma":[0.9984583,0.0005384436,0.0003485741,0.0004774805,0.0001257986,0.00005142719],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001396165,0.00003740707,0.001265364,0.0001022856,0.000012404,0.000001494005,0.00004899811,0.00000149671,0.9833035,0.01469353,0.00009769264,0.000296183],"study_design_scores_gemma":[0.0006039587,0.00002132476,0.00167276,0.00001434623,0.0000134495,0.00000191702,0.0003073299,0.00001747762,0.980267,0.007435469,0.009516854,0.000128077],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.957593,0.0007558392,0.02170743,0.00007628644,0.0001326612,0.0002210831,0.00002263973,0.00005235638,0.0194387],"genre_scores_gemma":[0.9793121,0.00004003657,0.01672018,0.00006036449,0.00006942738,0.00004021443,0.0001208538,0.00001876791,0.003618026],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02171912,"threshold_uncertainty_score":0.4366129,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2106381897","doi":"10.1128/mcb.20.23.9076-9083.2000","title":"Mutational and Structural Analyses of the Ribonucleotide Reductase Inhibitor Sml1 Define Its Rnr1 Interaction Domain Whose Inactivation Allows Suppression of <i>mec1</i> and <i>rad53</i> Lethality","year":2000,"lang":"en","type":"article","venue":"Molecular and Cellular Biology","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":88,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Columbia College","funders":"National Institute of General Medical Sciences; National Institutes of Health; Royal Swedish Academy of Sciences; Alexander and Margaret Stewart Trust","keywords":"Biology; Ribonucleotide reductase; Lethality; Genetics; Domain (mathematical analysis); Mutation; Molecular biology; Gene; Protein subunit","authors":[{"name":"Xiaolan Zhao","is_ca":true},{"name":"Bilyana Georgieva","is_ca":true},{"name":"Andrei Chabes","is_ca":false},{"name":"Vladimir Domkin","is_ca":false},{"name":"Hans Ippel","is_ca":false},{"name":"Jürgen Schleucher","is_ca":false},{"name":"Sybren S. Wijmenga","is_ca":false},{"name":"Lars Thelander","is_ca":false},{"name":"Rodney Rothstein","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01475880726265416,"gpt":0.2717232433119054,"spread":0.2569644360492513,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001679482,0.0001616891,0.0002451701,0.00005489363,0.00008380652,0.00001293048,0.0000850095,0.0001441145,0.000257708],"category_scores_gemma":[0.000074879,0.0001234961,0.00006570481,0.0001082004,0.000140708,0.00009160813,0.00007745403,0.000118483,5.732625e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002297348,"about_ca_system_score_gemma":0.0000214714,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001084085,"about_ca_topic_score_gemma":0.000006476508,"domain_scores_codex":[0.9988787,0.0001733813,0.0003693426,0.00030978,0.0001409574,0.0001278489],"domain_scores_gemma":[0.9993598,0.00005920866,0.0002397824,0.0002085273,0.00007680784,0.00005585869],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001087281,0.00002880805,0.0003621252,0.00008245944,0.00005407322,0.000003576662,0.0001382661,0.00003044065,0.9966427,0.0006960364,0.000009346973,0.001843454],"study_design_scores_gemma":[0.0006584666,0.00003708684,0.0004270423,0.00003346934,0.00006514946,0.00004232498,0.0001086004,0.0004147817,0.9948693,0.002998973,0.0002273241,0.000117501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980225,0.0008480612,0.0004464293,0.0001938549,0.0000613563,0.0001112539,0.0001014063,0.000009783414,0.0002053519],"genre_scores_gemma":[0.9987981,0.00004601646,0.0006721056,0.00005822987,0.00002692651,0.000006879312,0.0003220491,0.00001198285,0.00005769039],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002302936,"threshold_uncertainty_score":0.5036023,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2415681988","doi":"10.1039/c6cc03904a","title":"An iron–oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Canadian Institutes of Health Research","keywords":"Catalytic cycle; Cysteine; Dioxygenase; Catalysis; Chemistry; Oxygen; Enzyme; Absorption (acoustics); Photochemistry; Biochemistry; Organic chemistry; Materials science","authors":[{"name":"Egor P. Tchesnokov","is_ca":false},{"name":"Abayomi S. Faponle","is_ca":false},{"name":"Casey G. Davies","is_ca":false},{"name":"Matthew G. Quesne","is_ca":false},{"name":"Rufus Turner","is_ca":false},{"name":"Matthias Fellner","is_ca":false},{"name":"R.J. Souness","is_ca":false},{"name":"Sigurd M. Wilbanks","is_ca":false},{"name":"Sam P. de Visser","is_ca":false},{"name":"Guy N. L. Jameson","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01824797115976042,"gpt":0.2665251396593021,"spread":0.2482771684995417,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002430372,0.0001952439,0.0002455441,0.00005765138,0.0001890684,0.00002345279,0.002529522,0.0001248982,0.0003046684],"category_scores_gemma":[0.0004127953,0.0001246735,0.0001378806,0.0001942644,0.0004220308,0.0002361565,0.0006797074,0.000233317,0.00009999336],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001442722,"about_ca_system_score_gemma":0.00005411054,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002472933,"about_ca_topic_score_gemma":0.00002014764,"domain_scores_codex":[0.9985361,0.00005829092,0.0005661213,0.0002707438,0.0002766754,0.0002920453],"domain_scores_gemma":[0.9949965,0.0003992628,0.0002785026,0.004003895,0.000146016,0.0001757916],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001950253,0.0001467716,0.00006252903,0.00006755762,0.00003488319,6.029799e-7,0.0002766695,0.000001331815,0.9955502,0.001371558,0.00003293152,0.002435487],"study_design_scores_gemma":[0.0007861882,0.00001028521,0.0002424407,0.00007674892,0.00003947458,0.00001303095,0.000201808,0.0003574365,0.9955594,0.001673304,0.0008526887,0.0001871772],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946736,0.0002655406,0.0004270886,0.001042841,0.0000333662,0.0001432483,0.0002016646,0.0001317966,0.003080815],"genre_scores_gemma":[0.9977248,0.0001289579,0.001015532,0.0000419467,0.00006707322,0.0001324377,0.0002601078,0.00004142087,0.0005876723],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003733151,"threshold_uncertainty_score":0.5084038,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2963368358","doi":"10.1038/s41467-019-11214-9","title":"Acetylation regulates ribonucleotide reductase activity and cancer cell growth","year":2019,"lang":"en","type":"article","venue":"Nature Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":80,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"National Institute of Diabetes and Digestive and Kidney Diseases; National Cancer Institute; U.S. Department of Health and Human Services; School of Medicine, New York University; National Institutes of Health; Emory University; Winship Cancer Institute; York University","keywords":"Ribonucleotide reductase; Acetylation; DNA replication; SIRT2; Histone; DNA synthesis; DNA damage; Biochemistry; Deoxyribonucleoside; Biology; Chemistry; DNA; Cell biology; Protein subunit; Gene","authors":[{"name":"Guo Chen","is_ca":false},{"name":"Yin Luo","is_ca":false},{"name":"Kurt Warncke","is_ca":false},{"name":"Youwei Sun","is_ca":false},{"name":"David S. Yu","is_ca":false},{"name":"Haian Fu","is_ca":false},{"name":"Madhusmita Behera","is_ca":false},{"name":"Suresh S. Ramalingam","is_ca":false},{"name":"Paul W. Doetsch","is_ca":false},{"name":"Duc M. Duong","is_ca":false},{"name":"Michael Lammers","is_ca":false},{"name":"Walter J. Curran","is_ca":false},{"name":"Xingming Deng","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01321497628609096,"gpt":0.2725334132098693,"spread":0.2593184369237783,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001856586,0.0001581323,0.0001664444,0.00005040759,0.0002133223,0.00005127437,0.0006452281,0.0003172954,0.0009376116],"category_scores_gemma":[0.0001066213,0.0001620611,0.00005571233,0.0001851564,0.00007001132,0.0003474734,0.000347903,0.0007162572,0.00005340497],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001242658,"about_ca_system_score_gemma":0.00005747006,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002186067,"about_ca_topic_score_gemma":0.0003337283,"domain_scores_codex":[0.9991059,0.0000639902,0.0001814734,0.0002817187,0.00020231,0.0001646643],"domain_scores_gemma":[0.9975839,0.0002013521,0.0001926493,0.001747562,0.0001897016,0.00008483278],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001356279,0.00009108243,0.0009724313,0.00006300506,0.00003092966,1.818158e-7,0.0001812586,0.000006884718,0.9823152,0.01361316,0.0009576619,0.00175464],"study_design_scores_gemma":[0.0005760048,0.000007430251,0.003428924,0.00004306823,0.00006449,0.00000559202,0.0001613426,0.002591549,0.9756894,0.001406742,0.01573433,0.0002911201],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9631549,0.007655952,0.00002578194,0.002971644,0.000155193,0.0002059247,0.0001519587,0.0001557266,0.02552295],"genre_scores_gemma":[0.990126,0.00194461,0.005340216,0.000115688,0.00004436406,0.00004652368,0.0002789006,0.0000307413,0.00207293],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02697116,"threshold_uncertainty_score":0.9999757,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2329486597","doi":"10.1021/ic3018503","title":"New Insights into