{"meta":{"page":1,"per_page":50,"max_per_page":100,"total":217,"total_is_capped":false,"direct_labels_cover":0,"predictions_cover":217,"direct_label_status":"direct model label, unvalidated","prediction_status":"machine_predicted_unvalidated (Codex and Gemma teacher distillation)","score_status":"score_only:v0-immature-baseline (scores rank; they never assert a category)","snapshot":{"source":"OpenAlex, pinned release, all 482 partitions","release":"2026-06-24","frame_built":"2026-07-12"},"query_hash":"eff6574aea47","filters":{"venue":"Tetrahedron Letters"}},"results":[{"id":"W2950618898","doi":"10.1016/j.tetlet.2015.03.135","title":"Metal-catalyzed organic reactions using mechanochemistry","year":2015,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":202,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Mechanosynthesis; Mechanochemistry; Chemistry; Catalysis; Grinding; Explosive material; Supramolecular chemistry; Metal; Oxygenate; Organic reaction; Organic synthesis; Nanotechnology; Organic chemistry; Combinatorial chemistry; Chemical engineering; Ball mill; Metallurgy; Crystal structure; Materials science","retraction":null,"screen_n_in":null,"score":{"opus":0.03290856573634849,"gpt":0.2621395524859126,"spread":0.2292309867495641,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009676786,0.0002071781,0.0001767283,0.0001028611,0.0001178638,0.00005088334,0.0002120037,0.0001133981,0.001241979],"category_scores_gemma":[0.00009139386,0.0002275986,0.0001955432,0.0002628693,0.00007482634,0.0001754739,0.00005349494,0.0003152026,0.00005206695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002120436,"about_ca_system_score_gemma":0.0000638967,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001576857,"about_ca_topic_score_gemma":0.00001545886,"domain_scores_codex":[0.9988198,0.00001626685,0.0002610794,0.0003343242,0.000255396,0.0003131561],"domain_scores_gemma":[0.9990916,0.00003341209,0.0001121964,0.0004927725,0.00006004435,0.0002100361],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001298745,0.00006760434,0.00008381241,0.00002858064,0.0001188083,0.00004123622,0.0001038349,0.00009196287,0.9974871,0.00004326945,0.00184488,0.0000758774],"study_design_scores_gemma":[0.0006155879,0.00000639732,0.00001101179,0.00004245237,0.0001601844,0.0003471354,0.0006965967,0.0002369625,0.9619139,0.0001115005,0.03548782,0.0003704511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.98366,0.00009789569,0.005247452,0.0006179276,0.0003095571,0.00004873192,0.00002616466,0.0002733995,0.009718898],"genre_scores_gemma":[0.9975017,0.000003910814,0.001224528,0.0003413812,0.0001809248,0.00001276489,0.0001019093,0.00004428379,0.0005886224],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03557325,"threshold_uncertainty_score":0.999671,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2164870496","doi":"10.1016/s0040-4039(01)01983-9","title":"Synthesis and cross-coupling reactions of tetraalkylammonium organotrifluoroborate salts","year":2001,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":171,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Coupling (piping); Coupling reaction; Combinatorial chemistry; Computational chemistry; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01388614132792547,"gpt":0.2640203406603764,"spread":0.250134199332451,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002346861,0.0002999176,0.0003711216,0.0001850786,0.0002658726,0.0001404057,0.0002510529,0.0001841148,0.0006846213],"category_scores_gemma":[0.0003990844,0.0003281781,0.0001339716,0.0004404317,0.0004525751,0.0003244831,0.00006794192,0.0004020311,0.00005688063],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002087578,"about_ca_system_score_gemma":0.00006055581,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005282823,"about_ca_topic_score_gemma":0.00003747914,"domain_scores_codex":[0.9980628,0.000001169475,0.0006001541,0.0005288048,0.0003241863,0.0004828435],"domain_scores_gemma":[0.9982467,0.0005410135,0.000272355,0.0006726582,0.0001072997,0.000159965],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005220414,0.00009385153,0.03780556,0.0001387409,0.00007297714,0.0000364888,0.0001070928,0.0009731301,0.9593859,0.00005065209,0.0002094102,0.00107405],"study_design_scores_gemma":[0.0005274094,0.00001147615,0.01494105,0.0001441223,0.0001107557,0.0002180888,0.0001762701,0.001245228,0.9793074,0.00003315125,0.002881614,0.0004034598],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972317,0.0001651044,0.0001789199,0.00089899,0.0002107876,0.00008571095,0.00005259414,0.00028498,0.000891197],"genre_scores_gemma":[0.9986398,0.0001374043,0.0001731475,0.00008583048,0.0002061827,0.00002650399,0.00002356559,0.00007602742,0.000631546],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02286451,"threshold_uncertainty_score":0.999917,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2952656232","doi":"10.1016/j.tetlet.2003.10.129","title":"Bismuth triflate-catalyzed mild and efficient epoxide opening by aromatic amines under aqueous conditions","year":2003,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":162,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Epoxide; Trifluoromethanesulfonate; Aqueous solution; Bismuth; Catalysis; Organic chemistry; Ring (chemistry); Aqueous medium; Medicinal chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.0109077931343602,"gpt":0.2255109682749872,"spread":0.214603175140627,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007486826,0.0002192544,0.0002494372,0.00005593538,0.0002071894,0.00007061569,0.0001174919,0.0001093594,0.0005737789],"category_scores_gemma":[0.00009195655,0.0001935535,0.00009504004,0.0001327353,0.0001634094,0.00005990336,0.00002237542,0.0002101671,0.00004499152],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001060446,"about_ca_system_score_gemma":0.00001237683,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007760104,"about_ca_topic_score_gemma":0.000004124692,"domain_scores_codex":[0.9988149,0.0000231398,0.0002988458,0.0003443767,0.0001841739,0.0003345706],"domain_scores_gemma":[0.9991735,0.0002911323,0.0001011426,0.0002682193,0.00000958911,0.0001563848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004384814,0.00009376391,0.0002069382,0.00003756144,0.00005475347,0.000007609371,0.00006884146,0.00008465209,0.9953364,0.00006608832,0.003826656,0.000212424],"study_design_scores_gemma":[0.0009657759,0.000005917819,0.0004038534,0.0001214786,0.0001193487,0.00009821925,0.0003929038,0.0003124533,0.9902148,0.0001210496,0.006799445,0.0004448125],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936204,0.0003481455,0.0002438268,0.001726288,0.00007499856,0.00009031322,0.00003547418,0.0001195241,0.003741007],"genre_scores_gemma":[0.9984916,0.0000218431,0.0002332325,0.0004799589,0.00003874435,0.00003091777,0.00007018667,0.0000335983,0.0005999144],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005121584,"threshold_uncertainty_score":0.7892882,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2951188690","doi":"10.1016/j.tetlet.2004.10.046","title":"Convenient synthesis of 12H-benzo[a]xanthenes from 2-tetralone","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthesis of Organic Compounds","field":"Medicine","cited_by":159,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Acadia University","funders":"","keywords":"Chemistry; Tetralone; Stereochemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01138814604047997,"gpt":0.2316306495555557,"spread":0.2202425035150757,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001781889,0.0002920289,0.0006650253,0.0002274397,0.0000562685,0.0000173246,0.0002843741,0.0001157447,0.0009754648],"category_scores_gemma":[0.000314132,0.0002683268,0.0002551274,0.0002459816,0.0002591514,0.0001035251,0.00005546775,0.0002023034,0.0002180187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002729092,"about_ca_system_score_gemma":0.0001018357,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007849805,"about_ca_topic_score_gemma":0.00002296021,"domain_scores_codex":[0.9980201,0.00004387986,0.0005237297,0.0004468574,0.0005599136,0.0004055464],"domain_scores_gemma":[0.9984249,0.0004009639,0.0001720044,0.000756951,0.00005227499,0.0001929066],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001777913,0.0004235021,0.01668424,0.00008769729,0.0003121299,0.000119401,0.000474379,0.00003241675,0.9733055,0.0001678809,0.00153038,0.006684721],"study_design_scores_gemma":[0.001795538,0.0001415104,0.1275127,0.0004406793,0.0003363937,0.00007453597,0.0002242096,0.00001378906,0.8670685,0.0002067724,0.001866667,0.000318694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9812266,0.0003939976,0.0004221422,0.01621239,0.0003496585,0.0002758164,0.00003308348,0.0001737237,0.0009125585],"genre_scores_gemma":[0.9933625,0.00004087994,0.004334423,0.001876499,0.0002476897,0.000019053,0.00001304057,0.00006714521,0.000038719],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1108284,"threshold_uncertainty_score":0.9999769,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2112180074","doi":"10.1016/s0040-4039(01)01129-7","title":"Solvent free permanganate oxidations","year":2001,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":154,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Regina","funders":"","keywords":"Chemistry; Permanganate; Primary (astronomy); Organic chemistry; Solvent; Oxidative coupling of methane; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01229169687423629,"gpt":0.2219813682045493,"spread":0.209689671330313,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00003874308,0.0001226674,0.0001113431,0.00003680729,0.0001247799,0.00003115539,0.0002429445,0.00006746356,0.005121371],"category_scores_gemma":[0.00004321687,0.0001114081,0.0001209886,0.00009655099,0.00006215655,0.00008024671,0.00004474758,0.000184473,0.0002343621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000107372,"about_ca_system_score_gemma":0.000008419564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001046217,"about_ca_topic_score_gemma":0.00002666993,"domain_scores_codex":[0.9991893,0.000005336324,0.0001663452,0.0002101072,0.0001717366,0.0002571484],"domain_scores_gemma":[0.9993575,0.00006520087,0.0000467065,0.0004184797,0.00001305685,0.00009907005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000003964049,0.00007171641,0.00112793,0.00001075748,0.00002663549,0.00001719075,0.00004305695,0.0000129692,0.9738431,0.0001217913,0.02213067,0.002590198],"study_design_scores_gemma":[0.0005336514,0.000004957163,0.002740518,0.00004275686,0.0000601246,0.00007220968,0.0001301557,0.0001660297,0.4626403,0.0002134082,0.5330123,0.0003836486],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9420423,0.00006180292,0.0002056273,0.01164077,0.00009446197,0.00002959313,0.00001671729,0.0001846656,0.04572407],"genre_scores_gemma":[0.9960104,0.00005311848,0.0002265345,0.001001949,0.0003054448,0.00001766583,0.00003652968,0.00002312284,0.002325247],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5112029,"threshold_uncertainty_score":0.9957881,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2120340355","doi":"10.1016/j.tetlet.2005.10.123","title":"Catalytic