{"meta":{"page":1,"per_page":50,"max_per_page":100,"total":113,"total_is_capped":false,"direct_labels_cover":0,"predictions_cover":113,"direct_label_status":"direct model label, unvalidated","prediction_status":"machine_predicted_unvalidated (Codex and Gemma teacher distillation)","score_status":"score_only:v0-immature-baseline (scores rank; they never assert a category)","snapshot":{"source":"OpenAlex, pinned release, all 482 partitions","release":"2026-06-24","frame_built":"2026-07-12"},"query_hash":"cebdf79039ce","filters":{"topic":"Synthesis of Indole Derivatives"}},"results":[{"id":"W2508595669","doi":"10.1021/acscatal.5b00909","title":"Recent Advances in the Synthesis of Triarylmethanes by Transition Metal Catalysis","year":2015,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":190,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"Japan Society for the Promotion of Science; Natural Sciences and Engineering Research Council of Canada; Nagoya University; Hattori Hokokai Foundation; Canada Foundation for Innovation","keywords":"Chemistry; Catalysis; Transition metal; Nanotechnology; Biochemical engineering; Combinatorial chemistry; Organic chemistry; Materials science","retraction":null,"screen_n_in":null,"score":{"opus":0.02059513494301862,"gpt":0.2601013306748315,"spread":0.2395061957318129,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009905068,0.0002424639,0.0005905537,0.0001812111,0.00004991762,0.00002619419,0.0006588192,0.0001231718,0.0001700994],"category_scores_gemma":[0.001745979,0.0001800145,0.0002248784,0.0008402046,0.0001728128,0.000477611,0.00003750483,0.0001487107,0.00002057927],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007802356,"about_ca_system_score_gemma":0.00004999186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001956393,"about_ca_topic_score_gemma":0.0001120108,"domain_scores_codex":[0.9979578,0.0001914997,0.0005730384,0.0003801085,0.0006368423,0.0002607727],"domain_scores_gemma":[0.9976591,0.001115242,0.0002921929,0.0007223548,0.000138459,0.00007264822],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005905475,0.001596662,0.00196893,0.0002632534,0.001274383,0.00003429759,0.01627945,0.0003923388,0.3573137,0.00005903268,0.002007415,0.61822],"study_design_scores_gemma":[0.0004335635,0.0000140495,0.00006035393,0.00004279666,0.0004967652,0.000007557836,0.01212168,0.00004186155,0.9755918,0.0001502359,0.01081395,0.0002254098],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9723634,0.01987955,0.00008690667,0.001667638,0.00003752169,0.0001151766,0.0001401348,0.00004705825,0.005662597],"genre_scores_gemma":[0.995858,0.003337813,0.0001781676,0.00006191592,0.00005456226,0.0001511678,0.0002806171,0.00002460215,0.00005319711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6182781,"threshold_uncertainty_score":0.7340777,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2332520438","doi":"10.1021/ja412159g","title":"Synthesis of Enantiomerically Enriched Triarylmethanes by Enantiospecific Suzuki–Miyaura Cross-Coupling Reactions","year":2014,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":176,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Coupling reaction; Organic chemistry; Enantioselective synthesis; Coupling (piping); Stereochemistry; Computational chemistry; Combinatorial chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01116044612372841,"gpt":0.2647628934811176,"spread":0.2536024473573892,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009796941,0.0003049893,0.0009995603,0.00003957873,0.0001619766,0.00006251802,0.001156551,0.0001476162,0.0001769795],"category_scores_gemma":[0.004210036,0.0002058434,0.001327215,0.0006173049,0.001364521,0.0001943432,0.0001577612,0.0006809441,0.000004512881],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001949439,"about_ca_system_score_gemma":0.00009585048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005503499,"about_ca_topic_score_gemma":1.605944e-7,"domain_scores_codex":[0.9971868,0.00004998635,0.001257539,0.0002964116,0.0007989075,0.0004103661],"domain_scores_gemma":[0.9924464,0.003254368,0.003152714,0.0005829846,0.0004032628,0.0001603102],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001395819,0.0002439716,0.00539056,0.00006921621,0.0003593181,6.289893e-7,0.0001499631,0.00004539563,0.9870445,0.00001903282,0.002551525,0.003986361],"study_design_scores_gemma":[0.0004871527,0.00002863216,0.001999047,0.0001478462,0.0001292821,0.00004206141,0.0007527351,0.0002575397,0.9925717,0.0001590006,0.003183641,0.0002414391],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974847,0.0001774827,0.0005176357,0.00108922,0.0001191299,0.00004635743,0.00002069214,0.00003314806,0.0005115663],"genre_scores_gemma":[0.9954606,0.0002677251,0.003492773,0.0001365943,0.0004352092,0.000007648579,0.000001627347,0.00005136421,0.0001464982],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005527177,"threshold_uncertainty_score":0.8394051,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2066721962","doi":"10.1021/ja108106h","title":"Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":169,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"National Institute of General Medical Sciences","keywords":"Chemistry; Enantioselective synthesis; Alkene; Palladium; Catalysis; Combinatorial chemistry; Ligand (biochemistry); Substrate (aquarium); Copper; Electronic effect; Stereochemistry; Organic chemistry; Receptor; Biochemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01227169094464085,"gpt":0.2486789005173432,"spread":0.2364072095727023,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000442515,0.0001347268,0.0002791164,0.00001722863,0.0001823375,0.00002377679,0.0004272846,0.00006749923,0.00005353121],"category_scores_gemma":[0.0009908957,0.00007953201,0.0003558532,0.0002950145,0.0004426453,0.0001829855,0.0000594098,0.0005597463,3.818852e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003200315,"about_ca_system_score_gemma":0.0001131414,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003238968,"about_ca_topic_score_gemma":0.000005713379,"domain_scores_codex":[0.9987801,0.00004789468,0.000396151,0.0001388747,0.0004561076,0.0001808215],"domain_scores_gemma":[0.997438,0.0005900729,0.00141535,0.0002682963,0.0002205881,0.00006774233],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008827494,0.00008134473,0.00049175,0.00001477421,0.0001543642,3.126053e-7,0.0004267165,0.00002355456,0.9976977,0.0002265681,0.0001528965,0.0006417438],"study_design_scores_gemma":[0.0002682851,0.00002196421,0.001095735,0.00005286804,0.00009566792,0.00006675776,0.004354449,0.0006101225,0.990033,0.003183134,0.0001194831,0.00009856636],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944063,0.00001481519,0.00437605,0.0007654634,0.0001558667,0.00004043322,0.000005453496,0.00001405451,0.0002215045],"genre_scores_gemma":[0.9974182,0.00002851671,0.002026214,0.0001186256,0.0003683141,0.000002422341,0.00000293693,0.00002145471,0.00001329027],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007664733,"threshold_uncertainty_score":0.3243221,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2148412047","doi":"10.1002/anie.201307019","title":"Modular Synthesis of Triarylmethanes through Palladium‐Catalyzed Sequential Arylation of Methyl Phenyl Sulfone","year":2013,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":166,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"","keywords":"Sulfone; Chemistry; Palladium; Aryl; Catalysis; Combinatorial chemistry; Modular design; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02278616751625021,"gpt":0.2624468021289779,"spread":0.2396606346127277,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002320296,0.0002312152,0.0004052551,0.0001314409,0.00003913745,0.00002877609,0.0004012964,0.000200574,0.005341264],"category_scores_gemma":[0.001349661,0.0002321146,0.0002410322,0.0001441409,0.0001895265,0.000802658,0.00007763566,0.0001299929,0.00003106491],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001118691,"about_ca_system_score_gemma":0.00004845431,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000562518,"about_ca_topic_score_gemma":0.000005538811,"domain_scores_codex":[0.9980429,0.00003424978,0.000705318,0.0003374623,0.000691193,0.0001888831],"domain_scores_gemma":[0.9976305,0.0006805944,0.000683979,0.0003365708,0.0006167627,0.00005158793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001181024,0.0001854623,0.0003454659,0.0001359809,0.0003560229,0.000001679168,0.0003250381,0.00003891104,0.9955852,0.0002693927,0.0006541419,0.001984589],"study_design_scores_gemma":[0.0007153185,0.00001003801,0.001161246,0.000234089,0.00007639979,0.000005882294,0.0003775799,0.0001909346,0.9930573,0.003658184,0.0003100321,0.0002029641],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9786513,0.0001803342,0.003314629,0.0006869906,0.0004745335,0.000161283,0.0002890906,0.00007118106,0.01617061],"genre_scores_gemma":[0.9951327,0.0001384978,0.002820448,0.00002671666,0.0009123961,0.0001447884,0.0006240841,0.00003388313,0.0001664445],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01648139,"threshold_uncertainty_score":0.995568,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W4237334620","doi":"10.1002/ange.201307019","title":"Modular Synthesis of Triarylmethanes through Palladium‐Catalyzed Sequential Arylation of Methyl Phenyl Sulfone","year":2013,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":133,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Sulfone; Aryl; Palladium; Catalysis; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02667637836510066,"gpt":0.2531867631138061,"spread":0.2265103847487055,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002698444,0.0003155581,0.0007494723,0.000085365,0.00004856482,0.00002148576,0.0004375254,0.0002637573,0.003053297],"category_scores_gemma":[0.001154273,0.0002975256,0.0003059649,0.000241853,0.0002684143,0.0004310763,0.0001058814,0.0001424155,0.00003235953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005739454,"about_ca_system_score_gemma":0.00006151162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007834255,"about_ca_topic_score_gemma":0.000006407229,"domain_scores_codex":[0.9980145,0.00004863159,0.0007418867,0.0004134816,0.0004546299,0.0003269445],"domain_scores_gemma":[0.9974479,0.0008682833,0.0006044679,0.0007197357,0.0002802093,0.00007936955],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009550206,0.0001516766,0.0005809966,0.0003960394,0.0003422017,0.000002386746,0.0006330887,0.00001280094,0.9957127,0.00005508918,0.0001990777,0.001818447],"study_design_scores_gemma":[0.0007665451,0.00001035534,0.0006072377,0.0001977564,0.0001500701,0.000003911125,0.0005856095,0.00002781535,0.9959948,0.001185442,0.0001861997,0.0002842494],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9852521,0.0009461946,0.0001591476,0.0002080751,0.00006067992,0.000180273,0.00007985174,0.00007697968,0.01303672],"genre_scores_gemma":[0.9950513,0.0001875387,0.004082805,0.00001827137,0.0001865645,0.0001126235,0.00008025008,0.00005517012,0.0002255201],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0128112,"threshold_uncertainty_score":0.9999477,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2102678387","doi":"10.1002/ejoc.200500863","title":"“On Water”‐Promoted Direct Coupling of Indoles with 1,4‐Benzoquinones without Catalyst","year":2005,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":96,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"Chinese Academy of Sciences; National Natural Science Foundation of China","keywords":"Chemistry; Catalysis; Indole test; Direct coupling; Coupling (piping); Solvent; Organic chemistry; Oxidative coupling of methane; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.008403328593966058,"gpt":0.2004086160479824,"spread":0.1920052874540163,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000588867,0.0003339747,0.0005536969,0.00006019295,0.00008016935,0.00004488741,0.0006916335,0.00006332645,0.001952839],"category_scores_gemma":[0.0003251278,0.0002316727,0.0001477091,0.0001186108,0.0001788205,0.0001580939,0.00009749963,0.0004688913,0.0000396051],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009887322,"about_ca_system_score_gemma":0.0000866402,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":8.416339e-7,"about_ca_topic_score_gemma":7.099071e-7,"domain_scores_codex":[0.9980022,0.00003117791,0.0008409393,0.0002783534,0.0005305649,0.0003167715],"domain_scores_gemma":[0.9980925,0.0001368008,0.0008248014,0.000488721,0.0002852636,0.000171893],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003068362,0.000216726,0.001253368,0.0001831085,0.0002538831,0.0001616435,0.0006422607,0.0002139322,0.9955342,5.882523e-7,0.00008702877,0.001146401],"study_design_scores_gemma":[0.001411593,0.00007725735,0.0003089382,0.0009124115,0.00008750705,0.0005792621,0.0005139861,0.00002687805,0.9952833,0.000002939703,0.0005115743,0.0002843746],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9816825,0.0002486298,0.00006155557,0.0001630574,0.00002704271,0.00002839776,0.0000093832,0.00004702077,0.01773244],"genre_scores_gemma":[0.9981719,0.00002489709,0.0005040818,0.00002266619,0.0005442403,4.749455e-7,0.000009515026,0.0001163123,0.0006058817],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01712656,"threshold_uncertainty_score":0.9989595,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2032593866","doi":"10.1021/ja010826g","title":"Flash