the Electronic Structure and Reactivity of One-Electron Oxidized Copper(II)-(Disalicylidene)diamine Complexes","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Reactivity (psychology); Electron paramagnetic resonance; Ligand (biochemistry); Moiety; Diamine; Copper; Crystallography; Redox; Cyclic voltammetry; Benzyl alcohol; Benzaldehyde; Corrole; Oxidation state; Nitrosobenzene; Photochemistry; Metal; Stereochemistry; Inorganic chemistry; Electrochemistry; Polymer chemistry; Physical chemistry; Nuclear magnetic resonance; Organic chemistry; Catalysis","authors":[{"name":"Kazutaka Asami","is_ca":false},{"name":"K. Tsukidate","is_ca":false},{"name":"Satoshi Iwatsuki","is_ca":false},{"name":"Fumito Tani","is_ca":false},{"name":"Satoru Karasawa","is_ca":false},{"name":"Linus Chiang","is_ca":true},{"name":"Tim Storr","is_ca":true},{"name":"Fabrice Thomas","is_ca":false},{"name":"Yuichi Shimazaki","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.009966810816933023,"gpt":0.2337672021325682,"spread":0.2238003913156352,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000201953,0.0003831867,0.0004786279,0.00003325527,0.0002283846,0.00003682703,0.0005240979,0.0003247962,0.002014523],"category_scores_gemma":[0.0002505068,0.0003204848,0.0001020898,0.0002980325,0.0001300378,0.0002455369,0.000307814,0.0006320319,0.00000889193],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002753412,"about_ca_system_score_gemma":0.0002955564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002384643,"about_ca_topic_score_gemma":0.00009069359,"domain_scores_codex":[0.997934,0.00003882335,0.000473626,0.0004424134,0.0004932482,0.000617862],"domain_scores_gemma":[0.9982301,0.0001715373,0.0003801757,0.000872856,0.00009482376,0.0002505089],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004436537,0.0000923242,0.0001909782,0.0001814011,0.0001374351,5.29432e-7,0.001461774,5.682568e-7,0.9959843,0.001013773,0.0003429775,0.0005496386],"study_design_scores_gemma":[0.0008990724,0.00002075837,0.0002740808,0.00003140694,0.0001247824,0.00005309945,0.0001910883,0.00001353664,0.989821,0.003517772,0.004725692,0.0003277465],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945264,0.003584801,0.0001147009,0.0003047117,0.0000592855,0.000115694,0.00001931259,0.0001015225,0.001173559],"genre_scores_gemma":[0.9974583,0.0001836156,0.000328337,0.00007544503,0.0004814864,0.000009755263,0.0001679368,0.00006362837,0.001231538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00616327,"threshold_uncertainty_score":0.9999247,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2728982395","doi":"10.1021/acs.joc.7b01069","title":"Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp<sup>3</sup> C–H Bonds","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Hewitt Foundation; National Institute of General Medical Sciences; Agency for Science, Technology and Research; Welch Foundation","keywords":"Intramolecular force; Decoding methods; Hydroxylation; Mechanism (biology); Chemistry; Stereochemistry; Bond; Computer science; Physics; Biochemistry; Algorithm; Enzyme; Business","authors":[{"name":"Rachel Trammell","is_ca":false},{"name":"Yi Yang See","is_ca":false},{"name":"Aaron T. Herrmann","is_ca":false},{"name":"Nan Xie","is_ca":false},{"name":"Daniel E. Díaz","is_ca":false},{"name":"Maxime A. Siegler","is_ca":false},{"name":"Phil S. Baran","is_ca":false},{"name":"Isaac Garcia‐Bosch","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01356834755229814,"gpt":0.2381807862953156,"spread":0.2246124387430174,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001445066,0.0002319636,0.0004450565,0.00003763139,0.0002890365,0.00005165218,0.001675208,0.00019934,0.002973407],"category_scores_gemma":[0.001321693,0.0001545989,0.0002043761,0.0001357325,0.0001716783,0.0001716731,0.0002420667,0.0005523955,0.000006221077],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009793037,"about_ca_system_score_gemma":0.0001922656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001142038,"about_ca_topic_score_gemma":0.000001284357,"domain_scores_codex":[0.9978507,0.00005869094,0.0009581649,0.000155129,0.0007430722,0.0002342405],"domain_scores_gemma":[0.9954607,0.0002087791,0.002568413,0.001216971,0.0004453474,0.00009978853],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006163843,0.00005696369,0.00003180616,0.0001462485,0.0002166943,0.000008021531,0.0005532756,0.00009757689,0.9980955,0.0001946704,0.00009879259,0.0004388572],"study_design_scores_gemma":[0.0007702358,0.00001916303,0.00003287322,0.0001542585,0.000304894,0.0003130208,0.0005687108,0.003578901,0.9905337,0.003503002,0.00007844293,0.0001427623],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992187,0.000284183,0.003361082,0.0004400001,0.00007800992,0.00006371288,0.00001579739,0.00002330155,0.003546918],"genre_scores_gemma":[0.9983487,0.0001366212,0.000790386,0.00002090852,0.0002471488,0.000001207078,0.000008495818,0.00004436055,0.0004022117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007561719,"threshold_uncertainty_score":0.997938,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2061872781","doi":"10.1021/jp810715t","title":"A DFT Study of Nucleobase Dealkylation by the DNA Repair Enzyme AlkB","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nucleobase; AlkB; Ferric; Ligand (biochemistry); Alkylation; Catalysis; Photochemistry; Oxygen; Density functional theory; Stereochemistry; DNA; Computational chemistry; DNA repair; Inorganic chemistry; Organic chemistry; Biochemistry","authors":[{"name":"Haining Liu","is_ca":true},{"name":"Jorge Llano","is_ca":true},{"name":"James W. Gauld","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01221365932551938,"gpt":0.2547797152992521,"spread":0.2425660559737327,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006177978,0.0001886718,0.0003209393,0.00001399399,0.0001177794,0.00001980692,0.0006424769,0.00006479795,0.0002794859],"category_scores_gemma":[0.0002064764,0.0001087649,0.0002516624,0.0001809696,0.00006496414,0.0001174541,0.0000524989,0.0004729411,0.000007037709],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006223882,"about_ca_system_score_gemma":0.00004962485,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007653248,"about_ca_topic_score_gemma":5.385679e-7,"domain_scores_codex":[0.998257,0.00007779547,0.000575394,0.0001390237,0.000765754,0.000185011],"domain_scores_gemma":[0.9980299,0.0002631781,0.0008149524,0.0005696879,0.0002192489,0.0001029924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000131517,0.001017776,0.00001035199,0.00002954584,0.000107502,0.000005322658,0.00110075,0.0001977522,0.9948909,0.00004531482,0.001730242,0.000733049],"study_design_scores_gemma":[0.0009292336,0.0001492706,0.0000705007,0.00003167211,0.0002285883,0.00005014227,0.001447989,0.001419323,0.9940966,0.0009967301,0.0004630479,0.0001168974],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969131,0.0001026558,0.000109906,0.0003782045,0.00001974662,0.00007795898,0.00001461063,0.00002863914,0.002355205],"genre_scores_gemma":[0.9989333,0.000005904034,0.00004382221,0.00006770232,0.0004395497,0.000001891423,0.00000694573,0.00001653929,0.0004843326],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00202024,"threshold_uncertainty_score":0.4435305,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2555515524","doi":"10.1021/jacs.6b09576","title":"Tuning Electronic Structure To Control Manganese Nitride Activation","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; Compute Canada","keywords":"Chemistry; Substituent; Nitride; Manganese; Ligand (biochemistry); Ring (chemistry); Polar effect; Activation energy; Photochemistry; Medicinal chemistry; Organic chemistry; Receptor; Layer (electronics)","authors":[{"name":"Ryan M. Clarke","is_ca":true},{"name":"Tim Storr","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.006029117129812291,"gpt":0.2317065765602287,"spread":0.2256774594304164,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002387907,0.0001520895,0.00030753,0.00002001256,0.00007213057,0.00002237957,0.0005526747,0.00006681694,0.0002893543],"category_scores_gemma":[0.0004896693,0.00008156214,0.0004189106,0.0002724912,0.00009741961,0.0001189277,0.00007290069,0.0004102227,0.000005557128],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005194838,"about_ca_system_score_gemma":0.0001178093,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007491074,"about_ca_topic_score_gemma":4.195336e-7,"domain_scores_codex":[0.998634,0.00003352489,0.0003614095,0.0001547787,0.0005034389,0.0003127898],"domain_scores_gemma":[0.9983602,0.0002237558,0.0008088885,0.0002799444,0.000186227,0.0001410214],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007236037,0.00001788833,0.0001778611,0.000006931936,0.0001333161,5.001052e-7,0.0000995446,0.00001387649,0.9939727,0.00005719636,0.0019277,0.003520174],"study_design_scores_gemma":[0.0007449842,0.00002193521,0.0001417761,0.00004766829,0.00005150499,0.00004317793,0.0001717975,0.00004514796,0.994487,0.001309814,0.002812018,0.0001231234],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9868032,0.00001757337,0.007452058,0.005537226,0.0000554937,0.00004770002,0.00001658221,0.00001817584,0.0000520283],"genre_scores_gemma":[0.9957073,0.00001388568,0.001692652,0.001913966,0.0004319741,0.000002423479,0.000001296262,0.0000244166,0.0002120375],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008904186,"threshold_uncertainty_score":0.3326007,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2078884613","doi":"10.1021/ic9002466","title":"Effects