oxidations of alcohols to carbonyl compounds by oxygen under solvent-free and transition-metal-free conditions","year":2005,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":100,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Ministerio de Educación, Cultura y Deporte; Canada Research Chairs; Eli Lilly and Company","keywords":"Hypervalent molecule; Chemistry; Catalysis; Reagent; Iodine; Alcohol oxidation; Transition metal; Benzene; Organic chemistry; Solvent; Styrene; Oxygen","retraction":null,"screen_n_in":null,"score":{"opus":0.009749912787199704,"gpt":0.2358804677187975,"spread":0.2261305549315978,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008242499,0.0002881586,0.0003169224,0.000105551,0.0001702322,0.00004438445,0.0004984391,0.0001226318,0.001324071],"category_scores_gemma":[0.00008807638,0.0003384167,0.000119457,0.0002797995,0.0002691853,0.0001987768,0.0001089229,0.0002674984,0.00004442113],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002891869,"about_ca_system_score_gemma":0.00005438076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001380881,"about_ca_topic_score_gemma":0.0001102739,"domain_scores_codex":[0.9983984,0.00001670709,0.0004390928,0.0004543761,0.0003331554,0.0003582668],"domain_scores_gemma":[0.9983605,0.0001646794,0.0001356043,0.00103523,0.00006549048,0.000238464],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008246965,0.0001606129,0.00008442606,0.00005689634,0.0001468901,0.000002264688,0.0003182237,0.0001501978,0.9390132,0.0001081291,0.05986,0.00009085112],"study_design_scores_gemma":[0.001771339,0.00002416382,0.001205217,0.00007237291,0.0002421919,0.00006487534,0.0006904814,0.0001997381,0.9883953,0.000245755,0.006577118,0.0005114261],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9566127,0.00009421813,0.0008656782,0.03131088,0.0000501244,0.0001728996,0.002141518,0.000150948,0.008601009],"genre_scores_gemma":[0.9960488,0.000009245685,0.0009353872,0.001422008,0.0001467051,0.0000429458,0.0005739068,0.00005235574,0.0007686465],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05328288,"threshold_uncertainty_score":0.9999068,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2052342356","doi":"10.1016/s0040-4039(00)00743-7","title":"The hydration of nitriles catalyzed by water-soluble rhodium complexes","year":2000,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":94,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université de Moncton","funders":"European Regional Development Fund","keywords":"Chemistry; Rhodium; Catalysis; Water soluble; Organic chemistry; Medicinal chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.0053590134629038,"gpt":0.2036012363947628,"spread":0.198242222931859,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001711115,0.0001515791,0.0001825767,0.00005694676,0.0002186118,0.0000502395,0.0003236179,0.00006512792,0.003435476],"category_scores_gemma":[0.00001759637,0.0001023998,0.000120312,0.0002139031,0.0001520253,0.0001188251,0.00002227966,0.0001174494,0.0002184859],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006112949,"about_ca_system_score_gemma":0.00001141502,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002327036,"about_ca_topic_score_gemma":0.00002058616,"domain_scores_codex":[0.9987717,0.0000267862,0.0003544569,0.0002169745,0.0003387973,0.0002912331],"domain_scores_gemma":[0.9993421,0.0001037586,0.0000828269,0.0003792523,0.00002999031,0.00006207132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002651301,0.00005234627,0.0003636399,0.00002286083,0.00006930377,0.000001496172,0.000269025,0.00008628614,0.9647363,0.00003107668,0.01987844,0.01446273],"study_design_scores_gemma":[0.0003916672,0.000005642657,0.00004073796,0.000005514754,0.00002847803,0.000003243908,0.000118566,0.0003801979,0.8972213,0.00002241638,0.1016376,0.0001446638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851297,0.000226198,0.0001346113,0.00228136,0.00005498107,0.00006065948,0.00003200004,0.0000882811,0.01199226],"genre_scores_gemma":[0.9947547,0.00005845923,0.00003717377,0.0003088647,0.00006657204,0.00001678835,0.0004736284,0.00002007027,0.004263748],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08175918,"threshold_uncertainty_score":0.9974755,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2950209312","doi":"10.1016/j.tetlet.2006.03.153","title":"First example of direct reductive amination of aldehydes with primary and secondary amines catalyzed by water-soluble transition metal catalysts","year":2006,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":86,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Université de Moncton","funders":"European Regional Development Fund; Natural Sciences and Engineering Research Council of Canada; Université de