Photolytic Generation of <i>o</i><i>rtho</i>-Quinone Methide in Aqueous Solution and Study of Its Chemistry in that Medium","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":90,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Quinone methide; Aqueous solution; Aqueous medium; Flash (photography); Quinone; Flash photolysis; Photochemistry; Organic chemistry; Kinetics","retraction":null,"screen_n_in":null,"score":{"opus":0.02918351955551849,"gpt":0.269833216257759,"spread":0.2406496967022405,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005329701,0.0001746489,0.0006337445,0.00002802855,0.00002676264,0.000009915012,0.0003897498,0.0001005324,0.00003500902],"category_scores_gemma":[0.0005289369,0.000136236,0.0002220594,0.0003605223,0.0003430505,0.0001134121,0.0001409362,0.0005075167,1.786872e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001934882,"about_ca_system_score_gemma":0.00009077104,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001069977,"about_ca_topic_score_gemma":0.00001713062,"domain_scores_codex":[0.9982253,0.00007657031,0.0007649014,0.0001902132,0.0005265549,0.0002165005],"domain_scores_gemma":[0.9978734,0.0003337944,0.001360493,0.00024032,0.0001256166,0.00006637675],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001195153,0.0005301349,0.03803673,0.00007824942,0.00008979626,0.000005669567,0.001784069,0.00004656025,0.9578767,1.576131e-7,0.0001452273,0.001287164],"study_design_scores_gemma":[0.001152667,0.00004659751,0.005829977,0.000174019,0.00005016996,0.00006225518,0.004287812,0.0007145978,0.9875137,0.00001699442,0.00003098287,0.0001202161],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988048,0.0004764688,0.00001231707,0.0004382474,0.00002641235,0.00008420458,0.000003579021,0.000004869053,0.0001490759],"genre_scores_gemma":[0.9985337,0.0005175102,0.0006979238,0.0000798352,0.0001184723,0.000005547414,8.531784e-7,0.00001722069,0.00002894501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03220676,"threshold_uncertainty_score":0.5555545,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W4280591169","doi":"10.1007/s43440-022-00370-3","title":"Recent progress in biologically active indole hybrids: a mini review","year":2022,"lang":"en","type":"review","venue":"Pharmacological Reports","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":86,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"","keywords":"Indole test; Isatin; Chalcone; Biological activity; Antifungal; Chemistry; Pyrimidine; Drug discovery; Combinatorial chemistry; Biochemistry; Biology; Organic chemistry; Microbiology; In vitro","retraction":null,"screen_n_in":null,"score":{"opus":0.1257433519135173,"gpt":0.4120789794125042,"spread":0.2863356274989869,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001497459,0.001068478,0.004093514,0.000193574,0.0001441273,0.00004484633,0.001020359,0.0005432838,0.05389476],"category_scores_gemma":[0.00391657,0.0007623222,0.001013863,0.0008810257,0.0003445928,0.0001125513,0.001112623,0.002199842,0.00007660403],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001013279,"about_ca_system_score_gemma":0.0006528221,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002916515,"about_ca_topic_score_gemma":6.377495e-7,"domain_scores_codex":[0.9927807,0.000871857,0.00269662,0.001898992,0.0008114129,0.0009404231],"domain_scores_gemma":[0.994252,0.001934307,0.002660434,0.0007308209,0.0001029305,0.0003195057],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0000365431,0.0008327449,0.00004754397,0.01662211,0.0003186235,0.01036761,0.00001191985,8.391137e-8,0.00001643536,0.000002331292,0.004070668,0.9676734],"study_design_scores_gemma":[0.0001835301,0.00005968221,0.00001208034,0.02015119,0.0007727979,0.001319582,0.0000182248,3.750807e-7,0.0002530495,0.00004315596,0.9763372,0.0008491583],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0001782159,0.9790816,1.741252e-7,0.000222127,0.0003645686,0.001815402,0.00008460729,0.0002767366,0.0179766],"genre_scores_gemma":[0.0000311581,0.9904006,0.0001213831,0.0006423674,0.000254322,0.007622628,0.0004698021,0.00009141463,0.0003663581],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9722665,"threshold_uncertainty_score":0.9994828,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2343245391","doi":"10.1021/acs.orglett.6b00744","title":"Arylative Desulfonation of Diarylmethyl Phenyl Sulfone with Arenes Catalyzed by Scandium Triflate","year":2016,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":72,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"Japan Society for the Promotion of Science; Nagoya University; Hattori Hokokai Foundation","keywords":"Scandium; Trifluoromethanesulfonate; Chemistry; Catalysis; Sulfone; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.006213718521487503,"gpt":0.190951158239126,"spread":0.1847374397176385,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000137332,0.0002411477,0.0003195226,0.00007649076,0.00005995774,0.00001677845,0.0002825153,0.000088721,0.001003593],"category_scores_gemma":[0.0002512884,0.0001615877,0.00006083655,0.0001982634,0.0002554353,0.0002760951,0.00004470181,0.00008815753,0.00003812685],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001381669,"about_ca_system_score_gemma":0.00005742482,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000471078,"about_ca_topic_score_gemma":0.00001013326,"domain_scores_codex":[0.9986768,0.00004007555,0.0003074764,0.0003631992,0.0003286245,0.0002838335],"domain_scores_gemma":[0.9986273,0.0005086532,0.0003224427,0.0003882847,0.00008065278,0.00007268479],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001481049,0.0000518663,0.004185464,0.00003527983,0.0001582446,0.000005647947,0.0004125939,5.821298e-7,0.9905739,0.00001239277,0.001263364,0.003152522],"study_design_scores_gemma":[0.001615285,0.00001621929,0.001936038,0.0001801831,0.00004119288,0.000005364041,0.0001289672,0.000002154621,0.9955877,0.00003696598,0.0001919473,0.0002579795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920951,0.0001275107,0.002540155,0.004551745,0.00003877199,0.00008451362,0.00009461562,0.00008210038,0.0003855111],"genre_scores_gemma":[0.998969,0.00003490396,0.0004157086,0.0001769564,0.00008400103,0.00001875263,0.00004009029,0.00005754734,0.0002029942],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006873969,"threshold_uncertainty_score":0.9999096,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2075785662","doi":"10.1021/ja508523g","title":"Thiourea-Catalyzed Enantioselective Addition of Indoles to Pyrones: Alkaloid Cores with Quaternary Carbons","year":2014,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"National Institutes of Health; National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada; Vertex Pharmaceuticals","keywords":"Chemistry; Stereocenter; Enantioselective synthesis; Catalysis; Brønsted–Lowry acid–base theory; Electrophile; Indole test; Stereoselectivity; Thiourea; Organic chemistry; Stereochemistry; Natural product; Organocatalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.006591705529226618,"gpt":0.2243080082760697,"spread":0.2177163027468431,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002326375,0.0002079302,0.0005607234,0.00002762093,0.00006956941,0.00001954882,0.0006564561,0.00006790437,0.0000374086],"category_scores_gemma":[0.0005562498,0.000125991,0.0004382426,0.0003116011,0.0006245124,0.00009776979,0.0001144671,0.0004103969,0.00000180088],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001549709,"about_ca_system_score_gemma":0.0001017553,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001086564,"about_ca_topic_score_gemma":0.00000313785,"domain_scores_codex":[0.9984989,0.00006216863,0.0004507979,0.0001891474,0.0005478641,0.0002511606],"domain_scores_gemma":[0.9974142,0.0005583033,0.00130672,0.0003262341,0.0002657775,0.000128815],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003255595,0.0001345239,0.01038625,0.00003098088,0.0003345869,9.683995e-7,0.001192981,0.00002754049,0.9843103,0.00001358315,0.001866635,0.001376106],"study_design_scores_gemma":[0.0005037352,0.00009946514,0.006582199,0.0003116955,0.00009155245,0.00005202314,0.002320803,0.00006156591,0.9893661,0.0001715549,0.0002677203,0.0001716357],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980338,0.00003903072,0.0003084027,0.00107112,0.00003107513,0.00005278039,0.00002507576,0.00001772703,0.0004209559],"genre_scores_gemma":[0.9956261,0.00002548185,0.003653121,0.0003301389,0.0003014102,0.00000657056,0.000002979778,0.00003181691,0.00002236979],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00505576,"threshold_uncertainty_score":0.5137765,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2897879530","doi":"10.1002/anie.201810760","title":"Transition‐Metal‐Free [4+3]‐Cycloaddition of <i>ortho</i>‐Quinone Methides and Isomünchnones: Catalytic and Diastereoselective Assembly of Oxa‐bridged Oxazocine Scaffolds","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto; Deutsche Forschungsgemeinschaft; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Cycloaddition; Chemistry; Diastereomer; Catalysis; Yield (engineering); Rhodium; Quinone; Combinatorial chemistry; Stereochemistry; Organic chemistry; Materials science","retraction":null,"screen_n_in":null,"score":{"opus":0.0123400502472004,"gpt":0.2461266778857096,"spread":0.2337866276385092,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002416563,0.0002437326,0.000374562,0.0002029568,0.00007863897,0.00002865613,0.000235258,0.0001737918,0.0003524127],"category_scores_gemma":[0.0005448284,0.0002528406,0.00009711778,0.0001650798,0.0005696843,0.0006004476,0.00009070467,0.0001085008,0.000003068863],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007079921,"about_ca_system_score_gemma":0.00004124907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001207982,"about_ca_topic_score_gemma":0.00004090794,"domain_scores_codex":[0.9983935,0.00002532818,0.000512666,0.0003986992,0.0004881339,0.0001816536],"domain_scores_gemma":[0.998188,0.0003905546,0.0004313372,0.0002761509,0.000636516,0.00007745036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002009038,0.0001606919,0.000476284,0.0002008914,0.000283622,0.000003066818,0.001045427,9.622555e-7,0.994657,0.0002733608,0.0008537524,0.001843975],"study_design_scores_gemma":[0.001178337,0.0001072755,0.005634212,0.0004327466,0.0001150238,0.00004823036,0.0006867021,0.00007674194,0.9898455,0.001448726,0.0002075288,0.0002190212],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875805,0.0003071419,0.001986496,0.0006352482,0.0001688723,0.000110004,0.0007865442,0.00005232846,0.008372883],"genre_scores_gemma":[0.9974255,0.0001952231,0.0009186224,0.00008254859,0.000700705,0.00004059392,0.0005113502,0.0000293927,0.0000960618],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00984502,"threshold_uncertainty_score":0.9999924,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1996280285","doi":"10.1021/ja001557h","title":"Kinetics and Mechanisms of Hydration of <i>o</i>-Quinone Methides in Aqueous Solution","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true},"ca_institutions":"University of Toronto","funders":"","keywords":"Citation; Computer science; Altmetrics; Aqueous solution; Chemistry; Library science; World Wide Web; Information retrieval; Physical chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.009252802293048756,"gpt":0.2360127071992781,"spread":0.2267599049062293,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002100153,0.00009684254,0.000364969,0.00001441285,0.00001721854,0.000005388972,0.0002328679,0.00006388898,0.00006986977],"category_scores_gemma":[0.0002111175,0.0000709535,0.00022854,0.0001717331,0.0004479814,0.00006231359,0.00004532181,0.0002344568,1.840802e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006988808,"about_ca_system_score_gemma":0.0000255758,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004981651,"about_ca_topic_score_gemma":0.000001015545,"domain_scores_codex":[0.9989585,0.0000386856,0.0005013935,0.00008815102,0.000293797,0.0001194585],"domain_scores_gemma":[0.9986519,0.0002522838,0.0008295971,0.0001462116,0.00008262072,0.00003744649],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000754085,0.0001144834,0.0004436349,0.00003601742,0.00005570959,4.381651e-7,0.0004408748,0.0000433312,0.9864079,0.00001630824,0.0001051541,0.01226075],"study_design_scores_gemma":[0.0002932723,0.00004736082,0.0008778339,0.0001141489,0.00003669491,0.00002362097,0.0006118265,0.0003148332,0.995937,0.001634452,0.00004218446,0.00006672987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983699,0.000178667,0.0004374984,0.0006769024,0.00001163884,0.00002418564,0.000004379678,0.000003552476,0.0002932703],"genre_scores_gemma":[0.9887778,0.000212934,0.01081653,0.0001147734,0.0000472612,8.429563e-7,4.177488e-7,0.000009930507,0.00001954489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01219402,"threshold_uncertainty_score":0.28934,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2165031609","doi":"10.1002/chem.201500020","title":"A Surprising Substituent Effect Provides a Superior Boronic Acid Catalyst for Mild and Metal‐Free Direct Friedel–Crafts Alkylations and Prenylations of Neutral Arenes","year":2015,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Winnipeg; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Friedel–Crafts