of Electron-Deficient β-Diketiminate and Formazan Supporting Ligands on Copper(I)-Mediated Dioxygen Activation","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":74,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"National Institute of General Medical Sciences","keywords":"Chemistry; Electron paramagnetic resonance; Copper; Formazan; Cyclic voltammetry; Aryl; Ligand (biochemistry); Resonance Raman spectroscopy; Density functional theory; Raman spectroscopy; Crystallography; Photochemistry; Inorganic chemistry; Medicinal chemistry; Alkyl; Stereochemistry; Electrochemistry; Physical chemistry; Organic chemistry; Nuclear magnetic resonance; Computational chemistry; Electrode","authors":[{"name":"Sungjun Hong","is_ca":true},{"name":"Lyndal M. R. Hill","is_ca":true},{"name":"Aalo K. Gupta","is_ca":true},{"name":"Benjamin D. Naab","is_ca":true},{"name":"Joe B. Gilroy","is_ca":true},{"name":"Robin G. Hicks","is_ca":true},{"name":"Christopher J. Cramer","is_ca":true},{"name":"William B. Tolman","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.004703296486603944,"gpt":0.2221502722057608,"spread":0.2174469757191568,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002251077,0.000293304,0.0003337081,0.00005388649,0.00009594253,0.00003271495,0.0002395384,0.0002555632,0.0002266276],"category_scores_gemma":[0.0006004098,0.0002988409,0.0000805677,0.0002485931,0.00004038568,0.0001131414,0.00005752696,0.000323242,0.00001495055],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001492704,"about_ca_system_score_gemma":0.00008578207,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003340417,"about_ca_topic_score_gemma":2.361617e-7,"domain_scores_codex":[0.9981963,0.00000986195,0.000506425,0.0004321649,0.0004320914,0.000423159],"domain_scores_gemma":[0.9987388,0.0001963859,0.0004283147,0.0003772433,0.00010342,0.000155836],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005588251,0.000162362,0.00003706437,0.0004415284,0.00003133565,0.0000061821,0.0002378264,0.000003667493,0.9978057,0.00008634199,0.0001530499,0.0009791066],"study_design_scores_gemma":[0.001047639,0.00006719535,0.0003010166,0.0001266699,0.00004398251,0.0000198321,0.00009905453,0.0002211529,0.9974447,0.0001998317,0.0001523282,0.0002765487],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995003,0.0000897083,0.00007106033,0.0002281719,0.00003902904,0.0001215828,0.00001540002,0.0001327756,0.004299297],"genre_scores_gemma":[0.9989593,0.00003832722,0.00007427898,0.0001384585,0.000110899,0.00001270685,0.0002181329,0.00003497691,0.0004129138],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003956331,"threshold_uncertainty_score":0.9999464,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1971581101","doi":"10.1021/bi011047f","title":"Kinetic Analysis of Product Inhibition in Human Manganese Superoxide Dismutase","year":2001,"lang":"en","type":"article","venue":"Biochemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":73,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Waterloo","funders":"National Institute of General Medical Sciences; National Heart, Lung, and Blood Institute","keywords":"Chemistry; Superoxide; Hydrogen peroxide; Disproportionation; Active site; Photochemistry; Catalysis; Superoxide dismutase; Reaction rate constant; Reactive oxygen species; Stereochemistry; Enzyme; Kinetics; Biochemistry","authors":[{"name":"Amy S. Hearn","is_ca":true},{"name":"M. Elizabeth Stroupe","is_ca":true},{"name":"Diane E. Cabelli","is_ca":true},{"name":"James R. Lepock","is_ca":true},{"name":"John A. Tainer","is_ca":true},{"name":"Harry S. Nick","is_ca":true},{"name":"David N. Silverman","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01411515988111664,"gpt":0.2555376867354163,"spread":0.2414225268542997,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000198894,0.0001999385,0.0003376515,0.000231962,0.00003781755,0.00001723197,0.000163205,0.0001378651,0.00229947],"category_scores_gemma":[0.0001375238,0.0002147277,0.0001728238,0.001034878,0.00006749496,0.00006525497,0.00006712278,0.0001526445,0.00001114688],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000995474,"about_ca_system_score_gemma":0.00003083804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001114631,"about_ca_topic_score_gemma":0.00003327269,"domain_scores_codex":[0.9984176,0.00001744114,0.0005114029,0.0004737109,0.0003347672,0.0002451059],"domain_scores_gemma":[0.9989239,0.00002577612,0.0001749484,0.0006970286,0.00008390247,0.00009442671],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001779159,0.0002044248,0.003259534,0.000159235,0.0001276629,0.00006158691,0.00007085544,0.00008100554,0.995727,0.00007385659,0.00006326243,0.000153754],"study_design_scores_gemma":[0.0004424354,0.000004842649,0.001305722,0.0000418711,0.0002533167,0.0000174448,0.0001637807,0.0002372518,0.9971225,0.0001046479,0.00009320807,0.0002130007],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995962,0.0001957974,0.00005312177,0.00005638916,0.00001850275,0.00005876201,0.00009168509,0.00005290808,0.003510794],"genre_scores_gemma":[0.9964979,0.00001807323,0.000194565,0.00001771878,0.00008128482,0.00002996474,0.001621088,0.00002188323,0.001517535],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002288324,"threshold_uncertainty_score":0.9986126,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2900230500","doi":"10.1021/jacs.8b07726","title":"Oxygen–Oxygen Bond Cleavage and Formation in Co(II)-Mediated Stoichiometric O <sub>2</sub> Reduction via the Potential Intermediacy of a Co(IV) Oxyl Radical","year":2018,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":71,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Calgary","funders":"Social Sciences and Humanities Research Council of Canada; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canadian Institutes of Health Research; Alberta Innovates - Technology Futures","keywords":"Chemistry; Protonation; Catalysis; Bond cleavage; Stoichiometry; Photochemistry; Oxygen; Reagent; Cobalt; Dimer; Reaction intermediate; Reactive intermediate; Kinetic isotope effect; Inorganic chemistry; Organic chemistry; Ion","authors":[{"name":"Lucie Nurdin","is_ca":true},{"name":"Denis M. Spasyuk","is_ca":true},{"name":"Laura Fairburn","is_ca":true},{"name":"Warren E. Piers","is_ca":true},{"name":"Laurent Maron","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.00848646914921563,"gpt":0.2427452842567058,"spread":0.2342588151074902,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009169286,0.0002314579,0.000516074,0.0001374585,0.0001868205,0.00003830844,0.0006251776,0.0001605625,0.00004639903],"category_scores_gemma":[0.0005348544,0.0001523998,0.0004513263,0.001187866,0.001249027,0.0002779943,0.0002085377,0.0008097971,0.0000056309],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003106794,"about_ca_system_score_gemma":0.00009596344,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001777329,"about_ca_topic_score_gemma":0.000001036606,"domain_scores_codex":[0.9974595,0.0001060205,0.0009956351,0.0002288184,0.0008771716,0.0003328373],"domain_scores_gemma":[0.9972353,0.0001896805,0.001823919,0.000350358,0.0002312421,0.0001694829],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001784907,0.0001470401,0.00005958464,0.00004170327,0.0001270711,0.0000018967,0.001292619,0.00000248368,0.9847685,0.000005751234,0.007872171,0.005502691],"study_design_scores_gemma":[0.00114752,0.0001113483,0.001028428,0.000056048,0.00009546801,0.0003565795,0.0015053,0.001511298,0.9933675,0.0002937464,0.0003656515,0.0001611059],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972296,0.0001180407,0.001131465,0.001046146,0.0001895673,0.0001305674,0.0000307765,0.00001689158,0.0001069037],"genre_scores_gemma":[0.9977735,0.0002598692,0.001052661,0.0002731708,0.0005688171,0.000006117998,0.0000242725,0.00002926738,0.00001236551],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008599008,"threshold_uncertainty_score":0.6214683,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2041684847","doi":"10.1021/bi400665t","title":"Characterizing the Promiscuity of LigAB, a Lignin Catabolite Degrading Extradiol Dioxygenase from <i>Sphingomonas paucimobilis</i> SYK-6","year":2013,"lang":"en","type":"article","venue":"Biochemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"National Institute of General Medical Sciences; University of British Columbia","keywords":"Sphingomonas paucimobilis; Enzyme kinetics; Chemistry; Stereochemistry; Dioxygenase; Methyl gallate; Enzyme; Active site; Substrate (aquarium); Biochemistry; Gallic acid; Biology; Bacteria","authors":[{"name":"Kevin P. Barry","is_ca":false},{"name":"Erika