Moncton","keywords":"Chemistry; Reductive amination; Catalysis; Primary (astronomy); Amination; Salt (chemistry); Alkylation; Transition metal; Organic chemistry; Amine gas treating; Hydrogen; Gaseous hydrogen; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.004361851037233357,"gpt":0.1774482534956986,"spread":0.1730864024584653,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001362775,0.0002091161,0.0003877848,0.0002123383,0.00007512281,0.00001466188,0.0001179232,0.00008157813,0.000115787],"category_scores_gemma":[0.000008128389,0.0001712168,0.00008956574,0.0003046244,0.0002468717,0.0003049982,0.00002115403,0.00009679041,0.000001869498],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009431518,"about_ca_system_score_gemma":0.00001609316,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003005349,"about_ca_topic_score_gemma":0.0001153865,"domain_scores_codex":[0.9986726,0.00002328486,0.0003917088,0.0003572601,0.0003415039,0.0002136164],"domain_scores_gemma":[0.9993544,0.00007487852,0.000199322,0.0002469338,0.0000767523,0.00004768652],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006301736,0.0001710418,0.0003315184,0.0003911791,0.000171929,0.00000463999,0.0008745245,0.0001117963,0.9957088,0.00001443637,0.0008189291,0.001338154],"study_design_scores_gemma":[0.0009350682,0.00003327774,0.001042376,0.0000333773,0.0002036422,0.00001562121,0.0002247263,0.00012505,0.9963383,0.000007575573,0.0008233454,0.0002176563],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995383,0.0003163137,0.0006975372,0.0004462504,0.00002341089,0.0001041905,0.0001430656,0.00005231509,0.002833871],"genre_scores_gemma":[0.9967999,0.00001573628,0.0002687746,0.00004534644,0.00003640045,0.00002304782,0.002453722,0.00002785527,0.0003292036],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002889963,"threshold_uncertainty_score":0.6982018,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2951009010","doi":"10.1016/j.tetlet.2006.09.082","title":"Direct-type catalytic three-component Mannich reaction in aqueous media","year":2006,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Aldehyde; Cyclohexanone; Ketone; Amine gas treating; Catalysis; Yield (engineering); Organic chemistry; Mannich reaction; Selectivity; Aqueous medium; Trifluoromethanesulfonate; Aqueous solution","retraction":null,"screen_n_in":null,"score":{"opus":0.009774890444939571,"gpt":0.2069379625166305,"spread":0.1971630720716909,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007886976,0.0001901782,0.0002229944,0.00008369749,0.00005789111,0.00002640922,0.0001587277,0.0001360606,0.0002833911],"category_scores_gemma":[0.00004343849,0.0001782431,0.00009549325,0.0001919536,0.00006836793,0.00008596086,0.00002718064,0.0002936909,0.000167704],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003851467,"about_ca_system_score_gemma":0.00001495414,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003403826,"about_ca_topic_score_gemma":0.001047184,"domain_scores_codex":[0.9987497,0.000009404393,0.000308252,0.0003423613,0.0002428389,0.0003474365],"domain_scores_gemma":[0.9993192,0.0001903994,0.00008233338,0.0003238572,0.00001484689,0.00006933886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002203877,0.0001548064,0.004025932,0.00002872216,0.00001380568,0.00004241518,0.0000325403,0.00003265659,0.9869147,0.00002303769,0.003719093,0.00499026],"study_design_scores_gemma":[0.0007200061,0.000008327094,0.05002483,0.000123621,0.00006434264,0.00006126299,0.0000517232,0.0002933898,0.8919127,0.0002157191,0.05593088,0.0005932148],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9706577,0.0002742619,0.000008928031,0.001456347,0.0002379439,0.00005392918,0.000008697895,0.0001606217,0.02714155],"genre_scores_gemma":[0.9988365,0.0000214488,0.00006239548,0.0001455346,0.0004007803,0.00001477216,0.0001139141,0.00003225698,0.0003724437],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.095002,"threshold_uncertainty_score":0.7268542,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2095895250","doi":"10.1016/j.tetlet.2004.11.062","title":"Silica gel supported InBr3 and InCl3: new catalysts for the facile and rapid oxidation of 2′-hydroxychalcones and flavanones to their corresponding flavones under solvent free conditions","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthesis of Organic Compounds","field":"Medicine","cited_by":81,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Catalysis; Flavones; Yield (engineering); Silica gel; Solvent; Organic chemistry; Chromatography; Metallurgy","retraction":null,"screen_n_in":null,"score":{"opus":0.02206626936602114,"gpt":0.2659270895429716,"spread":0.2438608201769504,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002337201,0.0002116959,0.0003429205,0.0002306736,0.0001840251,0.00003694314,0.0001242424,0.00007074884,0.0000336246],"category_scores_gemma":[0.0002283541,0.000160681,0.00005761497,0.000160586,0.0002250134,0.0001417009,0.0001051252,0.00009477557,0.000002516687],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006760554,"about_ca_system_score_gemma":0.00007657515,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002339321,"about_ca_topic_score_gemma":0.0001445495,"domain_scores_codex":[0.9989143,0.00002442805,0.0003108004,0.0003254347,0.0001842605,0.0002407482],"domain_scores_gemma":[0.9986861,0