reaction; Chemistry; Substituent; Catalysis; Allylic rearrangement; Commodity chemicals; Boronic acid; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02909109542072879,"gpt":0.246429527259895,"spread":0.2173384318391662,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007737538,0.0003122518,0.0004378635,0.00004559525,0.0002878177,0.0001894763,0.0003300272,0.00006475237,0.00003470305],"category_scores_gemma":[0.001738756,0.0002824886,0.0001528403,0.00009576835,0.0002920414,0.0003048138,0.0001508952,0.0002619258,0.000001075888],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007649578,"about_ca_system_score_gemma":0.0001580514,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000892845,"about_ca_topic_score_gemma":0.00000749434,"domain_scores_codex":[0.9984213,0.0001130436,0.0005559951,0.0003632673,0.0002205037,0.0003259035],"domain_scores_gemma":[0.9983277,0.0003556132,0.0003621461,0.0004016902,0.000216134,0.000336758],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002090257,0.00008229587,0.007933739,0.0005642376,0.0003227754,0.00003408053,0.001407938,0.00004308268,0.987147,0.000006878905,0.0002192016,0.002029735],"study_design_scores_gemma":[0.002283798,0.00007653415,0.002781379,0.0004799482,0.0003237952,0.0004872915,0.0006766631,0.0004593665,0.9910201,0.0000955506,0.0009625629,0.0003530431],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926827,0.004143766,0.0002005645,0.0001416667,0.00004255562,0.0001485062,0.0001351536,0.00005331726,0.002451785],"genre_scores_gemma":[0.9974947,0.00006460645,0.001870418,0.000006911097,0.0002559204,0.00002118037,0.00004067793,0.00006286454,0.0001827213],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00515236,"threshold_uncertainty_score":0.9999627,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2321124147","doi":"10.1021/ol2030636","title":"Multicomponent Synthesis of 6<i>H</i>-Dibenzo[<i>b,d</i>]pyran-6-ones and a Total Synthesis of Cannabinol","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Enamine; Domino; Pyran; Knoevenagel condensation; Total synthesis; Diene; Organic chemistry; Medicinal chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01340430677496934,"gpt":0.1930730665576259,"spread":0.1796687597826566,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001738943,0.0003360399,0.0006615195,0.0001389509,0.00006393569,0.0000126582,0.0004079371,0.0001426908,0.001438745],"category_scores_gemma":[0.0007494212,0.0003200285,0.0001611811,0.0001419662,0.0004332132,0.0001555468,0.0001550214,0.0001466266,0.00001640555],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006218445,"about_ca_system_score_gemma":0.00004648762,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004519298,"about_ca_topic_score_gemma":0.00001402768,"domain_scores_codex":[0.9981689,0.00006543924,0.0006120156,0.0004364359,0.0003420665,0.0003751482],"domain_scores_gemma":[0.9980623,0.000705564,0.0004119738,0.0006278979,0.00007071065,0.0001215677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001054121,0.0002075397,0.007574594,0.0004457759,0.0002746944,0.00001655165,0.001773678,7.621477e-7,0.98535,0.00003244135,0.000192211,0.004026385],"study_design_scores_gemma":[0.0003081373,0.00001313566,0.01479478,0.0002973851,0.0001412831,0.00003183456,0.0008880949,0.00002134158,0.9831312,0.00001291724,0.0000447633,0.0003150835],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975029,0.0001365823,0.00004363549,0.0007463047,0.00006186042,0.0001053976,0.00006893072,0.00007503128,0.001259309],"genre_scores_gemma":[0.9977273,0.0000343343,0.001906191,0.000124763,0.00005243881,0.00004870903,0.000001493355,0.00007426932,0.00003045885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00722019,"threshold_uncertainty_score":0.9999252,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1964551161","doi":"10.1021/ol060266w","title":"Total Synthesis of (−)-Xyloketal A","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"British Columbia Knowledge Development Fund","keywords":"Chemistry; Boron trifluoride; Hydroxymethyl; Acetal; Total synthesis; Electrophile; Phloroglucinol; Natural product; Bicyclic molecule; Organic chemistry; Stereochemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.004669815426792244,"gpt":0.1820802279118016,"spread":0.1774104124850094,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006091259,0.0001481726,0.0002184699,0.00004802605,0.00003750932,0.00001612993,0.0002187318,0.00006687696,0.002966929],"category_scores_gemma":[0.0001899801,0.0001459873,0.0001042249,0.0001025143,0.0001173679,0.00008460061,0.0000489463,0.00008770992,0.00009461965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005718732,"about_ca_system_score_gemma":0.00002115712,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007698129,"about_ca_topic_score_gemma":0.000004357648,"domain_scores_codex":[0.9990741,0.00001581766,0.000253619,0.0002151833,0.000217973,0.0002233008],"domain_scores_gemma":[0.9992238,0.0002687229,0.0001280423,0.0003271869,0.00002090732,0.00003136909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000138293,0.00005545441,0.002713639,0.00004257151,0.00003963984,0.00001282219,0.00004754191,0.000003566839,0.9939377,0.00005909628,0.002146682,0.0009274215],"study_design_scores_gemma":[0.0001578847,0.000002713046,0.006073277,0.00004439696,0.00002431035,0.00002067693,0.00009540499,0.000008981073,0.9932258,0.00001856089,0.0001709729,0.0001570263],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991887,0.00004189933,0.00007936012,0.001226456,0.00004270684,0.00002509685,0.00001454078,0.00008201251,0.006600916],"genre_scores_gemma":[0.9989163,0.000001341029,0.0005383335,0.0001456591,0.0002041823,0.000009108954,0.000004143947,0.00003755047,0.0001433523],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007029317,"threshold_uncertainty_score":0.9979445,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2149530860","doi":"10.1139/v03-184","title":"Photogeneration of 1,5-naphthoquinone methides via excited-state (formal) intramolecular proton transfer (ESIPT) and photodehydration of 1-naphthol derivatives in aqueous solution","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Quinone methide; Photochemistry; Aqueous solution; Flash photolysis; Intramolecular force; Naphthoquinone; Excited state; Photodissociation; Quinone; Organic chemistry; Kinetics; Reaction rate constant","retraction":null,"screen_n_in":null,"score":{"opus":0.009196780851407156,"gpt":0.2076317647689669,"spread":0.1984349839175597,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003916819,0.0002330013,0.0004554407,0.0002202792,0.00006557096,0.00002967132,0.0002159269,0.0002123826,0.0001323225],"category_scores_gemma":[0.0002940545,0.0002249492,0.000119827,0.0002287934,0.0003366247,0.0004287366,0.00001026604,0.000313674,2.357024e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002492617,"about_ca_system_score_gemma":0.0008646659,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001328539,"about_ca_topic_score_gemma":0.0008617017,"domain_scores_codex":[0.9982313,0.00004172379,0.0009389731,0.0001978276,0.0002758209,0.0003143456],"domain_scores_gemma":[0.9987066,0.00006131557,0.0004498757,0.0001952475,0.0003300894,0.0002568499],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001219718,0.0000538427,0.001235375,0.0005808654,0.000078667,0.00006760415,0.002993217,0.0007464754,0.9909908,0.000006122018,0.00000262129,0.003122469],"study_design_scores_gemma":[0.001181469,0.00005468518,0.0006253615,0.0006529266,0.00002615277,0.0002316695,0.0007132079,0.0001568196,0.9954389,0.0006782442,0.0000342068,0.0002064037],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921843,0.0008653985,0.006268515,0.0001414861,0.00001969594,0.0001720256,0.00002682724,0.000005827042,0.0003159715],"genre_scores_gemma":[0.9984925,0.00007723438,0.001281262,0.00002636394,0.0000464232,0.00002009802,0.00001529562,0.00002767795,0.00001308642],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006308306,"threshold_uncertainty_score":0.9173161,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2009838848","doi":"10.1139/v08-172","title":"A catalyst-free protocol for the green and efficient condensation of indoles with aldehydes in ionic liquids","year":2009,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"","keywords":"Ionic liquid; Chemistry; Catalysis; Bromide; Condensation; Microwave irradiation; Organic chemistry; Condensation reaction; Indole test; Reaction conditions","retraction":null,"screen_n_in":null,"score":{"opus":0.01377002187791024,"gpt":0.2418373415577777,"spread":0.2280673196798674,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002314997,0.0001230817,0.0002163203,0.00005849352,0.00005963431,0.00002827483,0.0003670894,0.0000882249,0.00006335777],"category_scores_gemma":[0.0004105353,0.00008686012,0.00005442653,0.00008913274,0.0001896431,0.00005258968,0.000009013863,0.0001750025,8.741399e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001138095,"about_ca_system_score_gemma":0.000790242,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000421725,"about_ca_topic_score_gemma":0.001486043,"domain_scores_codex":[0.9991729,0.000008639736,0.0003612656,0.0001096465,0.0001578347,0.0001897664],"domain_scores_gemma":[0.9988528,0.0001855953,0.0003532046,0.0002521823,0.0001886839,0.0001675596],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001280004,0.000157723,0.01638221,0.001495916,0.000250922,0.0001161899,0.004414493,0.001164031,0.9638126,0.00009555261,0.0007512675,0.01007912],"study_design_scores_gemma":[0.00233721,0.0000756168,0.005106899,0.0008353423,0.00002417913,0.0001723633,0.001322159,0.0001324549,0.9890463,0.0003102721,0.0004985814,0.0001386381],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946694,0.0001342583,0.00002961801,0.001273396,0.000005315575,0.002989207,0.00002352114,0.000003045153,0.0008722532],"genre_scores_gemma":[0.998314,8.298658e-7,0.0001796843,0.00003901543,0.00008584949,0.001292907,0.000001544154,0.00001074217,0.0000753835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02523372,"threshold_uncertainty_score":0.3542053,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2059697216","doi":"10.1021/ja0120375","title":"Flash Photolytic Generation of <i>o</i>-Quinone α-Phenylmethide and <i>o</i>-Quinone α-(<i>p</i>-Anisyl)methide in Aqueous Solution and Investigation of Their Reactions in that Medium. Saturation of Acid-Catalyzed Hydration","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Protonation; Quinone methide; Flash photolysis; Aqueous solution; Benzyl alcohol; Photochemistry; Catalysis; Kinetic isotope effect; Quinone; Nucleophile; Solvent; Reaction rate constant; Acid catalysis; Reaction intermediate; Alcohol; Medicinal chemistry; Organic chemistry; Kinetics; Ion","retraction":null,"screen_n_in":null,"score":{"opus":0.02746723376502749,"gpt":0.2474905961305569,"spread":0.2200233623655294,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008407073,0.000202096,0.0006501618,0.00009655939,0.00004763117,0.00001519119,0.000217871,0.0001617478,0.000008160595],"category_scores_gemma":[0.0008240215,0.0001605206,0.0002086316,0.0005315743,0.0007909765,0.0003790651,0.0000823673,0.0004626382,9.227922e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001913659,"about_ca_system_score_gemma":0.0001424014,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003210096,"about_ca_topic_score_gemma":0.00007144811,"domain_scores_codex":[0.9978856,0.0001648894,0.001094841,0.0002153546,0.0004544446,0.0001848894],"domain_scores_gemma":[0.9961748,0.0005147251,0.002775688,0.0002493478,0.0002125018,0.00007296717],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001617835,0.00009629968,0.01984722,0.0001077532,0.00007371895,7.308e-7,0.002572208,0.00004606605,0.9746023,0.000007768936,0.00004796215,0.002436172],"study_design_scores_gemma":[0.0008345581,0.00004495202,0.01402197,0.0003181084,0.00006417809,0.00006196085,0.001647864,0.002180737,0.9802456,0.0004346899,0.00001522614,0.0001301835],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977199,0.0005404473,0.0003937169,0.00111445,0.00004090029,0.0001246969,0.00001085785,0.000006843905,0.00004816431],"genre_scores_gemma":[0.9934288,0.00112694,0.005208963,0.00009716555,0.0000945479,0.000007046352,0.00001096802,0.00001859731,0.000006953762],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005825248,"threshold_uncertainty_score":0.6545839,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2324156760","doi":"10.1021/ol201102x","title":"A Highly Efficient Access to Spiroketals, Mono-unsaturated Spiroketals, and Furans: Hg(II)-Catalyzed Cyclization of Alkyne Diols and Triols","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval","funders":"","keywords":"Alkyne; Chemistry; Regioselectivity; Catalysis; Aqueous