A. Taylor","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01233063711137837,"gpt":0.2123185840763578,"spread":0.1999879469649794,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003732884,0.0004792358,0.0005179532,0.00004391508,0.0002087085,0.0001463189,0.001039079,0.0003414193,0.001299779],"category_scores_gemma":[0.0003741349,0.0003792123,0.0002908607,0.0002540227,0.0001813513,0.0002604384,0.0002528034,0.0004797955,0.0001093573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001235731,"about_ca_system_score_gemma":0.0001554938,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004765999,"about_ca_topic_score_gemma":0.000003147178,"domain_scores_codex":[0.9971743,0.000044907,0.0008341132,0.000790588,0.0005871388,0.0005689731],"domain_scores_gemma":[0.9971585,0.0002426835,0.0005878812,0.001521557,0.0001943173,0.0002951128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001303026,0.0001196609,0.0003886364,0.0002651473,0.0001091456,0.000006484255,0.0004983371,6.021658e-7,0.9958793,0.00005210544,0.0007920699,0.001875472],"study_design_scores_gemma":[0.0004914418,0.00000729314,0.000448842,0.0001950319,0.00006223291,0.00002217846,0.0005429196,0.0002529362,0.9959636,0.0003589626,0.001227078,0.0004274829],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943029,0.001311439,0.00006675091,0.0002815384,0.0001444857,0.0003203857,0.0004510709,0.0001776487,0.002943834],"genre_scores_gemma":[0.9959848,0.00007082276,0.000943745,0.0001670809,0.0005760564,0.0003373496,0.0006866378,0.00007827133,0.001155246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001788588,"threshold_uncertainty_score":0.999866,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2420061576","doi":"10.1021/acs.inorgchem.5b01297","title":"A Biomimetic Mechanism for the Copper-Catalyzed Aerobic Oxygenation of 4-<i>tert</i>-Butylphenol","year":2015,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University; Concordia University","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Chemistry; Catalysis; Catalytic cycle; Phenols; Photochemistry; Ligand (biochemistry); Chemoselectivity; Selectivity; Reaction mechanism; Turnover number; Combinatorial chemistry; Oxygenation; Medicinal chemistry; Organic chemistry; Receptor; Biochemistry","authors":[{"name":"Mohammad S. Askari","is_ca":true},{"name":"Kenneth Virgel N. Esguerra","is_ca":true},{"name":"Jean‐Philip Lumb","is_ca":true},{"name":"Xavier Ottenwaelder","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02905460819824625,"gpt":0.2498053902601257,"spread":0.2207507820618794,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005581633,0.0003836065,0.0004339376,0.00005043981,0.0001454214,0.00006260417,0.0009827679,0.000335776,0.001132922],"category_scores_gemma":[0.0007576111,0.0003217611,0.0002364392,0.0003779644,0.0001192833,0.0001406072,0.0002087004,0.0002459941,0.00008805402],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002501778,"about_ca_system_score_gemma":0.0003079157,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004899459,"about_ca_topic_score_gemma":0.00000740121,"domain_scores_codex":[0.9975489,0.00001907186,0.0007600615,0.0005658393,0.0006576683,0.0004485062],"domain_scores_gemma":[0.9972098,0.0002752255,0.0005252547,0.00115917,0.0005933274,0.0002372173],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005218255,0.0001144893,0.00001074595,0.0003082624,0.0001785359,0.000001944648,0.0003550079,0.000008473448,0.9963702,0.001188648,0.0008114089,0.0006000872],"study_design_scores_gemma":[0.002280507,0.00001527659,0.000002749534,0.00004441571,0.0002192951,0.00005929338,0.001083348,0.001625091,0.9885955,0.004505313,0.001225304,0.0003439151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762957,0.0007432969,0.0165522,0.001002502,0.0005360161,0.0006651299,0.0003095299,0.0003492111,0.003546393],"genre_scores_gemma":[0.9941597,0.00002675242,0.00259533,0.0001155132,0.0002937235,0.0001962172,0.0003788986,0.00009842506,0.002135413],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01786401,"threshold_uncertainty_score":0.9999235,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1986431620","doi":"10.1002/chem.201001401","title":"Ligand Radical Localization in a Nonsymmetric One‐Electron Oxidized Ni<sup>II</sup> Bis‐phenoxide Complex","year":2010,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"National Institute of General Medical Sciences","keywords":"Delocalized electron; Ligand (biochemistry); Chemistry; Radical ion; Electron delocalization; Photochemistry; Crystallography; Stereochemistry; Organic chemistry; Ion; Receptor","authors":[{"name":"Tim Storr","is_ca":true},{"name":"Pratik Verma","is_ca":false},{"name":"Yuichi Shimazaki","is_ca":false},{"name":"Erik C. Wasinger","is_ca":false},{"name":"T. Daniel P. Stack","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01998361948965233,"gpt":0.2351714827726325,"spread":0.2151878632829802,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001638496,0.0004883052,0.0005332307,0.0002696209,0.0004680162,0.000277973,0.001002712,0.0002249826,0.004508338],"category_scores_gemma":[0.001235372,0.0005097408,0.000227788,0.0009210434,0.0001752191,0.0002410526,0.0002534136,0.002297312,0.0001661793],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002355042,"about_ca_system_score_gemma":0.0002851041,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006265844,"about_ca_topic_score_gemma":0.000002783324,"domain_scores_codex":[0.996266,0.0001857175,0.001204543,0.0006584525,0.0008693073,0.0008159482],"domain_scores_gemma":[0.9977264,0.000102038,0.0005904469,0.0007014404,0.0002437706,0.0006358732],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001063716,0.0003677921,0.0001233728,0.0001183902,0.00006951377,0.0002690803,0.000314268,0.0002791184,0.9948561,0.00004257262,0.002033209,0.00142028],"study_design_scores_gemma":[0.005097766,0.00004341432,0.0001400737,0.0001458246,0.00009019693,0.001667745,0.0002367631,0.01634748,0.9422301,0.0002242313,0.03304419,0.0007322232],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9803875,0.0001592834,0.003009683,0.000310681,0.0001220148,0.0001023941,0.00002175531,0.0001537146,0.01573293],"genre_scores_gemma":[0.9922397,0.00008362131,0.003798119,0.0002087748,0.001081904,0.000007872041,0.000231444,0.0001538812,0.002194745],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05262593,"threshold_uncertainty_score":0.9997354,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W3180875629","doi":"10.1038/s41557-021-00732-z","title":"Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen","year":2021,"lang":"en","type":"article","venue":"Nature Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Basic Energy Sciences; Andlinger Center for Energy and the Environment, Princeton University; Office of Science; Samsung; Canadian Institute for Advanced Research; Princeton University; U.S. Department of Energy","keywords":"Chemistry; Catalysis; Hydrogen bond; Photochemistry; Visible spectrum; Hydrogen; Chemical bond; Molecule; Chemical physics; Combinatorial chemistry; Nanotechnology; Organic chemistry; Optoelectronics","authors":[{"name":"Yoonsu Park","is_ca":false},{"name":"Sangmin Kim","is_ca":false},{"name":"Lei Tian","is_ca":false},{"name":"Hongyu Zhong","is_ca":false},{"name":"Gregory D. Scholes","is_ca":false},{"name":"Paul J. Chirik","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.004351840736495046,"gpt":0.2124074782809203,"spread":0.2080556375444252,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001157676,0.0002972923,0.0003597301,0.00003462021,0.00004989055,0.00003806263,0.0003709079,0.0007323212,0.001089751],"category_scores_gemma":[0.0002230895,0.0002806388,0.000134197,0.0004115973,0.00005017405,0.00018525,0.0001322316,0.0007005584,0.00001852432],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001318597,"about_ca_system_score_gemma":0.0002205632,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001891829,"about_ca_topic_score_gemma":9.638029e-7,"domain_scores_codex":[0.9980834,0.00000940777,0.0004170352,0.0004837092,0.0006751298,0.0003312809],"domain_scores_gemma":[0.9983326,0.0000386934,0.0002714308,0.0008208986,0.0003736513,0.000162698],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003060289,0.00009932059,0.00001105192,0.0009747546,0.00008270583,0.0000710021,0.00005629832,0.00003074442,0.9976723,0.000300317,0.0005046618,0.0001662638],"study_design_scores_gemma":[0.0007358741,0.000004823399,6.505211e-7,0.0001484439,0.0001024166,0.0002837632,0.0001952576,0.0002891115,0.9925283,0.0004222408,0.004979614,0.0003095315],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9142676,0.002365588,0.0005017563,0.0003906493,0.00003433559,0.0000710882,0.00009068921,0.0001353588,0.08214293],"genre_scores_gemma":[0.9935519,0.00002061334,0.001874924,0.00008391501,0.0001084996,0.00002491739,0.001372705,0.00005353436,0.002908992],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0792843,"threshold_uncertainty_score":0.9999646,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W3012761025","doi":"10.1021/acs.inorgchem.0c00381","title":"Effect of Distortions on the Geometric and Electronic Structures of One-Electron Oxidized Vanadium(IV), Copper(II), and Cobalt(II)/(III) Salen Complexes","year":2020,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada; Agence Nationale de la Recherche; LABoratoires d’EXcellence ARCANE","keywords":"Chemistry; Crystallography; Square pyramidal molecular geometry; Vanadium; Denticity; Octahedron; Molecule; Ligand (biochemistry); Electron paramagnetic