.000607167,0.0001104113,0.0003849808,0.00004145825,0.0001698384],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001378693,0.00004921245,0.00133119,0.00007524084,0.0001475799,0.000003066208,0.001809435,0.00001410687,0.9877878,0.0002048757,0.005331381,0.00310824],"study_design_scores_gemma":[0.005566827,0.0005693405,0.2007916,0.0003117613,0.0004821177,0.0003092532,0.003493706,0.000212428,0.7841269,0.001076855,0.002611339,0.0004478311],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9495187,0.0006208585,0.002471822,0.04631187,0.0001099145,0.0008127792,0.00006128308,0.00006614316,0.00002660479],"genre_scores_gemma":[0.9974146,0.00008697957,0.0008130277,0.001416391,0.00009622142,0.00003719289,0.00005043724,0.00003050344,0.00005460708],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2036609,"threshold_uncertainty_score":0.6552383,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2949617131","doi":"10.1016/j.tetlet.2003.09.053","title":"Diastereoselective allylations and crotylations under phase-transfer conditions using trifluoroborate salts: an application to the total synthesis of (−)-tetrahydrolipstatin","year":2003,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":78,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Potassium; Phase (matter); Aqueous medium; Organic chemistry; Combinatorial chemistry; Aqueous solution","retraction":null,"screen_n_in":null,"score":{"opus":0.02060158112287717,"gpt":0.309578038122368,"spread":0.2889764569994908,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000359436,0.0002474712,0.0002698044,0.00009352004,0.0002757364,0.00004966303,0.0001816406,0.0001097356,0.0005921616],"category_scores_gemma":[0.0003133762,0.0002321029,0.00007474214,0.0004471283,0.0002023939,0.0001682394,0.00001655577,0.0002110072,0.000006937759],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000150423,"about_ca_system_score_gemma":0.00008761791,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007178895,"about_ca_topic_score_gemma":0.00001792321,"domain_scores_codex":[0.9983777,0.0001682352,0.0004532816,0.0004454665,0.0002465952,0.000308758],"domain_scores_gemma":[0.9982976,0.0008048783,0.0001088974,0.00054809,0.0000818084,0.000158746],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001958786,0.000170944,0.0001615918,0.00003547602,0.00007449854,6.80886e-7,0.0007541344,0.005851724,0.9905823,0.0005241295,0.0000397353,0.001785181],"study_design_scores_gemma":[0.0006954093,0.00002830096,0.0009607224,0.00004316836,0.0001850954,0.00005168981,0.001055399,0.004712587,0.991506,0.0002297855,0.0002162131,0.0003156168],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8243358,0.00003455359,0.1734868,0.0009209097,0.00003459685,0.0002628443,0.0002307554,0.00006749051,0.0006262825],"genre_scores_gemma":[0.9908506,0.000003324455,0.008624636,0.0002064119,0.0000692068,0.0001204837,0.00003620241,0.0000521689,0.00003701819],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1665148,"threshold_uncertainty_score":0.9464882,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2949196406","doi":"10.1016/j.tetlet.2009.06.007","title":"Functionalization of Csp3–H bond—Sc(OTf)3-catalyzed domino 1,5-hydride shift/cyclization/Friedel–Crafts acylation reaction of benzylidene Meldrum’s acids","year":2009,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":78,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Waterloo","funders":"","keywords":"Chemistry; Friedel–Crafts reaction; Domino; Catalysis; Acylation; Hydride; Meldrum's acid; Surface modification; Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Hydrogen","retraction":null,"screen_n_in":null,"score":{"opus":0.01634142494110306,"gpt":0.2640599214351231,"spread":0.2477184964940201,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006627538,0.0004533658,0.0006320812,0.0005158238,0.0001694878,0.00004872943,0.0003409348,0.000326003,0.001422754],"category_scores_gemma":[0.0006675115,0.0005169914,0.0003067862,0.001015681,0.00018391,0.0008139196,0.00005629434,0.0002798546,0.00003722448],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004256067,"about_ca_system_score_gemma":0.000150269,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001455523,"about_ca_topic_score_gemma":0.0000300916,"domain_scores_codex":[0.9961402,0.00009314505,0.00149102,0.000711902,0.00115154,0.0004122388],"domain_scores_gemma":[0.9970891,0.0003936743,0.001126403,0.0008576454,0.0003762998,0.0001568275],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003481686,0.000260707,0.006819639,0.0001756257,0.0001258008,0.000003479795,0.0004359047,0.004404922,0.9765514,0.003422873,0.003573755,0.003877691],"study_design_scores_gemma":[0.003918711,0.0001068729,0.07657429,0.0002921879,0.0004630466,0.00005336492,0.0002194788,0.003399182,0.9014601,0.002969381,0.009573538,0.0009698865],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8149071,0.0001885672,0.1751735,0.003190145,0.0007492422,0.0004014822,0.0001477019,0.0003449795,0.004897289],"genre_scores_gemma":[0.9913388,0.00004366725,0.003755943,0.0006516691,0.0004539964,0.00002904027,0.003065624,0.00007271611,0.0005885416],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1764317,"threshold_uncertainty_score":0.9997281,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2951224518","doi":"10.1016/s0040-4039(99)02289-3","title":"1-Ethyl-3-methylimidazolium