solution; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02097135637637359,"gpt":0.226647012957954,"spread":0.2056756565815804,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001591305,0.00034414,0.000508627,0.0001624149,0.0001299047,0.00008064075,0.0004236745,0.0001473938,0.0003259205],"category_scores_gemma":[0.000286261,0.0003171344,0.00006515961,0.0003386247,0.0001835,0.0002614447,0.0002680166,0.0001447714,0.00001098362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004746566,"about_ca_system_score_gemma":0.00002642939,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004918361,"about_ca_topic_score_gemma":0.000007127197,"domain_scores_codex":[0.9982384,0.00004567108,0.0005217018,0.0005794535,0.0002581615,0.0003565986],"domain_scores_gemma":[0.9988358,0.0001436714,0.0002852225,0.0005018911,0.00005608457,0.0001773342],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001348201,0.0001065618,0.003699601,0.0001271092,0.0001147066,0.0000111671,0.002206029,0.000006128151,0.9916662,0.00001999749,0.0001458163,0.001761846],"study_design_scores_gemma":[0.0009965168,0.00003039668,0.03182975,0.0001776662,0.00007554059,0.00001605811,0.0002850071,0.000056962,0.9660333,0.0000168894,0.0001226888,0.0003591904],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964972,0.0003494066,0.0007486441,0.001555075,0.00007205306,0.000318925,0.00003653598,0.0001093942,0.0003128083],"genre_scores_gemma":[0.9984083,0.00007561551,0.0005142156,0.0007878484,0.00006694748,0.00002602135,0.00002907058,0.00006376552,0.00002827272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02813015,"threshold_uncertainty_score":0.9999281,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2095504936","doi":"10.1021/ol047578o","title":"Phenylboronic Acid Mediated Triple Condensation Reactions of Phloroglucinol and Unsaturated Carbonyl Compounds","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Simon Fraser University","funders":"British Columbia Knowledge Development Fund; Universities Space Research Association","keywords":"Chemistry; Phloroglucinol; Phenylboronic acid; Condensation; Organic chemistry; Condensation reaction; Medicinal chemistry; Stereochemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01004811329629824,"gpt":0.2109108843708963,"spread":0.200862771074598,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001032157,0.0001847391,0.0002544751,0.0000780585,0.00007674419,0.00002638079,0.0001595867,0.0001195676,0.0009624962],"category_scores_gemma":[0.0002390037,0.0001875487,0.00004647605,0.0001819264,0.000159852,0.0002025218,0.000034453,0.0001987722,0.00002927586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001838089,"about_ca_system_score_gemma":0.00005405108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005119064,"about_ca_topic_score_gemma":0.00004102577,"domain_scores_codex":[0.998885,0.00003620144,0.0003621973,0.0002714086,0.0002156806,0.0002294552],"domain_scores_gemma":[0.9991086,0.0002022878,0.0002402515,0.0003159213,0.00006272555,0.0000702662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002772238,0.00004156533,0.0007832742,0.00003610058,0.00009473988,0.000001903187,0.0005437706,0.000003095935,0.9972057,0.00002412769,0.0005070007,0.000730954],"study_design_scores_gemma":[0.001022739,0.000008878276,0.00325001,0.00004290387,0.00004208838,0.00001963845,0.0003772344,0.0002499652,0.9936253,0.000009246069,0.001163621,0.0001883035],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994321,0.0002284173,0.0000327624,0.00430064,0.00006279143,0.00007414162,0.0000258871,0.0001317366,0.000822651],"genre_scores_gemma":[0.9988425,0.00004068156,0.0003059732,0.0004972004,0.000139075,0.000008396843,0.00005086878,0.0000379567,0.00007732179],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004521554,"threshold_uncertainty_score":0.9999508,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2345951767","doi":"10.1139/cjc-2015-0629","title":"Trityl chloride promoted the synthesis of 3-(2,6-diarylpyridin-4-yl)-1H-indoles and 2,4,6-triarylpyridines by in situ generation of trityl carbocation and anomeric based oxidation in neutral media","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"","keywords":"Chemistry; Carbocation; In situ; Ammonium acetate; Solvent; Chloride; Anomer; Ammonium chloride; Condensation; Organic chemistry; Medicinal chemistry; High-performance liquid chromatography","retraction":null,"screen_n_in":null,"score":{"opus":0.01475086678623377,"gpt":0.2009507153381234,"spread":0.1861998485518897,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006588361,0.000200334,0.000460399,0.0002173343,0.00004544247,0.00002700345,0.0002545768,0.0001874289,0.00005756474],"category_scores_gemma":[0.002505187,0.0001525415,0.00006876858,0.0002602639,0.000320408,0.0001860462,0.00001276625,0.0001875888,1.23342e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001773947,"about_ca_system_score_gemma":0.0006876921,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009969509,"about_ca_topic_score_gemma":0.004157871,"domain_scores_codex":[0.998472,0.00007550833,0.000798034,0.0002122341,0.000202967,0.0002392554],"domain_scores_gemma":[0.9978355,0.0008528048,0.0006882204,0.0002168513,0.0001927369,0.0002139377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001092558,0.00003042609,0.02017591,0.0001732241,0.00002735902,0.000009318914,0.0003004425,0.00000969626,0.9739078,0.000004118994,0.00005260942,0.005199841],"study_design_scores_gemma":[0.001244245,0.00001309154,0.01467655,0.0005442124,0.00003139296,0.00002241409,0.0004319825,0.00009791562,0.9826779,0.00008453951,0.00002495508,0.0001508165],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996992,0.00108033,0.00001714568,0.001546062,0.00004297195,0.00009004404,0.00005748019,0.000003591287,0.0001703609],"genre_scores_gemma":[0.9995117,0.0002042617,0.00007041764,0.00001366912,0.0001459211,0.00001284007,0.00001241866,0.0000197102,0.000009025117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00877009,"threshold_uncertainty_score":0.6220463,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2050903553","doi":"10.1139/v04-138","title":"Total synthesis of ()-xyloketal D and its enantiomer Confirmation of absolute stereochemistry","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"Simon Fraser University","keywords":"Chemistry; Diastereomer; Morpholine; Enantiomer; Chiral auxiliary; Total synthesis; Absolute configuration; Stereochemistry; Quinone methide; Enantioselective synthesis; Quinone; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.009204875166548115,"gpt":0.2000630439423116,"spread":0.1908581687757635,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001783912,0.0001950185,0.0004577245,0.00008597253,0.00004799251,0.0000223697,0.0002963947,0.0002055339,0.0008715634],"category_scores_gemma":[0.0008392902,0.000201042,0.0001638298,0.0001034493,0.0002517741,0.0001796251,0.00002009728,0.0002279126,0.000001622228],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001280918,"about_ca_system_score_gemma":0.0009632249,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002469791,"about_ca_topic_score_gemma":0.00004326002,"domain_scores_codex":[0.9985766,0.000009336392,0.0007406162,0.0001506796,0.0002631291,0.0002595688],"domain_scores_gemma":[0.9980118,0.0001501956,0.0008456443,0.0002183495,0.0003554292,0.0004186377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003086418,0.00002958165,0.0007020702,0.000824396,0.0001594671,0.00004936444,0.0003690798,0.00003324386,0.9966724,0.0000162337,0.00004816789,0.001065115],"study_design_scores_gemma":[0.0005644196,0.000009779718,0.001046539,0.0009558665,0.00005865041,0.000546094,0.0009566165,0.000008096852,0.99547,0.00008000316,0.0001313822,0.0001725585],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894899,0.001296991,0.00001063794,0.0001836877,0.00004054383,0.00002329975,0.0001367451,0.00000471307,0.008813445],"genre_scores_gemma":[0.9994285,0.00004087082,0.0002183649,0.000008591144,0.0001239679,0.000002024266,0.000004802336,0.00002226757,0.0001506454],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009938528,"threshold_uncertainty_score":0.9543008,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2036825202","doi":"10.1021/jm501997q","title":"Synthesis and Biological Evaluation of Indolyl-Pyridinyl-Propenones Having Either Methuosis or Microtubule Disruption Activity","year":2015,"lang":"en","type":"article","venue":"Journal of Medicinal Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"National Cancer Institute; National Institutes of Health; McMaster University","keywords":"Chemistry; Microtubule; Cytotoxicity; Substituent; Stereochemistry; Structure–activity relationship; Chemical synthesis; Lead compound; Phenotypic screening; In vitro; Biochemistry; Cell biology; Phenotype; Biology","retraction":null,"screen_n_in":null,"score":{"opus":0.1492985222292273,"gpt":0.3488335996908611,"spread":0.1995350774616338,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.003223786,0.0002269353,0.000609085,0.00006377351,0.00005192708,0.0000237754,0.0002998332,0.0002445156,0.0009452275],"category_scores_gemma":[0.008583204,0.0001500769,0.0001204386,0.0001223977,0.0002868155,0.0002245404,0.00008596573,0.000375404,0.000001612533],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000207359,"about_ca_system_score_gemma":0.000345686,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002016586,"about_ca_topic_score_gemma":0.000001362649,"domain_scores_codex":[0.9977089,0.0001564214,0.0006193967,0.0002305962,0.001080284,0.0002043997],"domain_scores_gemma":[0.9969583,0.0007841054,0.001053942,0.0002323209,0.0007409718,0.000230369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009560336,0.0001806355,0.007824015,0.0002121323,0.0001624318,0.00001989572,0.0004214048,0.000007552212,0.948627,5.176987e-7,0.0001425579,0.04144584],"study_design_scores_gemma":[0.001253305,0.00008692189,0.005345921,0.0008110753,0.0003287964,0.0004517453,0.003381074,0.000165249,0.9877917,0.00007445052,0.0001431344,0.0001666992],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961597,0.001354815,0.00006986802,0.0004086021,0.00006243648,0.00006198677,0.000009383182,0.00001194501,0.001861286],"genre_scores_gemma":[0.998442,0.0001604295,0.0008510321,0.00001513126,0.0004302764,0.00001235804,0.000001500176,0.00002050314,0.0000667477],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04127914,"threshold_uncertainty_score":0.9999681,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2002766420","doi":"10.1021/jo4017524","title":"Scandium Triflate-Catalyzed Nucleophilic Additions to Indolylmethyl Meldrum’s Acid Derivatives via a Gramine-Type Fragmentation: Synthesis of Substituted Indolemethanes","year":2013,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Western University","funders":"","keywords":"Scandium; Nucleophile; Trifluoromethanesulfonate; Moiety; Chemistry; Catalysis; Meldrum's acid; Fragmentation (computing); Medicinal chemistry; Organic chemistry; Nucleophilic addition; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01143820529730785,"gpt":0.229198946516624,"spread":0.2177607412193161,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005414914,0.0004011607,0.0007508077,0.0001360866,0.0001847972,0.00005799887,0.001188958,0.0002264101,0.01276569],"category_scores_gemma":[0.003079995,0.0003082157,0.0002290256,0.0007875588,0.0003334283,0.0003871477,0.0001735901,0.0005206304,0.00007493095],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001546165,"about_ca_system_score_gemma":0.0002707386,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003404649,"about_ca_topic_score_gemma":0.000003431928,"domain_scores_codex":[0.9973795,0.0001101349,0.001201192,0.0002581104,0.0006636344,0.000387451],"domain_scores_gemma":[0.9955418,0.001397901,0.001299173,0.0006931585,0.0008042531,0.000263708],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002645647,0.0001984956,0.0004216026,0.0001735415,0.0004954429,0.000007399023,0.001360311,0.00001210216,0.99415,0.000001386315,0.0005173275,0.002397786],"study_design_scores_gemma":[0.0008419311,0.00002968834,0.002557984,0.0003700467,0.0002339358,0.0002319879,0.003628312,0.00000776542,0.9914692,0.000238888,0.00008380234,0.0003064803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969034,0.0004412977,0.0003432168,0.001301338,0.0001058909,0.000174913,0.00004763603,0.00004366145,0.0006386465],"genre_scores_gemma":[0.9975917,0.0001340255,0.0016306,0.00006376282,0.0003618634,0.00002589218,0.00002072728,0.00006743673,0.0001040354],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01269076,"threshold_uncertainty_score":0.999937,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2950181568","doi":"10.1021/jo900526p","title":"β,β-Disubstituted <i>C</i>- and <i>N</i>-Vinylindoles from One-Step Condensations of Aldehydes and Indole Derivatives","year":2009,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Indole test; Acetonitrile; Condensation; Medicinal chemistry; Aryl; Alkyl; Microwave irradiation; BETA (programming language); Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01295624943180519,"gpt":0.2205064155674986,"spread":0.2075501661356935,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002644373,0.000219077,0.0004492418,0.00003022696,0.0001180549,0.00003705929,0.0003872491,0.0001398321,0.000590102],"category_scores_gemma":[0.0006707104,0.0001696996,0.00006855367,0.000119012,0.0004153506,0.0001844761,0.00008004872,0.0003566465,9.602562e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003377123,"about_ca_system_score_gemma":0.0001088925,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000887071,"about_ca_topic_score_gemma":0.0000032202,"domain_scores_codex":[0.998694,0.00003980763,0.0006189659,0.0001579651,0.000313485,0.0001757761],"domain_scores_gemma":[0.99787,0.0007405438,0.0007821161,0.0002946154,0.0001970344,0.0001156838],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001035019,0.000110811,0.002390906,0.00005919087,0.0001748491,0.000004575535,0.001158592,0.000002347663,0.9942213,0.0000126794,0.00005730471,0.001703931],"study_design_scores_gemma":[0.001040495,0.00002440178,0.01153335,0.0003542686,0.0001524089,0.0001156388,0.002888112,0.00001572409,0.9826466,0.0009893593,0.00007252565,0.0001671359],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942959,0.003276744,0.0002631841,0.0008550709,0.00001741358,0.00003814093,0.00002968305,0.0000186515,0.001205223],"genre_scores_gemma":[0.9972904,0.0006119006,0.00176905,0.00008897662,0.000159578,5.918433e-7,0.000005031948,0.0000194497,0.00005497873],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01157473,"threshold_uncertainty_score":0.692015,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2952036626","doi":"10.1055/s-0030-1260146","title":"Waste-Free