resonance; Octahedral molecular geometry; Crystal structure; Coordination sphere; Transition metal; Coordination geometry; Diamine; Cobalt; Inorganic chemistry; Nuclear magnetic resonance; Hydrogen bond","authors":[{"name":"Hussein Kanso","is_ca":false},{"name":"Ryan M. Clarke","is_ca":true},{"name":"Amélie Kochem","is_ca":false},{"name":"Himanshu Arora","is_ca":false},{"name":"Christian Philouze","is_ca":false},{"name":"Olivier Jarjayes","is_ca":false},{"name":"Tim Storr","is_ca":true},{"name":"Fabrice Thomas","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.009784521052286518,"gpt":0.2248096306927617,"spread":0.2150251096404752,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000278105,0.0003436775,0.0006024561,0.00005684368,0.0002554581,0.00002309016,0.000420408,0.0002073317,0.001372948],"category_scores_gemma":[0.0006618851,0.0002842216,0.0001120088,0.0005439929,0.0002187305,0.00005688301,0.0002513615,0.000489993,0.000002253662],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001468472,"about_ca_system_score_gemma":0.0001410104,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005662643,"about_ca_topic_score_gemma":0.00001250946,"domain_scores_codex":[0.9980652,0.00005210803,0.0005220198,0.0004997248,0.0004547738,0.0004061286],"domain_scores_gemma":[0.9983461,0.0004679737,0.0004107967,0.0004973941,0.00008697421,0.00019073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001893549,0.00005248641,0.0001214709,0.0005782022,0.0001849432,0.000001099407,0.000218449,0.000004054161,0.9973665,0.0006172126,0.0003946168,0.0002715847],"study_design_scores_gemma":[0.001545964,0.0002694514,0.0001193878,0.00004018337,0.000196168,0.0000210557,0.00007593889,0.0000760811,0.996557,0.0003833935,0.0004761208,0.0002392287],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967769,0.001428763,0.00003578798,0.0004441704,0.00002049895,0.0002042858,0.0001428897,0.00006651023,0.0008802275],"genre_scores_gemma":[0.9992216,0.0001884264,0.00003415392,0.00008210606,0.00008625196,0.0000193929,0.0001267877,0.00004387098,0.0001973779],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002444766,"threshold_uncertainty_score":0.999961,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2002649329","doi":"10.1021/bi9929958","title":"Multiple Replacements of Glutamine 143 in Human Manganese Superoxide Dismutase:  Effects on Structure, Stability, and Catalysis","year":2000,"lang":"en","type":"article","venue":"Biochemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Waterloo","funders":"National Institute of General Medical Sciences; National Heart, Lung, and Blood Institute","keywords":"Chemistry; Active site; Superoxide dismutase; Manganese; Stereochemistry; Catalysis; Radiolysis; Enzyme; Dissociation (chemistry); Crystallography; Photochemistry; Radical; Biochemistry; Organic chemistry","authors":[{"name":"Vincent Lévêque","is_ca":true},{"name":"M. Elizabeth Stroupe","is_ca":true},{"name":"James R. Lepock","is_ca":true},{"name":"Diane E. Cabelli","is_ca":true},{"name":"John A. Tainer","is_ca":true},{"name":"Harry S. Nick","is_ca":true},{"name":"David N. Silverman","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.008553701969839362,"gpt":0.2337752297209663,"spread":0.2252215277511269,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001787504,0.0002965021,0.0003744092,0.00006652543,0.00006392993,0.00002208626,0.0002685273,0.0002258907,0.002890564],"category_scores_gemma":[0.0002191891,0.0002984519,0.00008245976,0.0001989825,0.00009320486,0.00006636338,0.00009008817,0.0002089531,0.000007545455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001192963,"about_ca_system_score_gemma":0.00002605983,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001289622,"about_ca_topic_score_gemma":0.00003697742,"domain_scores_codex":[0.9981628,0.00003168984,0.0004855319,0.0006330159,0.0003994565,0.0002874912],"domain_scores_gemma":[0.9986729,0.0001410184,0.000131282,0.0008747214,0.00004037236,0.0001396963],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009305603,0.0001834131,0.005725737,0.0008190373,0.00004784712,0.00002044636,0.0001059581,0.000006186234,0.9913836,0.000009240513,0.00003754691,0.001567936],"study_design_scores_gemma":[0.001644501,0.00002702928,0.001018128,0.00009938247,0.00004016954,0.00001010551,0.0001022064,0.00008806655,0.9965308,0.0001036972,0.00007484316,0.0002610262],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982347,0.0001822026,0.000002625928,0.00002099098,0.00002056865,0.00013353,0.0003486274,0.00004446477,0.001012228],"genre_scores_gemma":[0.9974384,0.00001494608,0.0001995653,0.0000242553,0.00005673355,0.0000276811,0.001236523,0.00003314192,0.0009687991],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005147249,"threshold_uncertainty_score":0.9999468,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2319228641","doi":"10.1021/ja029746i","title":"Spectroscopic and Electronic Structure Studies of 2,3-Dihydroxybiphenyl 1,2-Dioxygenase:  O<sub>2</sub> Reactivity of the Non-Heme Ferrous Site in Extradiol Dioxygenases","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval; University of British Columbia","funders":"National Center for Research Resources; National Institute of General Medical Sciences","keywords":"Chemistry; Active site; Crystallography; Square pyramidal molecular geometry; Stereochemistry; Dioxygenase; Substrate (aquarium); Extended X-ray absorption fine structure; Electronic structure; Heme; Bond length; X-ray absorption spectroscopy; Magnetic circular dichroism; Density functional theory; Reactivity (psychology); Absorption spectroscopy; Crystal structure; Enzyme; Computational chemistry","authors":[{"name":"Mindy I. Davis","is_ca":true},{"name":"Erik C. Wasinger","is_ca":true},{"name":"Monita Y. M. Pau","is_ca":true},{"name":"Frédéric H. Vaillancourt","is_ca":true},{"name":"Jeffrey T. Bolin","is_ca":true},{"name":"Lindsay D. Eltis","is_ca":true},{"name":"Britt Hedman","is_ca":true},{"name":"Keith O. Hodgson","is_ca":true},{"name":"Edward I. Solomon","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.00979206615837184,"gpt":0.2479778922636258,"spread":0.238185826105254,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005093363,0.0003024682,0.000908036,0.00003521072,0.0000873223,0.00001335829,0.0005516449,0.0001160542,0.00002562655],"category_scores_gemma":[0.0006132714,0.0001876931,0.0006152746,0.0006175981,0.000683918,0.0001198427,0.0001630498,0.0009316297,2.788803e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004440819,"about_ca_system_score_gemma":0.0002913321,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002067617,"about_ca_topic_score_gemma":0.00001391652,"domain_scores_codex":[0.9976779,0.0001342331,0.0008122002,0.0002802031,0.0006720625,0.000423421],"domain_scores_gemma":[0.9969806,0.0003040878,0.001902208,0.0005385219,0.0001813054,0.00009328685],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004542189,0.0001221158,0.001864099,0.000136142,0.0003241754,0.000001691563,0.0006830421,0.00003680319,0.9961439,0.00005942157,0.0002188498,0.0003643595],"study_design_scores_gemma":[0.00076,0.00005335088,0.001854717,0.0001270614,0.0001193232,0.0001007382,0.000920923,0.00006512503,0.9938253,0.00191718,0.00008055486,0.0001757656],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975227,0.001852273,0.00005167974,0.0002869169,0.0000827347,0.000124594,0.00003449859,0.000007139983,0.00003750005],"genre_scores_gemma":[0.9979118,0.0009418653,0.0008622553,0.000131452,0.00009606472,0.000004019004,0.000001604579,0.0000308511,0.00002012389],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002318616,"threshold_uncertainty_score":0.7653904,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2119550359","doi":"10.1074/jbc.m114.635672","title":"The Cysteine Dioxygenase Homologue from Pseudomonas aeruginosa Is a 3-Mercaptopropionate Dioxygenase","year":2015,"lang":"en","type":"article","venue":"Journal of Biological Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Marsden Fund; Royal Society Te Apārangi; Canadian Institutes of Health Research; Royal Society; University of Otago","keywords":"Dioxygenase; Chemistry; Cysteine; Biochemistry; Enzyme; Stereochemistry","authors":[{"name":"Egor P. Tchesnokov","is_ca":false},{"name":"Matthias Fellner","is_ca":false},{"name":"Eleni Siakkou","is_ca":false},{"name":"Torsten Kleffmann","is_ca":false},{"name":"Lois W. Martin","is_ca":false},{"name":"Sekotilani Aloi","is_ca":false},{"name":"Iain L. Lamont","is_ca":false},{"name":"Sigurd M. Wilbanks","is_ca":false},{"name":"Guy