halogenoaluminate ionic liquids as reaction media for the acylative cleavage of ethers","year":2000,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":76,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ionic liquid; Cleavage (geology); Aluminium chloride; Chloride; Adduct; Iodide; Ionic bonding; Organic chemistry; Lewis acids and bases; Benzoyl chloride; Aluminium; Medicinal chemistry; Polymer chemistry; Ion; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01544735546186524,"gpt":0.2460578253874076,"spread":0.2306104699255423,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002798634,0.0001927435,0.0002107605,0.00004907052,0.0001549151,0.00001633881,0.0003365419,0.0001146736,0.0003232069],"category_scores_gemma":[0.00008904046,0.0001416666,0.0001714325,0.0002031848,0.0001938864,0.000117047,0.00002603491,0.0002762744,0.0001074379],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001264945,"about_ca_system_score_gemma":0.00002889529,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002355007,"about_ca_topic_score_gemma":0.000006692817,"domain_scores_codex":[0.9987753,0.00003131352,0.0003441327,0.0002735959,0.0002160235,0.0003596075],"domain_scores_gemma":[0.9988713,0.0005124685,0.00008826942,0.0004164103,0.00004428026,0.00006729054],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001747089,0.00005079639,0.000005257306,0.0000489418,0.0001063637,0.000001004083,0.002042711,0.003162496,0.9650515,0.002469184,0.002425218,0.02446178],"study_design_scores_gemma":[0.001048688,0.0001683632,0.0004089103,0.00006104563,0.0001356291,0.00001058412,0.0008126588,0.01143211,0.9273648,0.0003336529,0.0578035,0.0004200566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826976,0.000319849,0.002581152,0.009585338,0.0002224619,0.0006108445,0.00003326166,0.0001568562,0.003792655],"genre_scores_gemma":[0.9968989,0.0001256024,0.0003890107,0.001073105,0.0002536425,0.0001915183,0.00002457122,0.00005149646,0.0009921402],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05537828,"threshold_uncertainty_score":0.5776997,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2176481864","doi":"10.1016/j.tetlet.2006.02.086","title":"Silica gel supported TaBr5: new catalyst for the facile and rapid cyclization of 2′-aminochalcones to the corresponding 2-aryl-2,3-dihydroquinolin-4(1H)-ones under solvent-free conditions","year":2006,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Université de Sherbrooke","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Isomerization; Catalysis; Aryl; Silica gel; Solvent; Environmentally friendly; Combinatorial chemistry; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01742032876792197,"gpt":0.2517697130819165,"spread":0.2343493843139945,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003065965,0.0003211398,0.0003313824,0.00019082,0.000357251,0.00008166959,0.0006759361,0.0001347138,0.0003646987],"category_scores_gemma":[0.0002590827,0.0002394751,0.0001775686,0.0003127723,0.0002701291,0.0001584169,0.0001193635,0.0001751073,0.00001127765],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000103057,"about_ca_system_score_gemma":0.0000667919,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006952683,"about_ca_topic_score_gemma":0.0004044642,"domain_scores_codex":[0.9981742,0.00003779034,0.0005496831,0.0004503714,0.0003404747,0.0004475165],"domain_scores_gemma":[0.9972661,0.001282307,0.0002780663,0.001004459,0.00007198086,0.00009710041],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007264276,0.00005750667,0.0008425943,0.00006136756,0.00007771995,0.000002522794,0.0002402175,0.000399353,0.9245474,0.0004139662,0.07214636,0.001138345],"study_design_scores_gemma":[0.0007663437,0.00004480984,0.00530602,0.00007887174,0.0002021053,0.00002425813,0.0005995706,0.0008384156,0.9833094,0.0004993157,0.007965178,0.000365705],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.962091,0.0003521798,0.01526107,0.02020017,0.0001302008,0.0007241095,0.0006052874,0.0002882881,0.0003477022],"genre_scores_gemma":[0.9962122,0.00002572368,0.0005554121,0.001747755,0.0002764723,0.000237498,0.0003611753,0.00006286457,0.0005208373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06418119,"threshold_uncertainty_score":0.9765509,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2106955615","doi":"10.1016/j.tetlet.2005.03.169","title":"A mild esterification process in phosphonium salt ionic liquid","year":2005,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":64,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; McMaster University","keywords":"Chemistry; Phosphonium; Ionic liquid; Salt (chemistry); Phosphonium salt; Process (computing); Ionic bonding; Organic chemistry; Inorganic chemistry; Chemical