Catalytic Propargylation/Allenylation of Aryl and Heteroaryl Nucleophiles and Synthesis of Naphthopyrans","year":2011,"lang":"en","type":"article","venue":"Synthesis","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"University of Winnipeg","keywords":"Chemistry; Carbocation; Friedel–Crafts reaction; Propargyl; Catalysis; Aryl; Organic chemistry; Electrophilic aromatic substitution; Nucleophilic aromatic substitution; Nucleophilic substitution; Nucleophile; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02176706562098367,"gpt":0.2030024306876816,"spread":0.1812353650666979,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002631869,0.0002739609,0.000549012,0.0001912774,0.00008263141,0.00001473756,0.0003321507,0.0001724661,0.0003285056],"category_scores_gemma":[0.001845767,0.0002571393,0.000106777,0.0001184442,0.0005044134,0.0002739558,0.0001502749,0.00008728785,0.000003643821],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002176678,"about_ca_system_score_gemma":0.00003116132,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001548381,"about_ca_topic_score_gemma":0.00002084928,"domain_scores_codex":[0.9984471,0.00003313918,0.0005833262,0.0004103254,0.0002929318,0.0002332282],"domain_scores_gemma":[0.99744,0.001236159,0.0004243804,0.0006969412,0.0001073166,0.00009519375],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005140507,0.000611882,0.06451504,0.002625879,0.000666733,0.00001072238,0.005954647,0.000006909546,0.8419289,0.001134875,0.00006317421,0.08196717],"study_design_scores_gemma":[0.0002403749,0.00002469139,0.02436149,0.0005246275,0.0001617255,0.00001173798,0.001593628,0.0001773327,0.9715884,0.001052806,0.00001264671,0.0002504853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885131,0.0004990177,0.00004277866,0.0001144554,0.00002092164,0.0001294134,0.0001137061,0.00005243998,0.01051422],"genre_scores_gemma":[0.9967909,0.000190124,0.002831386,0.000005255692,0.00003809813,0.00005886811,0.000002643781,0.00004851612,0.00003414966],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1296595,"threshold_uncertainty_score":0.9999881,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2046657780","doi":"10.1139/v07-143","title":"Photochemistry of 1,1′-bi-2-naphthol (BINOL) — ESIPT is responsible for photoracemization and photocyclization","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Racemization; Photochemistry; Deuterium; Intramolecular force; Ring (chemistry); Hydrogen–deuterium exchange; Photodissociation; Stereochemistry; Hydrogen; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02051526316387926,"gpt":0.2293912155888664,"spread":0.2088759524249872,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002077559,0.0002370246,0.0004227397,0.0001122239,0.0001780067,0.00003279571,0.000334533,0.0002924449,0.001071207],"category_scores_gemma":[0.001182038,0.0002610881,0.000167214,0.0001704125,0.0003321914,0.0002006915,0.00001538343,0.0002199137,8.34893e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000174017,"about_ca_system_score_gemma":0.001839782,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001585059,"about_ca_topic_score_gemma":0.00003802251,"domain_scores_codex":[0.9984688,0.00001315817,0.0006968302,0.0002443499,0.0002575884,0.0003193154],"domain_scores_gemma":[0.9975732,0.0002299036,0.0007736633,0.0003215019,0.0006181102,0.0004836074],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001772966,0.00002631075,0.005774155,0.0004631332,0.00008172866,0.00003798517,0.0007729906,0.00001593663,0.9881164,0.000003737383,0.004309829,0.0002205353],"study_design_scores_gemma":[0.001041481,0.00001946626,0.0002556905,0.0003436224,0.00003653104,0.0005633024,0.0006572372,0.00009252677,0.9899253,0.0001302243,0.006700941,0.0002337016],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936521,0.0008921436,0.0002524803,0.000212132,0.00004204966,0.0001193414,0.0001460502,0.00001174647,0.004671937],"genre_scores_gemma":[0.9961596,0.0001053487,0.001891072,0.00009665732,0.000203788,0.0000221762,0.00002794745,0.00004812061,0.001445334],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005518464,"threshold_uncertainty_score":0.9999841,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1963877715","doi":"10.1351/pac200173030529","title":"Quinone methide intermediates in organic photochemistry","year":2001,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Quinone methide; Quinone; Intramolecular force; Photochemistry; Reactive intermediate; Excited state; Ring (chemistry); Aqueous solution; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.007426244091540352,"gpt":0.2139315033728145,"spread":0.2065052592812741,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001138766,0.000324429,0.0003661407,0.00002592763,0.00006035693,0.00005427387,0.0003436965,0.0003224507,0.005359854],"category_scores_gemma":[0.0001388734,0.0003346898,0.00005717364,0.0001666462,0.0001798153,0.00005949679,0.0001569835,0.000462132,0.00002663416],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006885604,"about_ca_system_score_gemma":0.00004787106,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007637789,"about_ca_topic_score_gemma":0.000005479477,"domain_scores_codex":[0.9984565,0.000004475559,0.000358651,0.0005429098,0.0002093841,0.0004280134],"domain_scores_gemma":[0.9990935,0.0001816849,0.0001266159,0.0004170417,0.00002564692,0.0001555643],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006227,0.00009531678,0.004067978,0.0002636773,0.00003552972,0.0000339323,0.000242547,8.609036e-7,0.9911399,0.00001490357,0.0001493807,0.003893627],"study_design_scores_gemma":[0.0007075868,0.000001870626,0.0003303464,0.0001024859,0.00001727608,0.00006651291,0.001539618,0.00001325079,0.9935099,0.0006363885,0.002710111,0.0003646409],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8615723,0.0004245962,0.000009684205,0.0001619058,0.00001158662,0.00005116637,0.000008572505,0.000108133,0.137652],"genre_scores_gemma":[0.9972094,0.0002135829,0.0002127506,0.0001121533,0.0002699823,0.0001137046,0.00004623664,0.00004672243,0.001775446],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1358766,"threshold_uncertainty_score":0.9999105,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2056342283","doi":"10.1016/j.ejmech.2009.11.006","title":"Structure–activity relationships and mechanism of action of antitumor bis 8-hydroxyquinoline substituted benzylamines","year":2009,"lang":"en","type":"article","venue":"European Journal of Medicinal Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Institute of Cancer Research; Institut National Du Cancer; Centre National de la Recherche Scientifique; Ligue Contre le Cancer","keywords":"Chemistry; Mechanism of action; Quinone methide; Adduct; Biochemistry; Structure–activity relationship; Stereochemistry; Biological activity; DNA; Cancer cell; Cancer; In vitro; Quinone; Organic chemistry; Biology","retraction":null,"screen_n_in":null,"score":{"opus":0.0302971202330715,"gpt":0.2494872148490221,"spread":0.2191900946159507,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006165063,0.0001955792,0.0004507126,0.0000875369,0.00005924169,0.000009258005,0.0002671387,0.00007140267,0.0001869507],"category_scores_gemma":[0.001184694,0.000169366,0.0001002381,0.0001356787,0.00019314,0.0001775897,0.00002983082,0.000526372,3.525466e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003408908,"about_ca_system_score_gemma":0.00007441946,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002336764,"about_ca_topic_score_gemma":3.864558e-7,"domain_scores_codex":[0.9984142,0.00009880737,0.0007088028,0.0001656582,0.0004635876,0.0001489081],"domain_scores_gemma":[0.997851,0.00018721,0.001312958,0.0002350473,0.000281123,0.0001327162],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001802059,0.00008985608,0.001055372,0.0002706272,0.00007202524,0.00008839826,0.0001885976,0.0000153994,0.994365,0.00003930986,0.00004005635,0.003595203],"study_design_scores_gemma":[0.0009721151,0.00008794657,0.02017322,0.0006343225,0.00009866367,0.000593625,0.0004329074,0.00005390672,0.9766019,0.0001662177,0.00005886342,0.0001263347],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952546,0.0005070247,0.0005385393,0.0002460742,0.00006342051,0.00002388004,0.00001881549,0.00001385606,0.003333809],"genre_scores_gemma":[0.9984906,0.0001225519,0.000898229,0.000009523063,0.0004013724,9.999799e-8,0.000005368861,0.00001858378,0.00005362564],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01911785,"threshold_uncertainty_score":0.6906544,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2067316770","doi":"10.1139/v06-159","title":"Efficient Ru<sup>III</sup>-catalyzed condensation of indoles and aldehydes or ketones","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"","keywords":"Chemistry; Ruthenium; Catalysis; Condensation; Ketone; Organic chemistry; Aldehyde; Indole test; Medicinal chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.009817550868849747,"gpt":0.2053215632627045,"spread":0.1955040123938547,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002000415,0.0002052831,0.0003969528,0.0001044839,0.00009259166,0.00005572591,0.0002901473,0.0001821674,0.0008199943],"category_scores_gemma":[0.0004456515,0.0001846335,0.0001084326,0.0001160213,0.0003709144,0.00007190654,0.00001799153,0.0002246027,0.000001738914],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001410843,"about_ca_system_score_gemma":0.0008673587,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00120047,"about_ca_topic_score_gemma":0.0005020744,"domain_scores_codex":[0.9986287,0.00001541278,0.0006359479,0.0001758849,0.0002569537,0.0002870605],"domain_scores_gemma":[0.9983773,0.0002233594,0.0005544734,0.0002257483,0.0002766843,0.0003424475],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001392902,0.00005586291,0.01134906,0.0004318935,0.0001272558,0.0001707833,0.0008775112,0.001541668,0.9834138,0.00002368483,0.0007318406,0.00113735],"study_design_scores_gemma":[0.0009998434,0.000008658949,0.001987553,0.0004086391,0.00004217714,0.0004022607,0.002610011,0.0002532823,0.9923994,0.0001296836,0.0005504683,0.0002080536],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942471,0.001169191,0.00001646289,0.00020754,0.000025227,0.00003169363,0.00005712792,0.000008703001,0.004236962],"genre_scores_gemma":[0.9989315,0.00001213657,0.0002408606,0.00001828285,0.0002757702,0.000002224953,0.00001275787,0.00002525017,0.0004811751],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009361504,"threshold_uncertainty_score":0.8978362,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2969584275","doi":"10.1021/acs.orglett.9b02613","title":"Construction of Spirocyclic Tetrahydro-β-carbolines via Cross-Annulation of Phenols with Tryptamines in Water","year":2019,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; E.B. Eddy Endowment Fund; Ministry of Education of the People's Republic of China; Canada Research Chairs; Canada Foundation for Innovation; Science and Technology Department of Gansu Province; Lanzhou University","keywords":"Tryptamines; Chemistry; Annulation; Phenols; Organic chemistry; Stereochemistry; Tryptamine; Catalysis; Biochemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.004713731288178487,"gpt":0.2023344651283768,"spread":0.1976207338401983,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006298358,0.0001549677,0.0002954964,0.0001027203,0.00001354707,0.00001132783,0.0001557632,0.00008806665,0.0008883741],"category_scores_gemma":[0.00004114616,0.0001169274,0.00004019232,0.0001537671,0.00017911,0.0001880253,0.00002771749,0.00009105475,0.00002475633],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004521957,"about_ca_system_score_gemma":0.00001238356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005483995,"about_ca_topic_score_gemma":0.00001006763,"domain_scores_codex":[0.9989792,0.00001613108,0.0003773269,0.0002348905,0.000208121,0.0001843797],"domain_scores_gemma":[0.9993391,0.00006907388,0.0001939916,0.0003118061,0.00006470727,0.00002132671],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006376082,0.00002878594,0.2644126,0.0001239896,0.00002941745,0.00000146513,0.0003591219,0.00007366245,0.7346101,0.000006195171,0.000002268732,0.0002885301],"study_design_scores_gemma":[0.0008359862,0.00001499045,0.05850662,0.0001023191,0.00001278482,0.00001227101,0.0001487337,0.00007788934,0.9401182,0.00002109499,0.00001109674,0.0001380181],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9992645,0.00001169121,0.0001186138,0.0002247962,0.00005851981,0.00008862436,0.00000371202,0.00002390329,0.0002056193],"genre_scores_gemma":[0.9990523,0.000001769483,0.000757085,0.00005028947,0.00006127953,0.000004618821,0.00001403524,0.00002906672,0.00002948054],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.205906,"threshold_uncertainty_score":0.9727073,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2145896637","doi":"10.1351/pac200072122299","title":"Reactive