N. L. Jameson","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.04153539256872005,"gpt":0.2572348610868962,"spread":0.2156994685181761,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009679834,0.0004258506,0.0006333861,0.00003467176,0.0002000078,0.0001138178,0.00120323,0.0005167099,0.001233749],"category_scores_gemma":[0.001265968,0.000245604,0.0004785157,0.000209397,0.000295704,0.0001430436,0.0002786214,0.0009016364,0.0001102749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002212681,"about_ca_system_score_gemma":0.0002467774,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002394394,"about_ca_topic_score_gemma":0.000001631985,"domain_scores_codex":[0.9968874,0.00009653026,0.00120343,0.0004572138,0.000832446,0.0005230184],"domain_scores_gemma":[0.9964989,0.0004466458,0.001070373,0.0007189917,0.0006318229,0.0006333076],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003633505,0.0001853932,0.0001859425,0.00002647125,0.0002413065,0.0005325839,0.0001192664,0.00001091133,0.9931456,0.00005695949,0.003103819,0.002028408],"study_design_scores_gemma":[0.001718979,0.00009788924,0.00007703741,0.00005518204,0.00005948634,0.0005968027,0.0006371216,0.00009423992,0.9639964,0.00557978,0.02673818,0.0003488862],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907518,0.003950329,0.0003415162,0.001450658,0.0003233658,0.00007244363,0.0002468294,0.00006564421,0.002797388],"genre_scores_gemma":[0.9939334,0.0004975796,0.001632746,0.0003805649,0.00122951,0.00001700819,0.000140807,0.00003300021,0.002135408],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02914917,"threshold_uncertainty_score":0.9999996,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2408830764","doi":"10.1039/c6sc01433j","title":"Facile hydrogen atom transfer to iron(<scp>iii</scp>) imido radical complexes supported by a dianionic pentadentate ligand","year":2016,"lang":"en","type":"article","venue":"Chemical Science","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Division of Chemistry; Centre National de la Recherche Scientifique; Chinese Academy of Sciences; Canada Research Chairs; Institut Universitaire de France; Alexander von Humboldt-Stiftung; Natural Sciences and Engineering Research Council of Canada; Universität Heidelberg; Alfred P. Sloan Foundation; University of Calgary; National Science Foundation","keywords":"Chemistry; Toluene; Hydrogen atom; Ligand (biochemistry); Hydrogen; Atom (system on chip); Combinatorial chemistry; Medicinal chemistry; Photochemistry; Organic chemistry; Receptor; Biochemistry; Group (periodic table)","authors":[{"name":"Denis M. Spasyuk","is_ca":true},{"name":"Stephanie H. Carpenter","is_ca":false},{"name":"Christos E. Kefalidis","is_ca":false},{"name":"Warren E. Piers","is_ca":true},{"name":"Michael L. Neidig","is_ca":false},{"name":"Laurent Maron","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01381202439815613,"gpt":0.2438749234836917,"spread":0.2300628990855356,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004087804,0.0003174895,0.0003357676,0.00009029244,0.0002210592,0.0001252596,0.001350004,0.0001613361,0.001528637],"category_scores_gemma":[0.000307859,0.000238779,0.0001407577,0.0006361973,0.0008338833,0.0003865464,0.0002557953,0.0001943007,0.0008269648],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000291601,"about_ca_system_score_gemma":0.0001729607,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002675792,"about_ca_topic_score_gemma":0.00000336909,"domain_scores_codex":[0.9963297,0.00001697494,0.0004872726,0.001027997,0.001184368,0.0009537123],"domain_scores_gemma":[0.9980201,0.0002034124,0.00005137498,0.0005790097,0.00008821754,0.00105793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008739179,0.00008435431,0.0001027796,0.00001767981,0.00001024743,0.000008626961,0.0002553642,4.606572e-7,0.9954286,0.0003017451,0.002922451,0.0008590149],"study_design_scores_gemma":[0.0009930426,0.0000157988,0.00002644021,0.00003536282,0.00002100521,0.00003904611,0.00009552461,0.00005190781,0.9811507,0.0003188002,0.01705735,0.0001950398],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942852,0.00006661051,0.002829591,0.0005676179,0.00008923833,0.0001919287,0.000266387,0.0001690843,0.001534293],"genre_scores_gemma":[0.9969871,0.00002238954,0.0003734703,0.0003207151,0.00007987949,0.00006045963,0.00007931241,0.00003109046,0.002045562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01427786,"threshold_uncertainty_score":0.999951,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2044231792","doi":"10.1039/b802274g","title":"Synthesis and structure of iron(iii) diamine-bis(phenolate) complexes","year":2008,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Diamine; Chemistry; Combinatorial chemistry; Polymer chemistry","authors":[{"name":"Kamrul Hasan","is_ca":true},{"name":"Candace Fowler","is_ca":true},{"name":"Philip Kwong","is_ca":true},{"name":"Angela K. Crane","is_ca":true},{"name":"Julie L. Collins","is_ca":true},{"name":"Christoper M. Kozak","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01721879175765758,"gpt":0.2253088693513539,"spread":0.2080900775936964,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004089364,0.0001822466,0.0002805114,0.0001011793,0.0002253834,0.00001184181,0.0001502623,0.0001389085,0.005873242],"category_scores_gemma":[0.00002166194,0.000181274,0.00009062818,0.0001559211,0.0001326727,0.0001418395,0.000006788881,0.0001854558,0.000008058933],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002822465,"about_ca_system_score_gemma":0.00004222294,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001316211,"about_ca_topic_score_gemma":0.00008407187,"domain_scores_codex":[0.9989477,0.00002170728,0.000324766,0.0002739205,0.0002404751,0.0001914549],"domain_scores_gemma":[0.9992214,0.0001437782,0.0001167083,0.00034409,0.00006252137,0.0001115234],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002198651,0.0000679753,0.00009238338,0.000136447,0.00006821982,0.000004388347,0.0005372143,0.0001313516,0.9963666,0.0004633852,0.00004453964,0.002065503],"study_design_scores_gemma":[0.0004314574,0.000009546065,0.0006531416,0.00002023647,0.0001021599,0.00009062682,0.0002551663,0.0003042001,0.9961771,0.0001985086,0.001563402,0.0001944724],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9713864,0.0001753479,0.02537692,0.00009147105,0.00009699956,0.00008466056,0.0007603493,0.0001024457,0.001925368],"genre_scores_gemma":[0.9961104,0.0001519374,0.00257197,0.00001906507,0.00003666289,0.00001380451,0.00006787376,0.00002936448,0.0009989464],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02472393,"threshold_uncertainty_score":0.9950355,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2088829268","doi":"10.1002/cssc.201403024","title":"How a [Co<sup>IV</sup>${^{\\underline{.....}}}$O]<sup>2+</sup> Fragment Oxidizes Water: Involvement of a Biradicaloid [Co<sup>II</sup>–(⋅O⋅)]<sup>2+</sup> Species in Forming the OO Bond","year":2015,"lang":"en","type":"article","venue":"ChemSusChem","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Density functional theory; Moiety; Electronic structure; Intramolecular force; Cobalt; Oxidation state; Spin states; Atomic orbital; Crystallography; Computational chemistry; Metal; Stereochemistry; Inorganic chemistry; Electron; Physics","authors":[{"name":"Douglas W. Crandell","is_ca":false},{"name":"Soumya Ghosh","is_ca":false},{"name":"Curtis P. Berlinguette","is_ca":true},{"name":"Mu‐Hyun Baik","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.04056582222045788,"gpt":0.251777412077857,"spread":0.2112115898573991,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.003696682,0.002392297,0.002719155,0.0009624814,0.0008699046,0.0007492253,0.00347255,0.001483116,0.001569113],"category_scores_gemma":[0.001290684,0.001889713,0.001252348,0.001383677,0.001015406,0.001508484,0.001769345,0.002390299,0.0004745856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001903861,"about_ca_system_score_gemma":0.0008494642,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002661249,"about_ca_topic_score_gemma":0.00004467005,"domain_scores_codex":[0.9859667,0.0003348371,0.003417827,0.002822015,0.004101877,0.003356732],"domain_scores_gemma":[0.991843,0.0006603571,0.001163459,0.003947305,0.000893215,0.001492706],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001414475,0.004926843,0.002214581,0.004264992,0.002994684,0.0005150454,0.09676557,0.02770763,0.7927765,0.006647581,0.05420716,0.005564939],"study_design_scores_gemma":[0.00689528,0.0002767159,0.000010839,0.000464077,0.0003481493,0.0001165827,0.04278575,0.04220761,0.7749997,0.001997333,0.1280147,0.001883263],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9787946,0.001799158,0.0008618673,0.004422853,0.0001910915,0.001870799,0.000501874,0.0006438239,0.01091394],"genre_scores_gemma":[0.9735884,0.0004374729,0.005648023,0.0009550125,0.001593686,0.001011508,0.002204515,0.0005376092,0.01402374],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07380757,"threshold_uncertainty_score":0.9999112,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2118660903","doi":"10.1021/bi050902i","title":"Roles of the Equatorial Tyrosyl Iron Ligand of Protocatechuate 3,4-Dioxygenase in Catalysis<sup>,</sup>","year":2005,"lang":"en","type":"article","venue":"Biochemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"National Institute of General Medical Sciences","keywords":"Dioxygenase; Chemistry; Ligand (biochemistry); Catalysis; Stereochemistry; Biochemistry; Enzyme; Receptor","authors":[{"name":"Michael P. Valley","is_ca":false},{"name":"C. Kent Brown","is_ca":false},{"name":"David L. Burk","is_ca":true},{"name":"M.W. Vetting","is_ca":false},{"name":"D.H. Ohlendorf","is_ca":false},{"name":"John