engineering; Ion; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01226835989762854,"gpt":0.2439377744086596,"spread":0.231669414511031,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001004069,0.0001578233,0.0001449456,0.00007461802,0.00005360116,0.00002433655,0.000252566,0.00008022615,0.0001453956],"category_scores_gemma":[0.00001789478,0.0001513086,0.0000515582,0.0002637857,0.0000414571,0.0001922717,0.00002548114,0.0002466922,0.0002319812],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002257843,"about_ca_system_score_gemma":0.00002835223,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007007485,"about_ca_topic_score_gemma":0.00001702648,"domain_scores_codex":[0.9988607,0.00001096748,0.000317918,0.0002960147,0.0001624107,0.000351965],"domain_scores_gemma":[0.9995289,0.00002274845,0.00005187899,0.0003068376,0.0000214277,0.00006815965],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001103209,0.0001801368,0.000148221,0.00009367303,0.00001613143,0.00000238545,0.001550349,0.02452204,0.9669377,0.001396603,0.001889884,0.003152544],"study_design_scores_gemma":[0.001253688,0.00008824571,0.0008476081,0.0001444882,0.00001976594,0.00001302277,0.0001947042,0.04588198,0.9174996,0.00003087909,0.03335629,0.0006697091],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821779,0.0002199277,0.001946579,0.01446773,0.00007392874,0.0002412792,0.000002967274,0.0002075411,0.0006621649],"genre_scores_gemma":[0.9967511,0.00002740154,0.0006101292,0.001931585,0.000216184,0.0001900353,0.00001923703,0.00003592458,0.0002184418],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04943809,"threshold_uncertainty_score":0.6170185,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2951743999","doi":"10.1016/j.tetlet.2004.09.068","title":"A gentle and efficient route for the deoxygenation of sulfoxides using catecholborane (HBcat; cat=1,2-O2C6H4)","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Los Alamos National Laboratory; American Chemical Society Petroleum Research Fund; Mount Allison University; Canada Research Chairs","keywords":"Chemistry; Deoxygenation; Sulfoxide; Lewis acids and bases; Rhodium; Catalysis; Organic chemistry; Medicinal chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.0152915595934163,"gpt":0.2416367813800424,"spread":0.2263452217866261,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001175087,0.0001879612,0.0001868816,0.00004052736,0.0001418447,0.00003701819,0.0002167227,0.000103971,0.00007728918],"category_scores_gemma":[0.00006147182,0.0001553719,0.00008460323,0.0001247086,0.0001684438,0.00005055061,0.0000443491,0.0001134022,0.000003196953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002279476,"about_ca_system_score_gemma":0.00005593672,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002411054,"about_ca_topic_score_gemma":0.00001285077,"domain_scores_codex":[0.9989388,0.000005864819,0.0002789951,0.0002893692,0.0002077009,0.0002792664],"domain_scores_gemma":[0.9993061,0.000104483,0.0001393108,0.0003332467,0.00004729075,0.00006955548],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002192652,0.00005225497,0.0004648143,0.000188822,0.00003854123,0.000002393666,0.0004007682,0.002105047,0.9960451,0.00005890404,0.00007508948,0.0005464142],"study_design_scores_gemma":[0.00106631,0.00000965099,0.0009169892,0.00004601511,0.00007454857,0.00002422442,0.0002663728,0.000975813,0.9961669,0.00002237621,0.0002505909,0.0001801595],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946545,0.0004158361,0.002121138,0.002394626,0.00008935951,0.0001523284,0.00005108916,0.00006335572,0.00005777364],"genre_scores_gemma":[0.9981331,0.00002628661,0.001167063,0.0004565753,0.0001180002,0.00001488025,0.00001887301,0.00003727486,0.00002790609],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003478647,"threshold_uncertainty_score":0.6335881,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2950906565","doi":"10.1016/s0040-4039(01)01726-9","title":"Dysprosium(III) catalyzed formation of hexahydrofuro[3,2-c]quinolines via 2:1 coupling of dihydrofuran with substituted anilines","year":2001,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; AstraZeneca","keywords":"Chemistry; Dysprosium; Catalysis; Medicinal chemistry; Coupling (piping); Concerted reaction; Quinoline; Combinatorial chemistry; Photochemistry; Organic chemistry; Inorganic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01050996736186521,"gpt":0.2157996401953172,"spread":0.205289672833452,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001129063,0.0003205548,0.0004791333,0.0002010661,0.00008260561,0.00001795966,0.0002838006,0.0001380726,0.000140605],"category_scores_gemma":[0.00002427357,0.0002903544,0.0001211396,0.0004119091,0.0001692383,0.0004164235,0.00003681283,0.0002193371,0.00001147832],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001408298,"about_ca_system_score_gemma":0.00003818718,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003859175,"about_ca_topic_score_gemma":0.00009828201,"domain_scores_codex":[0.9980544,0.000008480409,0.0007103864,0.0003458605,0.0005075342,0.0003732828],"domain_scores_gemma":[0.998589,0.00005424147,0.000550504,0.0005327793,0.0001771052,0.000096378],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003152049,0.00009305073,0.002107163,0.000505759,0.00003545195,0.00002341724,0.0005200301,0.002966652,0.9924448,0.00002366163,0.00001810089,0.0009467161],"study_design_scores_gemma":[0.001888751,0.00004061049,0.0003273333,0.0001889962,0.00009964991,0.0001525118,0.0004123063,0.006831923,0.9895136,0.00001122071,0.0002107545,0.0003223617],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876715,0.000141518,0.01107283,0.0002287995,0.0001202189,0.0002172287,0.00001772733,0.0001946783,0.0003355055],"genre_scores_gemma":[0.9985774,0.00005843493,0.0008400495,0.0000558794,0.0001366216,0.00002423644,0.0002083555,0.00005464772,0.00004442557],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01090585,"threshold_uncertainty_score":0.9999549,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2093215681","doi":"10.1016/s0040-4039(03)00850-5","title":"Oxidation