intermediates. Some chemistry of quinone methides","year":2000,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Protonation; Reaction rate constant; Quinone; Carbocation; Kinetic isotope effect; Photochemistry; Medicinal chemistry; Quinone methide; Aqueous solution; Benzyl alcohol; Catalysis; Thiocyanate; Organic chemistry; Ion; Kinetics; Deuterium","retraction":null,"screen_n_in":null,"score":{"opus":0.006897961745053184,"gpt":0.21065191256742,"spread":0.2037539508223668,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000981849,0.0003270804,0.0004653833,0.00001237973,0.00006608097,0.00002919992,0.000338683,0.0003263786,0.006776671],"category_scores_gemma":[0.00007306138,0.000325268,0.0001021552,0.00008099033,0.0003955123,0.00009637119,0.00008626593,0.0003739255,0.00002023324],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003981116,"about_ca_system_score_gemma":0.00004990959,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008062757,"about_ca_topic_score_gemma":2.165146e-7,"domain_scores_codex":[0.9985082,0.00000456114,0.0003948071,0.0004962308,0.0002601328,0.0003360452],"domain_scores_gemma":[0.9989341,0.0002078253,0.0001959395,0.0004681778,0.00004033821,0.0001536003],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001170694,0.0001154816,0.0001787521,0.0006332971,0.0001213199,0.000005487484,0.0003339389,0.000002254248,0.9803918,0.00003382966,0.0002187458,0.01784802],"study_design_scores_gemma":[0.0005247249,0.000002909681,0.0001001262,0.0001143802,0.00004825176,0.00002013715,0.0009374738,0.000008043078,0.9942338,0.001255086,0.002431032,0.0003239804],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8099731,0.0005538547,0.000001496723,0.00009332088,0.000006850949,0.00003783193,0.00004625547,0.00008159844,0.1892057],"genre_scores_gemma":[0.9961229,0.0001849904,0.0002368171,0.00005819535,0.0003402423,0.0000603188,0.0000593813,0.00004297689,0.00289417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1863115,"threshold_uncertainty_score":0.99992,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1997035863","doi":"10.1139/v07-051","title":"A solvent-free protocol for facile condensation of indoles with carbonyl compounds using silica chloride as a new, highly efficient, and mild catalyst","year":2007,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Electrophilic substitution; Indole test; Chloride; Solvent; Organic chemistry; Electrophile; Condensation; Condensation reaction; Methane; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02565540269025062,"gpt":0.2669059264585719,"spread":0.2412505237683212,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002654944,0.0002183119,0.0003752352,0.0001095134,0.0001109071,0.00005470978,0.0003687954,0.0001614456,0.00008110273],"category_scores_gemma":[0.0006432594,0.0002053756,0.0001008911,0.0001206121,0.0002676149,0.00008639966,0.00002117043,0.0002223489,2.12013e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000270673,"about_ca_system_score_gemma":0.002397984,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001766747,"about_ca_topic_score_gemma":0.001596609,"domain_scores_codex":[0.9985858,0.000005986979,0.0005761648,0.0001982874,0.0002765946,0.0003571972],"domain_scores_gemma":[0.9976968,0.0001790507,0.0007125409,0.0003125797,0.0003493472,0.0007496965],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005975568,0.00003193723,0.00390466,0.0005292111,0.0001293838,0.00004954091,0.0007766802,0.0001282594,0.9933525,0.000008973427,0.0003083817,0.000182959],"study_design_scores_gemma":[0.002882903,0.0000454551,0.0002595892,0.0006952778,0.00004571254,0.0003341544,0.001627066,0.00007174291,0.9924886,0.0000890724,0.001249776,0.0002106479],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995001,0.00005240969,0.0001885844,0.0001416756,0.00001839071,0.002644116,0.00008379507,0.000007246882,0.001862788],"genre_scores_gemma":[0.9981774,2.448625e-7,0.0009914421,0.00003009744,0.0002429988,0.0003739847,0.000006679175,0.00003226757,0.0001448705],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003645071,"threshold_uncertainty_score":0.8374972,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2903232780","doi":"10.1002/anie.201810870","title":"Electrochemical Dimerization of Phenylpropenoids and the Surprising Antioxidant Activity of the Resultant Quinone Methide Dimers","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Ottawa","funders":"National Institute of General Medical Sciences; National Science Foundation","keywords":"Autoxidation; Quinone methide; Chemistry; Radical; Phenols; Quinone; Dimer; Electrochemistry; Quenching (fluorescence); Antioxidant; Combinatorial chemistry; Organic chemistry; Photochemistry; Electrode","retraction":null,"screen_n_in":null,"score":{"opus":0.01110142339958418,"gpt":0.2483513878042263,"spread":0.2372499644046421,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003618682,0.0001286417,0.0001992705,0.00003691076,0.00009328203,0.00002109114,0.0003141434,0.00009249581,0.0001417173],"category_scores_gemma":[0.001436445,0.00008203674,0.00009275767,0.0001441317,0.0009244658,0.0001966033,0.0001219725,0.0001678573,9.713401e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000582637,"about_ca_system_score_gemma":0.00004559146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001206391,"about_ca_topic_score_gemma":0.000009476769,"domain_scores_codex":[0.9988396,0.00004693566,0.0003109059,0.0002121417,0.0004659237,0.0001245557],"domain_scores_gemma":[0.9984343,0.0004624087,0.0004516748,0.0002466565,0.0003805195,0.00002442967],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004739855,0.00005873543,0.0003997647,0.00002985561,0.0001199892,1.877599e-7,0.0005015481,4.510213e-7,0.9969198,0.0004854026,0.0001371916,0.0008731592],"study_design_scores_gemma":[0.0008122318,0.00001324743,0.00275691,0.0001647874,0.00004303532,0.000007300895,0.0001714501,0.000120085,0.9948572,0.0007048197,0.0002609563,0.00008797403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863844,0.00007906912,0.002858785,0.001297735,0.0002479249,0.00009178087,0.00004165393,0.00001899268,0.008979694],"genre_scores_gemma":[0.9988701,0.00008156992,0.0003108839,0.00004837985,0.0005360217,0.00001382617,0.0000209709,0.00001420187,0.0001040992],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01248568,"threshold_uncertainty_score":0.3406233,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2016097865","doi":"10.1039/c1pp05182b","title":"Sterically congested quinone methides in photodehydration reactions of 4-hydroxybiphenyl derivatives and investigation of their antiproliferative activity","year":2011,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"","keywords":"Steric effects; Chemistry; Quinone; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.08852189176438599,"gpt":0.279715352302379,"spread":0.191193460537993,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0006291348,0.000254886,0.0005634439,0.0001139958,0.00009358204,0.00001781412,0.0003634278,0.0002315146,0.0002815174],"category_scores_gemma":[0.001209725,0.0001795749,0.00008242512,0.0005282824,0.003108358,0.0003496957,0.0001460851,0.0002507652,7.270324e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003833263,"about_ca_system_score_gemma":0.00007296757,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004411493,"about_ca_topic_score_gemma":0.00002806573,"domain_scores_codex":[0.9980924,0.0002000236,0.0006237688,0.0005652495,0.000240802,0.0002777674],"domain_scores_gemma":[0.9978023,0.001236672,0.0005232337,0.0002000514,0.0001330254,0.0001047543],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002002534,0.0001904121,0.06472569,0.00005291063,0.00002473818,7.621105e-7,0.001638722,0.000001371812,0.9326237,0.0002028005,0.000001125022,0.0003374659],"study_design_scores_gemma":[0.000283386,0.0001887077,0.06166055,0.0001470724,0.000008703157,0.000004661972,0.001141978,0.0004728933,0.9312969,0.004601058,0.000003166094,0.0001909384],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960338,0.00007689076,0.00006800416,0.00005248664,0.00001556267,0.0003175755,0.00003301233,0.00004158632,0.003361119],"genre_scores_gemma":[0.9964549,0.00005319926,0.003295869,0.00003891113,0.00001321022,0.0001248984,0.000007156712,0.000007405788,0.000004454327],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004398257,"threshold_uncertainty_score":0.9996046,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2024646315","doi":"10.1021/jo902004n","title":"Photochemical Formation and Chemistry of Long-Lived Adamantylidene-Quinone Methides and 2-Adamantyl Cations","year":2009,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Photochemistry; Substituent; Moiety; Flash photolysis; Intramolecular force; Quinone; Singlet state; Excited state; Quantum yield; Photodissociation; Nucleophile; Reactivity (psychology); Alkyl; Medicinal chemistry; Stereochemistry; Organic chemistry; Fluorescence; Reaction rate constant; Kinetics","retraction":null,"screen_n_in":null,"score":{"opus":0.01284286404098903,"gpt":0.2401484254162444,"spread":0.2273055613752554,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004704515,0.0002324856,0.0004127154,0.0000238227,0.0001115862,0.00003612975,0.0004203025,0.0001895183,0.0008547996],"category_scores_gemma":[0.0007897665,0.0001810051,0.00008632296,0.0001238034,0.0002726407,0.0002287324,0.00008833863,0.0004488512,0.000001213954],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000748939,"about_ca_system_score_gemma":0.0001035468,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000339954,"about_ca_topic_score_gemma":6.746127e-7,"domain_scores_codex":[0.9985026,0.00002570512,0.0007383866,0.0001515652,0.0003719196,0.0002097889],"domain_scores_gemma":[0.9978951,0.0004615345,0.0008816272,0.0003576525,0.0002656648,0.0001383973],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001129943,0.00008348523,0.0003420984,0.0003131159,0.00008523063,0.000007913498,0.0009038569,0.000001957713,0.9969755,0.000001089467,0.0001344471,0.001038284],"study_design_scores_gemma":[0.0007060262,0.00001936053,0.001348762,0.000332543,0.0001598707,0.001546375,0.002170481,0.0000470431,0.9932175,0.0002457068,0.00003246223,0.000173846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949191,0.002400369,0.0001723825,0.0007694422,0.00001067997,0.00004725079,0.00000823919,0.00001846305,0.001654109],"genre_scores_gemma":[0.9982468,0.0008191642,0.0005285775,0.00004519279,0.0001703687,0.000001394958,0.000006008593,0.00001982489,0.0001626303],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003758003,"threshold_uncertainty_score":0.9359456,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2130725419","doi":"10.1002/chem.201201144","title":"Very Efficient Generation of Quinone Methides through Excited State Intramolecular Proton Transfer to a Carbon Atom","year":2012,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"","keywords":"Conical intersection; Intramolecular force; Chemistry; Photochemistry; Ring (chemistry); Proton; Excited state; Solvent; Naphthalene; Deuterium; Molecule; Stereochemistry; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.03495668263375334,"gpt":0.2500944969662327,"spread":0.2151378143324794,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008323761,0.0003286644,0.000350797,0.00004736284,0.0001171375,0.00008077624,0.0004084887,0.00006830663,0.0004112088],"category_scores_gemma":[0.000273409,0.0003113826,0.0001832325,0.0001965645,0.0001222492,0.000136805,0.00007517613,0.000485265,0.00001437204],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001303105,"about_ca_system_score_gemma":0.00007415032,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000395116,"about_ca_topic_score_gemma":9.07829e-8,"domain_scores_codex":[0.9977219,0.0002042516,0.0007257188,0.0003044923,0.0005159759,0.0005277122],"domain_scores_gemma":[0.9988096,0.00006314493,0.000166346,0.0004282219,0.0002069265,0.0003257237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001542817,0.0002445978,0.0002445881,0.0002391546,0.0001359489,0.00006603677,0.003892826,0.0005080723,0.9932017,0.000003816382,0.00008186619,0.001227134],"study_design_scores_gemma":[0.0006902698,0.00003550736,0.0001678553,0.0002470894,0.00005191995,0.0002157584,0.0004947342,0.0005396625,0.9938285,0.000005123041,0.003398296,0.0003252588],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825199,0.0004932318,0.008216166,0.0001265154,0.00008249753,0.0001517171,0.00001677563,0.00005513114,0.00833806],"genre_scores_gemma":[0.9964473,0.00003745337,0.002460384,0.00008861443,0.0007124989,0.00001861553,0.00001389856,0.00009153534,0.0001296596],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01392743,"threshold_uncertainty_score":0.9999338,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2432567559","doi":"10.1039/c6ob01026a","title":"Boronic acid/Brønsted acid co-catalyst systems for the synthesis of 2H-chromenes from phenols and α,β-unsaturated carbonyls","year":2016,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Phenols; Catalysis; Brønsted–Lowry acid–base theory; Boronic