D. Lipscomb","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01003510908322507,"gpt":0.2315320398736085,"spread":0.2214969307903834,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000379901,0.00028183,0.0003997499,0.00006427284,0.00004888384,0.00001698374,0.0007557604,0.000329881,0.0003082402],"category_scores_gemma":[0.0003189582,0.0002348876,0.0002271901,0.000368274,0.0001378621,0.00008073982,0.0002124275,0.000270456,0.00001924341],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001268441,"about_ca_system_score_gemma":0.0002058701,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000387539,"about_ca_topic_score_gemma":0.00001456884,"domain_scores_codex":[0.9978272,0.00002782866,0.0008101792,0.0004431813,0.0005781066,0.0003134917],"domain_scores_gemma":[0.9981523,0.0000529401,0.000481956,0.001086905,0.0001287456,0.00009718534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000803317,0.0002321605,0.0002452451,0.0004568099,0.0000371043,0.000001830729,0.0002883028,0.0004392326,0.9968163,0.00006969619,0.0001378288,0.001195117],"study_design_scores_gemma":[0.00109812,0.000008976674,0.00001756364,0.0001341791,0.00004141673,0.000007648369,0.0002585194,0.001203163,0.9963524,0.0001286202,0.0005238457,0.0002255772],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972892,0.0003198049,0.0000297344,0.0001020958,0.00004281276,0.0003397201,0.0001070611,0.00003796753,0.001731564],"genre_scores_gemma":[0.9977416,0.00001438616,0.000447039,0.00001583359,0.0003537682,0.0001523292,0.0001022386,0.0000359072,0.001136864],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001017788,"threshold_uncertainty_score":0.9578439,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2047853910","doi":"10.1002/anie.201103233","title":"Bioinspired Five‐Coordinate Iron(III) Complexes for Stabilization of Phenoxyl Radicals","year":2011,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Radical; Diamine; Redox; Metal; Sequence (biology); Photochemistry; Combinatorial chemistry; Crystallography; Polymer chemistry; Inorganic chemistry; Organic chemistry; Biochemistry","authors":[{"name":"M. ALLARD","is_ca":false},{"name":"Jason A. Sonk","is_ca":false},{"name":"Mary Jane Heeg","is_ca":false},{"name":"Bruce R. McGarvey","is_ca":true},{"name":"H. Bernhard Schlegel","is_ca":false},{"name":"Cláudio N. Verani","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.03975072257971959,"gpt":0.2672033328905593,"spread":0.2274526103108397,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000237443,0.000204703,0.000254659,0.0001444061,0.00007886418,0.0000254357,0.0003696862,0.0001640393,0.005717327],"category_scores_gemma":[0.000277284,0.000214078,0.0001689965,0.0001150037,0.0001404906,0.0003739929,0.00006461908,0.00009739404,0.0000191351],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000135913,"about_ca_system_score_gemma":0.00004692374,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006256406,"about_ca_topic_score_gemma":0.0000110728,"domain_scores_codex":[0.9983783,0.00001276929,0.0005721754,0.00036773,0.0004626037,0.0002064702],"domain_scores_gemma":[0.9985338,0.0001195597,0.0004576637,0.0002621253,0.0005357891,0.00009105731],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000181767,0.0002382751,0.0001250613,0.0001514377,0.00009511692,0.000001434052,0.0005057136,0.00001026264,0.9846634,0.00989392,0.003294688,0.0008389669],"study_design_scores_gemma":[0.001519324,0.00003441953,0.0001198348,0.0000682953,0.00005622523,0.000005472608,0.0002420873,0.0006184979,0.9844439,0.007745645,0.004934047,0.0002122418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5526562,0.0002386382,0.3708635,0.0007440793,0.003415664,0.0008874978,0.003821877,0.0004916947,0.06688087],"genre_scores_gemma":[0.9881136,0.0000453035,0.005040621,0.00009962153,0.0007353947,0.0001613818,0.004506967,0.00004084074,0.001256235],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4354574,"threshold_uncertainty_score":0.9951916,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2053222012","doi":"10.1021/ic200388y","title":"Redox-Active Bridging Ligands Based on Indigo Diimine (“Nindigo”) Derivatives","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia; University of Alberta; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Chemistry; Diimine; Palladium; Deprotonation; Imine; Ligand (biochemistry); Redox; Medicinal chemistry; Photochemistry; Denticity; Substituent; Stereochemistry; Crystallography; Inorganic chemistry; Crystal structure; Organic chemistry; Catalysis","authors":[{"name":"Graeme Nawn","is_ca":true},{"name":"Kate M. Waldie","is_ca":true},{"name":"S.R. Oakley","is_ca":true},{"name":"Brendan Peters","is_ca":true},{"name":"D. Mandel","is_ca":true},{"name":"Brian O. Patrick","is_ca":true},{"name":"Robert McDonald","is_ca":true},{"name":"Robin G. Hicks","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02147617192557697,"gpt":0.2260758931888478,"spread":0.2045997212632709,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001884311,0.0004033675,0.0003744363,0.00009566666,0.0001067712,0.00003580657,0.0005355558,0.000310352,0.01051105],"category_scores_gemma":[0.0003859363,0.000434101,0.0001186578,0.0004188668,0.00008971425,0.0001589227,0.0001188001,0.0005720889,0.0001114067],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003090441,"about_ca_system_score_gemma":0.0001960862,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003612198,"about_ca_topic_score_gemma":0.000005990042,"domain_scores_codex":[0.9978364,0.00001430967,0.0005046767,0.0006916742,0.0004439497,0.0005090508],"domain_scores_gemma":[0.9985253,0.00010796,0.0003051065,0.0007873148,0.00008318432,0.0001911589],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001150387,0.0002796853,0.001562469,0.0001507261,0.00004106266,0.00008007531,0.001278207,0.0000087597,0.995301,0.00004066615,0.00005205419,0.001090265],"study_design_scores_gemma":[0.001234541,0.00001685715,0.001909255,0.0001547131,0.00002285291,0.00002261129,0.0005068761,0.00045388,0.9948304,0.0002591712,0.0001346205,0.0004542288],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9316518,0.00003129086,0.0002960147,0.00006893047,0.00007604041,0.00008404971,0.00006152569,0.0002005681,0.06752982],"genre_scores_gemma":[0.9974513,0.000007329766,0.0005900369,0.0001450083,0.0001732425,0.00004431277,0.0002039662,0.00008364613,0.001301128],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0662287,"threshold_uncertainty_score":0.9998111,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2888239057","doi":"10.1021/acs.inorgchem.8b02171","title":"Preface for the Forum on Applications of Metal Complexes with Ligand-Centered Radicals","year":2018,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true},"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Radical; Ligand (biochemistry); Metal; Combinatorial chemistry; Organic chemistry; Biochemistry; Receptor","authors":[{"name":"Tim Storr","is_ca":true},{"name":"Rabindranath Mukherjee","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01878204122038691,"gpt":0.2587010534877285,"spread":0.2399190122673416,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001363782,0.0002082244,0.000249025,0.00001603135,0.0001943749,0.00002846454,0.0006008177,0.0001260342,0.001555318],"category_scores_gemma":[0.00009898398,0.0001465505,0.000105433,0.0001627763,0.0002527015,0.0000440261,0.00008742515,0.0001529127,0.00003639484],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005492898,"about_ca_system_score_gemma":0.00008962649,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007544475,"about_ca_topic_score_gemma":0.00000678689,"domain_scores_codex":[0.9986935,0.000006266449,0.0003458977,0.000362365,0.0003249738,0.0002670525],"domain_scores_gemma":[0.9983589,0.0002476055,0.0002771023,0.0008407558,0.0001866773,0.00008897693],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008309816,0.0001310777,0.00003301993,0.0001616808,0.0001591233,2.51867e-7,0.00007760157,0.000001723035,0.9971014,0.0005598812,0.0009175765,0.0007735216],"study_design_scores_gemma":[0.0009380218,0.00003457414,0.00001047965,0.00003805349,0.0001013516,0.00001879993,0.0003351169,0.0001339184,0.9751266,0.0004874514,0.02261209,0.0001634985],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9311243,0.0005014839,0.0482698,0.001799336,0.0001183828,0.001177839,0.001003825,0.000309742,0.0156953],"genre_scores_gemma":[0.995311,0.00001003783,0.001044531,0.0001127525,0.000286077,0.0002303933,0.0001463717,0.00004657101,0.002812318],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06418666,"threshold_uncertainty_score":0.9993574,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2158818998","doi":"10.1073/pnas.1320039111","title":"Crystal structure of PhnZ in complex with substrate reveals a di-iron oxygenase mechanism for catabolism of organophosphonates","year":2014,"lang":"en","type":"article","venue":"Proceedings of the National Academy of Sciences","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"Argonne National Laboratory; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research","keywords":"Chemistry; Active site; Stereochemistry; Dioxygenase; Histidine; Enzyme; Biochemistry","authors":[{"name":"Laura M. van Staalduinen","is_ca":true},{"name":"Fern R. McSorley","is_ca":true},{"name":"Katharina Schiessl","is_ca":false},{"name":"Jacqueline P. Séguin","is_ca":true},{"name":"Peter B. Wyatt","is_ca":false},{"name":"Friedrich Hammerschmidt","is_ca":false},{"name":"David L. Zechel","is_ca":true},{"name":"Zongchao Jia","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02724524309613134,"gpt":0.2683492040501336,"spread":0.2411039609540022,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008742937,0.0001625827,0.0003675878,0.0001896305,0.00008472692,0.00001285709,0.0009380101,0.0001346826,0.00007726428],"category_scores_gemma":[0.0006594628,0.0001112619,0.00007659358,0.0006681983,0.0005058359,0.0002936455,0.0001007578,0.0001454693,1.573024e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000303266,"about_ca_system_score_gemma":0.00005737988,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002027877,"about_ca_topic_score_gemma":0.000001434748,"domain_scores_codex":[0.9976346,0.000006488167,0.0006396218,0.0003164715,0.001206223,0.0001965797],"domain_scores_gemma":[0.9978309,0.0001605593,0.001225421,0.00002525124,0.0007139195,0.00004389553],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004460304,0.00003882669,0.0005697398,0.0004263314,0.0000126224,2.643287e-9,0.0002191432,0.00008765007,0.8272673,0.1712731,0.00002505916,0.00003565282],"study_design_scores_gemma":[0.0005409074,0.00003717755,0.004975718,0.0001121365,0.00001818775,0.000004148058,0.0002660903,0.001277164,0.8392762,0.1533824,0.00001097128,0.00009893925],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984552,0.00003471227,0.00002338313,0.0003477274,0.00001140745,0.000267489,0.0003098174,0.000008466815,0.0005418253],"genre_scores_gemma":[0.9918979,0.000007686835,0.007913834,0.00005291439,0.0000338236,0.00001566118,0.000005067438,0.00001136219,0.00006171571],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01789072,"threshold_uncertainty_score":0.4537129,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2060010987","doi":"10.1126/science.1251550","title":"IRBIT is a novel regulator of ribonucleotide reductase in higher eukaryotes","year":2014,"lang":"en","type":"article","venue":"Science","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"National Institutes of Health; Stem Cell Network","keywords":"Ribonucleotide reductase; Allosteric regulation; Cell biology; Regulator; DNA replication; Biology; Phosphorylation; DNA; Biochemistry; Enzyme; Chemistry; Protein subunit; Gene","authors":[{"name":"Alexei Arnaoutov","is_ca":false},{"name":"Mary Dasso","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.02835944974496325,"gpt":0.2553124758199143,"spread":0.2269530260749511,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007687274,0.0001035336,0.0001538368,0.0001495464,0.00006167666,0.00002876618,0.0005788651,0.00004889895,0.001859827],"category_scores_gemma":[0.0003980329,0.00009753764,0.00003905499,0.0007056614,0.0003458228,0.0002466148,0.0001296471,0.00009424568,0.00006656465],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005615114,"about_ca_system_score_gemma":0.0001049053,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003640873,"about_ca_topic_score_gemma":0.000004465163,"domain_scores_codex":[0.9985067,0.0000084872,0.0002741402,0.0003967992,0.0005490769,0.0002647636],"domain_scores_gemma":[0.99902,0.00004441232,0.000143246,0.0005778954,0.0001064803,0.000107954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004047845,0.00004308999,0.0003039535,0.00002494801,0.000001549745,5.04513e-7,0.0001411326,0.00001204037,0.9895211,0.00925383,0.0001046195,0.00058918],"study_design_scores_gemma":[0.0003099127,0.000007958254,0.003713652,0.00003785051,0.000003999023,0.00000327683,0.0000380999,0.001551129,0.9892856,0.002843464,0.002084658,0.0001204154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887371,0.00002930732,0.0002585707,0.0005137129,0.0001892091,0.00004464918,0.00002392861,0.00003399551,0.0101695],"genre_scores_gemma":[0.9898588,0.000001329342,0.007526487,0.0001553041,0.00005055926,0.000005147293,0.000003711698,0.00001038935,0.002388247],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007781251,"threshold_uncertainty_score":0.9990526,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2049338973","doi":"10.1021/ja3067226","title":"Compound I Is the Reactive Intermediate in the First Monooxygenation Step during Conversion of Cholesterol to Pregnenolone by Cytochrome P450scc: EPR/ENDOR/Cryoreduction/Annealing Studies","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Structural Genomics Consortium; University of Toronto","funders":"National Heart, Lung, and Blood Institute; National Institutes of Health","keywords":"Chemistry; Electron paramagnetic resonance; Hydroxylation; Ferric; Photochemistry; Cytochrome; Pregnenolone; Cholesterol side-chain cleavage enzyme; Reactive intermediate; Ternary complex; Steroid; Stereochemistry; Cytochrome P450; Catalysis; Organic chemistry; Nuclear magnetic resonance","authors":[{"name":"Roman Davydov","is_ca":false},{"name":"А. А. Гилеп","is_ca":false},{"name":"Natallia Strushkevich","is_ca":true},{"name":"Sergey A. Usanov","is_ca":false},{"name":"Brian M. Hoffman","is_ca":false}],"retraction":null,"screen_n_in":null,"score":{"opus":0.01882212057783198,"gpt":0.2750002659191139,"spread":0.2561781453412819,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007156963,0.0001925561,0.0004091013,0.00003237849,0.0001798508,0.00002882713,0.0007521786,0.00006451027,0.000021223],"category_scores_gemma":[0.0002489964,0.0001053978,0.0003570703,0.0003803713,0.0003903902,0.000241844,0.0002389183,0.0005738062,0.00000303623],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004507531,"about_ca_system_score_gemma":0.00002682371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004955983,"about_ca_topic_score_gemma":0.000001242338,"domain_scores_codex":[0.9982206,0.00008801604,0.0006017844,0.0001671757,0.0006388199,0.0002836017],"domain_scores_gemma":[0.9976751,0.0003632861,0.001329427,0.000349897,0.0002069898,0.00007529306],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008498554,0.0001284159,0.001105281,0.00007917232,0.0002951639,4.276108e-7,0.01560665,0.00004187962,0.9796385,0.00000262473,0.002839238,0.0001776577],"study_design_scores_gemma":[0.0006119068,0.00002962622,0.005013745,0.0001552964,0.0001035092,0.00006672335,0.02395202,0.00008614736,0.969286,0.00003291393,0.0005411247,0.0001210027],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948956,0.0004165267,0.00007665007,0.00424881,0.0001470652,0.0001571557,0.00002542158,0.00000847529,0.00002426598],"genre_scores_gemma":[0.9982919,0.0002353412,0.0004153116,0.0006868187,0.0002967336,0.00001782,0.00000381282,0.00001934785,0.00003297658],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01035252,"threshold_uncertainty_score":0.4297996,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2031761997","doi":"10.1074/jbc.m110.194423","title":"Structural and Functional Studies of the Escherichia coli Phenylacetyl-CoA Monooxygenase Complex","year":2011,"lang":"en","type":"article","venue":"Journal of Biological Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Biotechnology Research Institute; McGill University","funders":"Canadian Institutes of Health Research","keywords":"Monooxygenase; Oxygenase; Protein subunit; Stereochemistry; Reductase; Biochemistry; Thermus thermophilus; Oxidoreductase; Active site; Escherichia coli; Homology modeling; Chemistry; Biology; Cofactor; Enzyme; Cytochrome P450; Gene","authors":[{"name":"Andrey M. Grishin","is_ca":true},{"name":"Eunice Ajamian","is_ca":true},{"name":"Limei Tao","is_ca":true},{"name":"Linhua Zhang","is_ca":true},{"name":"Robert Ménard","is_ca":true},{"name":"Mirosław Cygler","is_ca":true}],"retraction":null,"screen_n_in":null,"score":{"opus":0.1282409853335296,"gpt":0.2785113601041363,"spread":0.1502703747706067,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000287483,0.0001930385,0.0004058287,0.00001494114,0.0001033566,0.00001048074,0.0003065139,0.0001789826,0.002302302],"category_scores_gemma":[0.0004955726,0.0001073224,0.000209564,0.000103185,0.0003651603,0.00006466365,0.0001894954,0.0003579477,0.000001420725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004985113,"about_ca_system_score_gemma":0.00005274887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002802567,"about_ca_topic_score_gemma":4.24166e-7,"domain_scores_codex":[0.998687,0.00003786337,0.0006293085,0.0001794889,0.000290896,0.0001754741],"domain_scores_gemma":[0.9984559,0.0001180674,0.0007786456,0.0002157849,0.000313558,0.0001180344],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001546278,0.00004988212,0.001691483,0.00009504797,0.0001913293,0.000006211041,0.0001434213,0.000004861958,0.9970384,0.0001169416,0.000313163,0.0001946178],"study_design_scores_gemma":[0.0006652647,0.00003780714,0.01014508,0.00003518634,0.00005615103,0.0001349612,0.0009973699,0.00005596504,0.9851096,0.002311581,0.0003143874,0.0001366891],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974766,0.0008302705,0.00004171526,0.0000885542,0.0001266337,0.00003461582,0.00003162748,0.00001201166,0.00135801],"genre_scores_gemma":[0.9975368,0.0001176953,0.001807681,0.00007257484,0.0002024619,0.000002712175,0.000007353502,0.000008981629,0.0002437573],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01192886,"threshold_uncertainty_score":0.9986097,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null}]}