acid; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.008700747554778237,"gpt":0.2179923785486677,"spread":0.2092916309938894,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002318336,0.0005052557,0.0006709796,0.00003440159,0.0001697874,0.00009271512,0.0008309136,0.0004113322,0.0007513384],"category_scores_gemma":[0.001142872,0.0003361666,0.0002031785,0.0002061192,0.0005019092,0.000111642,0.0001589178,0.0001363732,0.00001610364],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001869473,"about_ca_system_score_gemma":0.0001886719,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007928134,"about_ca_topic_score_gemma":0.000003031506,"domain_scores_codex":[0.9976056,0.00004703702,0.0006433693,0.0007678695,0.0004150078,0.0005210946],"domain_scores_gemma":[0.9968252,0.001014287,0.0005126031,0.001293722,0.0001956398,0.000158542],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000973152,0.00006704024,0.0001953454,0.0004617602,0.0008156734,0.00001191906,0.000113585,7.395202e-8,0.9956863,0.000006199796,0.00014445,0.002400328],"study_design_scores_gemma":[0.00096635,0.00001172865,0.0000947361,0.0006245425,0.0003089557,0.00003557039,0.0009714189,0.00006013894,0.9955734,0.00002798612,0.000868277,0.000456922],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9757784,0.01569896,0.004635193,0.0005877644,0.0001024037,0.0003912156,0.001346662,0.0002066936,0.001252721],"genre_scores_gemma":[0.9985926,0.0004567415,0.000111335,0.00002162338,0.0001961459,0.0001835197,0.0000904183,0.0001199885,0.0002276483],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02281419,"threshold_uncertainty_score":0.999909,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2818585626","doi":"10.1002/anie.201806490","title":"A Bioinspired Synthesis of Polyfunctional Indoles","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Indole test; Combinatorial chemistry; Chemistry; Polymerization; Tyrosine; Melanin; Organic chemistry; Biochemistry; Polymer","retraction":null,"screen_n_in":null,"score":{"opus":0.01609273275042487,"gpt":0.2513423509289894,"spread":0.2352496181785645,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001142882,0.000156369,0.000171304,0.0001347091,0.00006906386,0.0000264084,0.000304683,0.0001268344,0.006249182],"category_scores_gemma":[0.0009077085,0.0001576351,0.0001228966,0.0001045201,0.0003053966,0.0002700863,0.00006456035,0.00009240911,0.00008297589],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001025048,"about_ca_system_score_gemma":0.00005267567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003621971,"about_ca_topic_score_gemma":0.000007952555,"domain_scores_codex":[0.9987376,0.00000940237,0.0003285881,0.0002668607,0.0005016221,0.000155957],"domain_scores_gemma":[0.9987622,0.0002953793,0.000251096,0.0002115007,0.0004251654,0.00005465985],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001559466,0.0001483946,0.003092943,0.00003330814,0.0001497952,0.000002338418,0.0001151059,7.032484e-7,0.9840782,0.0005508751,0.006983445,0.004688949],"study_design_scores_gemma":[0.0002950239,0.00001637503,0.003063011,0.0001911756,0.00002115468,0.0000134095,0.0002017955,0.00003180205,0.9873389,0.0006595413,0.008016713,0.0001510949],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7509968,0.00007957659,0.001782335,0.001598841,0.001439401,0.0000671259,0.0005424093,0.0001909433,0.2433026],"genre_scores_gemma":[0.9951964,0.00002188568,0.0007047477,0.000119494,0.003272434,0.00005104044,0.000157297,0.00002262246,0.0004540499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2441996,"threshold_uncertainty_score":0.9946592,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2129905098","doi":"10.1139/v07-125","title":"Chemistry of photogenerated α-phenyl-substituted <i>o</i>-, <i>m</i>-, and <i>p</i>-quinone methides from phenol derivatives in aqueous solution","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"","keywords":"Chemistry; Deprotonation; Aqueous solution; Photochemistry; Reactivity (psychology); Intramolecular force; Phenols; Quinone methide; Solvolysis; Substituent; Excited state; Quinone; Nucleophile; Phenol; Resorcinol; Medicinal chemistry; Organic chemistry; Ion; Hydrolysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01916742934694931,"gpt":0.20611231569198,"spread":0.1869448863450307,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002220398,0.0003902023,0.0007759303,0.0001071114,0.0001474177,0.00003511195,0.0005401293,0.0003938589,0.001235586],"category_scores_gemma":[0.001033843,0.0004223985,0.0001628615,0.0003174068,0.0007090563,0.0002771444,0.00004094606,0.0006275797,0.000001650839],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002734038,"about_ca_system_score_gemma":0.001745837,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003969317,"about_ca_topic_score_gemma":0.0007641157,"domain_scores_codex":[0.9976668,0.00004151566,0.001060294,0.0003708327,0.0003491404,0.0005114242],"domain_scores_gemma":[0.9974409,0.0002967964,0.0008328398,0.0003906841,0.0003916677,0.0006471176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009612373,0.00006116039,0.01153908,0.0001790029,0.0001704047,0.0004883692,0.001604435,0.00004128139,0.9847373,0.000001166621,0.0002878809,0.0007937714],"study_design_scores_gemma":[0.001338718,0.000009013623,0.001289459,0.0005197644,0.00004069931,0.0005714287,0.001135864,0.00006828377,0.9938124,0.0001164059,0.000722276,0.0003756978],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887334,0.007108484,0.00007107703,0.0001496945,0.00005827509,0.00005081331,0.0001576079,0.00001757244,0.0036531],"genre_scores_gemma":[0.99749,0.000336289,0.001607868,0.00006006665,0.000263301,0.00000707068,0.00004461548,0.00004885274,0.0001419578],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01024962,"threshold_uncertainty_score":0.9998228,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2022385096","doi":"10.1139/v2012-059","title":"2-Hydroxyethylammonium acetate as a reusable and cost-effective ionic liquid for the efficient synthesis of bis(pyrazolyl)methanes and 2-pyrazolyl-1-nitroalkanes","year":2012,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false},"ca_institutions":"","funders":"","keywords":"Chemistry; Ionic liquid; Pyrazolone; Knoevenagel condensation; Michael reaction; Alkyl; Organic chemistry; Aryl; Tandem; Reaction conditions; Combinatorial chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01107892163535353,"gpt":0.2343600430173208,"spread":0.2232811213819673,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008556027,0.000316276,0.0005718715,0.000101864,0.000255655,0.00006990784,0.0004344677,0.000228806,0.0002443566],"category_scores_gemma":[0.003008031,0.0002481948,0.0001914548,0.0001347184,0.0006374232,0.0001585667,0.0000502288,0.0003519465,0.000001291223],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001694619,"about_ca_system_score_gemma":0.0006056564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005082672,"about_ca_topic_score_gemma":0.0001130335,"domain_scores_codex":[0.9983143,0.00003211795,0.0005471787,0.0002343494,0.0002514147,0.0006206976],"domain_scores_gemma":[0.9953989,0.002577026,0.0006284719,0.0003701411,0.0002970978,0.0007283065],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004408513,0.00005518031,0.001757133,0.0006964759,0.0004915273,0.00002174898,0.001401302,0.0001068403,0.9880669,0.00002491334,0.0002533073,0.006683883],"study_design_scores_gemma":[0.0006149541,0.00004084921,0.0004901994,0.0004138412,0.0002176377,0.0005456649,0.00279898,0.00007043224,0.9887455,0.00004419472,0.005759113,0.0002586726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824411,0.01432773,0.00002528834,0.001006496,0.0001121178,0.0002895118,0.0000838456,0.000009068385,0.001704872],"genre_scores_gemma":[0.998813,0.0002251091,0.0001470244,0.00004142617,0.000344737,0.0001219559,0.000002242248,0.00004858194,0.0002558827],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01637197,"threshold_uncertainty_score":0.999997,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2112320873","doi":"10.1039/c1pp05338h","title":"Zwitterionic biphenyl quinone methides in photodehydration reactions of 3-hydroxybiphenyl derivatives: laser flash photolysis and antiproliferation study","year":2012,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Nucleophile; Flash photolysis; Deprotonation; Photochemistry; Protonation; Quenching (fluorescence); Zwitterion; Nucleophilic addition; Phenol; Reaction rate constant; Organic chemistry; Molecule; Kinetics","retraction":null,"screen_n_in":null,"score":{"opus":0.03982304742693073,"gpt":0.3058602495551674,"spread":0.2660372021282367,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001307019,0.0003738224,0.0006519072,0.0001895397,0.0002451952,0.00007648057,0.0004502986,0.0002536812,0.0008276724],"category_scores_gemma":[0.001566156,0.0002818592,0.0001221466,0.0008267983,0.001161756,0.0008103736,0.0002160643,0.0003473138,0.00001139537],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009949838,"about_ca_system_score_gemma":0.00005140169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003354977,"about_ca_topic_score_gemma":0.00004688417,"domain_scores_codex":[0.9970165,0.0002312996,0.0009049914,0.0007529866,0.0004788421,0.0006153503],"domain_scores_gemma":[0.9978729,0.001112322,0.0004058106,0.0003250419,0.00009023568,0.0001936924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008995493,0.0009367293,0.1508305,0.00003377883,0.00003596364,0.000001176352,0.001060062,0.00001339907,0.8467191,0.00005655189,0.000007820126,0.0002149213],"study_design_scores_gemma":[0.0005846753,0.0001758089,0.02339004,0.00009200098,0.00003102757,0.00001048236,0.00367127,0.0004744852,0.9705385,0.0005936131,0.00008814139,0.0003499675],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996452,0.000239487,0.00004264889,0.00007638721,0.00004860165,0.000624027,0.00002020406,0.00008300375,0.002413646],"genre_scores_gemma":[0.9977984,0.00007051442,0.001447817,0.00009601865,0.00008568748,0.0004426855,0.00001866954,0.0000151548,0.00002507684],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1274405,"threshold_uncertainty_score":0.9999633,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2334477690","doi":"10.1021/jo500290y","title":"Near-Visible Light Generation of a Quinone Methide from 3-Hydroxymethyl-2-anthrol","year":2014,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Quinone methide; Flash photolysis; Photochemistry; Quinone; Nucleophile; Hydroxymethyl; Anthracene; Protonation; Chromophore; Adduct; Photodissociation; Reaction rate constant; Stereochemistry; Organic chemistry; Kinetics","retraction":null,"screen_n_in":null,"score":{"opus":0.0167647920475968,"gpt":0.236874419187752,"spread":0.2201096271401553,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008979049,0.0002292978,0.0005092786,0.0000219876,0.0001188225,0.00004379366,0.0008011633,0.0001985347,0.006173498],"category_scores_gemma":[0.001447005,0.000165945,0.0001817161,0.0001557997,0.0001807191,0.0001491882,0.0001089964,0.0004961323,0.00001846394],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008502426,"about_ca_system_score_gemma":0.0001726106,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002908173,"about_ca_topic_score_gemma":0.000003839072,"domain_scores_codex":[0.9981393,0.00009575854,0.0008266125,0.0001674057,0.0005518619,0.0002190543],"domain_scores_gemma":[0.9970567,0.0007389078,0.001178191,0.0006526848,0.0002631146,0.000110379],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000733527,0.00009350959,0.0002648735,0.00006344677,0.000241262,0.000003390977,0.0008269143,0.00003988826,0.9963529,0.000002664734,0.0008994553,0.001138317],"study_design_scores_gemma":[0.0006918739,0.00002418333,0.0001086082,0.0001472093,0.0001884217,0.00009074925,0.0005278943,0.0004641045,0.9959122,0.0002710867,0.001406955,0.0001667151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923397,0.001095446,0.001509366,0.001175415,0.00008573167,0.00002662173,0.00001052399,0.0000197863,0.00373736],"genre_scores_gemma":[0.9963471,0.0001356231,0.001984647,0.00007476313,0.001131013,0.000001010633,0.000005707095,0.00004533993,0.0002748186],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006155035,"threshold_uncertainty_score":0.994735,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1980071902","doi":"10.1016/s1010-6030(01)00654-2","title":"Photogeneration of quinone methide-type intermediates from pyridoxine and derivatives","year":2002,"lang":"en","type":"article","venue":"Journal of Photochemistry and Photobiology A Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Quinone methide; Pyridoxine; Chemistry; Quinone; Biochemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01721015788789065,"gpt":0.22582618457444,"spread":0.2086160266865493,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002436231,0.0003446889,0.0007370778,0.00004181464,0.00007804552,0.00002639562,0.000318495,0.000447615,0.003483489],"category_scores_gemma":[0.001052502,0.0003093038,0.0001330548,0.0001070197,0.0007153543,0.0001521662,0.0001178964,0.0005210896,0.000001174795],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003570013,"about_ca_system_score_gemma":0.00004756873,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002094768,"about_ca_topic_score_gemma":0.000001030684,"domain_scores_codex":[0.9982665,0.00004144958,0.0009002648,0.0003570232,0.0001837804,0.000251032],"domain_scores_gemma":[0.9974492,0.0007203816,0.001057326,0.0002959814,0.0002919826,0.0001851368],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002987942,0.0001539101,0.006626624,0.0003146087,0.000343263,0.00002670961,0.0007727853,0.000001626255,0.9904416,0.000001132379,0.0002243399,0.0007946405],"study_design_scores_gemma":[0.00114216,0.00006227419,0.0003438026,0.0003102774,0.00009678935,0.0003424377,0.0008731768,0.0001333568,0.9956064,0.0002360228,0.0005802235,0.0002731434],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923025,0.005854959,0.00001359047,0.00009871573,0.00006393433,0.00005445662,0.00009166331,0.00001709329,0.001503093],"genre_scores_gemma":[0.9965798,0.001694666,0.001048557,0.00005796122,0.0003453537,0.00001079062,0.00003689891,0.00002464142,0.000201293],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006282821,"threshold_uncertainty_score":0.9999359,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2617657817","doi":"10.1021/acs.joc.6b02735","title":"Photochemical Formation of Anthracene Quinone Methide Derivatives","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"Hrvatska Zaklada za Znanost; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Chemistry; Anthracene; Quinone methide; Photochemistry; Quinone; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02186655987199157,"gpt":0.2741392262258825,"spread":0.252272666353891,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006256278,0.0001917179,0.0004159369,0.00001975474,0.000228966,0.00004619339,0.00139164,0.0001488757,0.002356739],"category_scores_gemma":[0.00277204,0.0001356871,0.0001572539,0.00005070451,0.0004650312,0.0003931657,0.0002070284,0.0004481055,0.000004853352],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008674004,"about_ca_system_score_gemma":0.0001188443,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005092193,"about_ca_topic_score_gemma":7.480136e-7,"domain_scores_codex":[0.9984991,0.000029695,0.0007141198,0.0001036427,0.0004512777,0.0002021626],"domain_scores_gemma":[0.9960991,0.0004456622,0.002240863,0.0008043681,0.0003227823,0.00008728549],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001662376,0.000085584,0.0004780279,0.0001951023,0.0001117585,0.000006328449,0.0008738353,0.000001434518,0.9971337,0.000002109666,0.0002685372,0.0006773884],"study_design_scores_gemma":[0.0006883725,0.00001340971,0.0006161812,0.0003213582,0.00008909565,0.0003620936,0.002021553,0.00002294412,0.9953063,0.0002539553,0.0001685978,0.0001361066],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921587,0.0004633739,0.0005557077,0.0008417871,0.00004131125,0.00003368217,0.000007917311,0.00001248184,0.00588501],"genre_scores_gemma":[0.9983186,0.0002541096,0.0009367706,0.00001923707,0.0002804899,0.000001275842,0.000001904642,0.00002664803,0.0001609804],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006159855,"threshold_uncertainty_score":0.9985552,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2320711933","doi":"10.1039/c6cc02108e","title":"Unveiling the first indole-fused thiazepine: structure, synthesis and biosynthesis of cyclonasturlexin, a remarkable cruciferous phytoalexin","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; University of Saskatchewan","keywords":"Phytoalexin; Biosynthesis; Indole test; Chemistry; Stereochemistry; Cruciferous vegetables; Organic chemistry; Biology; Biochemistry; Resveratrol","retraction":null,"screen_n_in":null,"score":{"opus":0.02082876828393865,"gpt":0.2408463723914657,"spread":0.220017604107527,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002609193,0.0003019733,0.0004495533,0.00007237204,0.00034466,0.00004375221,0.002010092,0.0002236345,0.0003873753],"category_scores_gemma":[0.003913911,0.0001897401,0.0001470553,0.0002583431,0.001306049,0.0001597837,0.0007963993,0.0003005044,0.00001376334],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008696206,"about_ca_system_score_gemma":0.0000585454,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004975169,"about_ca_topic_score_gemma":0.00005341838,"domain_scores_codex":[0.9983224,0.00009349316,0.0005925284,0.0003841277,0.000268936,0.0003385365],"domain_scores_gemma":[0.9894607,0.007151568,0.0003588735,0.002753624,0.0001718259,0.0001033896],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005088721,0.0001147084,0.002497439,0.000107213,0.0001335005,3.671807e-7,0.0002750483,5.091273e-7,0.9853317,0.0008023408,0.0003926794,0.01029359],"study_design_scores_gemma":[0.00031448,0.00000484941,0.001724851,0.0005483908,0.00006899531,0.00001343375,0.0002765058,0.00006079979,0.9905953,0.001383383,0.004744897,0.0002640501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9767756,0.002300584,0.00008072524,0.01101187,0.00002096154,0.0001875211,0.0002547872,0.000156766,0.009211161],"genre_scores_gemma":[0.9947017,0.0006995751,0.00414648,0.0001226844,0.00006735306,0.0001153983,0.000008843791,0.00005204453,0.0000859459],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01792605,"threshold_uncertainty_score":0.7737377,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2057232152","doi":"10.1021/ol027564n","title":"Indolophanetetrayne Cobalt Complexes via Nicholas Reactions","year":2003,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Windsor","funders":"","keywords":"Indole test; Chemistry; Cobalt; Stereochemistry; Lewis acids and bases; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01410347680422801,"gpt":0.224562606234719,"spread":0.210459129430491,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000132969,0.0002247886,0.0002279828,0.00006575183,0.0001725859,0.00005474791,0.0002911374,0.0001052247,0.007155168],"category_scores_gemma":[0.0004690038,0.0002342835,0.00008162553,0.0002110139,0.0001365786,0.0001721301,0.00003156224,0.0002991665,0.0005675677],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001553419,"about_ca_system_score_gemma":0.00003907558,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002513979,"about_ca_topic_score_gemma":0.000009632502,"domain_scores_codex":[0.9986746,0.00005843351,0.0002961108,0.0003524368,0.0002425014,0.0003758634],"domain_scores_gemma":[0.9989023,0.0003015855,0.0001370571,0.0005153152,0.00003482827,0.0001089403],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006477967,0.0000564028,0.001961546,0.00002458901,0.00007038775,0.00001606462,0.0001381618,0.00000237583,0.9925602,0.0001834052,0.004680616,0.0002997427],"study_design_scores_gemma":[0.0004380482,0.000006208646,0.001225377,0.00002959812,0.00001977791,0.00008699905,0.0001852868,0.000003419053,0.967291,0.0001061474,0.03034148,0.0002666604],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9852914,0.00009288418,0.0007055954,0.002044523,0.0001908697,0.00005915265,0.000009562001,0.0002243051,0.01138174],"genre_scores_gemma":[0.9964308,0.0000128131,0.00111587,0.001879771,0.0001379348,0.0000130183,0.00001496525,0.00005764062,0.0003372443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02566086,"threshold_uncertainty_score":0.9937524,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2758482099","doi":"10.1055/s-0036-1588563","title":"Synthesis of Tetraarylmethanes by the Triflic Acid-Promoted Formal Cross-Dehydrogenative Coupling of Triarylmethanes with Arenes","year":2017,"lang":"en","type":"article","venue":"Synlett","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Queen's University","funders":"Japan Society for the Promotion of Science","keywords":"Chemistry; Triflic acid; Nucleophile; Catalysis; Combinatorial chemistry; Nucleophilic addition; Organic chemistry; Umpolung","retraction":null,"screen_n_in":null,"score":{"opus":0.02060938411687574,"gpt":0.2822630103320536,"spread":0.2616536262151778,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008391502,0.0003915813,0.0008046419,0.00009565553,0.0005004572,0.00009837059,0.001494761,0.0002208019,0.0003031674],"category_scores_gemma":[0.003387527,0.0002531341,0.0002441183,0.000138698,0.00143017,0.0005289924,0.0001907244,0.0002587087,0.000005592749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003430996,"about_ca_system_score_gemma":0.0000990468,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002240351,"about_ca_topic_score_gemma":0.00001820069,"domain_scores_codex":[0.9977557,0.00004584334,0.0006718217,0.0004291408,0.0006225304,0.0004749296],"domain_scores_gemma":[0.9949451,0.001859102,0.001397795,0.001407971,0.0003092333,0.00008078301],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007395673,0.0001878886,0.01494464,0.0003820551,0.0006696375,0.00001114803,0.0006561148,0.00004067816,0.9737868,0.00008846929,0.00006396832,0.00842901],"study_design_scores_gemma":[0.001081344,0.00005864061,0.003425222,0.0004149404,0.0001366982,0.00002222647,0.0009954405,0.0002662809,0.9930661,0.0001005206,0.0001297617,0.0003028034],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945108,0.001032535,0.0001026128,0.0003400021,0.00005300299,0.0002196529,0.0002338017,0.00005970072,0.003447881],"genre_scores_gemma":[0.9989844,0.00006185973,0.0004135714,0.00001428985,0.00009446085,0.0001019926,0.00001170236,0.00006247396,0.0002552678],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01927929,"threshold_uncertainty_score":0.9999921,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2033431200","doi":"10.1021/jo301032f","title":"Protonated Carbonic Acid and Reactive Intermediates in the Acidic Decarboxylation of Indolecarboxylic Acids","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Decarboxylation; Protonation; Carbonic acid; Reagent; Catalysis; Carbon fibers; Cleavage (geology); Reaction mechanism; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01009062112060437,"gpt":0.2312863284818321,"spread":0.2211957073612277,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001201454,0.0002068784,0.0003379613,0.00004846623,0.00004887728,0.00001870968,0.0006251125,0.0001596942,0.000245293],"category_scores_gemma":[0.001038436,0.0001248467,0.00007900514,0.0002574069,0.0003400997,0.0002249545,0.0001044214,0.0006732548,0.000001273505],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001251331,"about_ca_system_score_gemma":0.0001241795,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001121918,"about_ca_topic_score_gemma":0.000003381486,"domain_scores_codex":[0.998485,0.0001104208,0.0006120221,0.0001041035,0.0004112754,0.0002771995],"domain_scores_gemma":[0.9979721,0.0006304017,0.0008304737,0.0003567363,0.000135848,0.00007446711],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000154986,0.0001103409,0.02711495,0.0001037349,0.00009279294,0.000003208543,0.006336016,5.58307e-7,0.9654607,0.000002828,0.00000909396,0.0006107425],"study_design_scores_gemma":[0.0006727632,0.00002174514,0.0186309,0.000220317,0.0000861271,0.0003613167,0.007853158,0.00001024006,0.9718773,0.000114787,0.00003123094,0.000120132],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956537,0.002199511,0.000007705594,0.00033741,0.00003455866,0.000111363,0.000003288198,0.000009314766,0.001643137],"genre_scores_gemma":[0.9994508,0.0001785611,0.00004032874,0.00002913986,0.0002489323,0.000009022879,0.000002239127,0.00002654151,0.00001444271],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008484057,"threshold_uncertainty_score":0.5091099,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2178717965","doi":"10.1562/2005-02-17-ra-444","title":"Photogeneration and Chemistry of Biphenyl Quinone Methides from Hydroxybiphenyl Methanols†","year":2005,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Moiety; Flash photolysis; Ring (chemistry); Biphenyl; Aqueous solution; Photochemistry; Substituent; Quinone; Intramolecular force; Medicinal chemistry; Alkylation; Benzene; Stereochemistry; Organic chemistry; Reaction rate constant; Kinetics","retraction":null,"screen_n_in":null,"score":{"opus":0.01146159766213743,"gpt":0.2299439191794206,"spread":0.2184823215172831,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002181728,0.0003912125,0.0006122769,0.00003104033,0.0001083758,0.00002689809,0.0002718211,0.0004912613,0.003207248],"category_scores_gemma":[0.0003415389,0.0003892898,0.0001009479,0.00008758136,0.0005611915,0.0001486233,0.0001667741,0.0003029813,0.000004586805],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003806674,"about_ca_system_score_gemma":0.0000548049,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002481444,"about_ca_topic_score_gemma":0.00001415351,"domain_scores_codex":[0.9981802,0.00004477124,0.0005706037,0.000708877,0.0001468939,0.000348731],"domain_scores_gemma":[0.9983113,0.0005992455,0.0003372948,0.0004948038,0.00008981337,0.0001675317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001538244,0.00009505493,0.001810749,0.000199459,0.0001801154,0.000003065243,0.0004544534,0.00000360856,0.9932091,0.00001245428,0.00005920642,0.003818881],"study_design_scores_gemma":[0.0008134006,0.00001689231,0.000139287,0.0000888333,0.00007218296,0.00005155867,0.0003828231,0.0003635568,0.9930174,0.0005540163,0.00411916,0.0003808377],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9884632,0.003514887,0.00004894676,0.0001187345,0.00002627668,0.0001230115,0.0002911059,0.00007510727,0.007338692],"genre_scores_gemma":[0.9951898,0.0005383653,0.003126339,0.000125552,0.0003282168,0.0001275682,0.0002079477,0.00003396312,0.000322273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007016419,"threshold_uncertainty_score":0.9998559,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null}]}