of meso-tetraphenyl-2,3-dihydroxychlorin: simplified synthesis of β,β′-dioxochlorins","year":2003,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":58,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Saint Mary's University","funders":"National Science Foundation","keywords":"Chemistry; Chromophore; Crystal structure; Base (topology); Reduction (mathematics); Stereochemistry; Crystallography; Photochemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01181099213399327,"gpt":0.2220640869799376,"spread":0.2102530948459443,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005368982,0.0002372345,0.0004296149,0.0001187523,0.00005218681,0.00001717694,0.0003681714,0.0001018026,0.001254769],"category_scores_gemma":[0.0003240266,0.0002324328,0.00016351,0.0003006649,0.000210622,0.0001745157,0.00003094001,0.000112973,0.0000532808],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005361882,"about_ca_system_score_gemma":0.00005251606,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006514069,"about_ca_topic_score_gemma":0.000002479063,"domain_scores_codex":[0.9981504,0.00009139784,0.0005967212,0.0003649639,0.0004314539,0.0003650661],"domain_scores_gemma":[0.9985946,0.0002886357,0.0003632143,0.0005793343,0.00006225516,0.0001118988],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003134357,0.0001000086,0.002262373,0.0001741681,0.00002093898,0.000006218,0.00009355554,0.00007299038,0.9950976,0.001472617,0.0005066694,0.0001615187],"study_design_scores_gemma":[0.0003078521,0.0000346869,0.002511533,0.00005769687,0.00003517744,0.00001773232,0.0000772603,0.00000637531,0.9956217,0.0001479882,0.0009580139,0.0002239681],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876314,0.0000629671,0.0004116651,0.0001401551,0.0002898509,0.0001320079,0.00003575808,0.00006894626,0.01122722],"genre_scores_gemma":[0.9982156,0.00001436924,0.001451356,0.0001290052,0.00005055062,0.00002039604,0.000007501085,0.00002807111,0.00008320429],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01114401,"threshold_uncertainty_score":0.9996582,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2949321702","doi":"10.1016/s0040-4039(01)01131-5","title":"Alkylation of 1-alkynes in THF","year":2001,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":52,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Alkylation; Halide; Iodide; Alkyl; Catalysis; Primary (astronomy); Methyl iodide; Organic chemistry; Medicinal chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.008182566193879035,"gpt":0.2300260564475523,"spread":0.2218434902536732,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006363841,0.00006438802,0.00007450202,0.00005050453,0.00001147297,0.000002110758,0.0000724807,0.00004131035,0.00003334562],"category_scores_gemma":[0.00001673653,0.00006040622,0.00003801565,0.00007095437,0.0000546536,0.000003591404,0.00001090091,0.00004334252,0.000006071475],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008294101,"about_ca_system_score_gemma":0.00001254893,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004089799,"about_ca_topic_score_gemma":0.00003542247,"domain_scores_codex":[0.9995283,0.00001349935,0.0001257307,0.0001257601,0.00009366873,0.0001130618],"domain_scores_gemma":[0.9998122,0.000008313262,0.00003471736,0.0001008942,0.00001472504,0.00002909459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00008573553,0.00005969748,0.03576237,0.00001332711,0.00001166999,0.00001269728,0.00003863955,0.0001795647,0.9566066,0.0002279857,0.003718823,0.003282872],"study_design_scores_gemma":[0.001541477,0.0004379508,0.7327006,0.00007013302,0.00001551787,0.0000721396,0.0001193781,0.000042762,0.1201872,0.0002759935,0.1442426,0.0002942289],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955597,0.0002513365,0.0002862307,0.002070219,0.00008379784,0.00005753851,0.000004394929,0.000005620448,0.001681193],"genre_scores_gemma":[0.9979852,0.0001088002,0.0002165639,0.001287001,0.0001495814,0.000003952718,0.0000778607,0.000006611425,0.0001643685],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8364194,"threshold_uncertainty_score":0.2463294,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2068323004","doi":"10.1016/j.tetlet.2008.06.022","title":"Mild, efficient and rapid O-debenzylation of ortho-substituted phenols with trifluoroacetic acid","year":2008,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Protein Tyrosine Phosphatases","field":"Biochemistry, Genetics and Molecular Biology","cited_by":51,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Trifluoroacetic acid; Phenols; Carbamate; Aryl; Ether; Organic chemistry; Ring (chemistry); Trifluoroacetic anhydride; Medicinal chemistry; Phenol; Benzene; Chelation; Alkyl","retraction":null,"screen_n_in":null,"score":{"opus":0.01042252318492489,"gpt":0.2007526555701556,"spread":0.1903301323852307,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008024948,0.0001637144,0.0001641657,0.00005538066,0.00007422644,0.000007129824,0.0001090728,0.00006782504,0.00001636978],"category_scores_gemma":[0.00003534998,0.0001430361,0.00004029971,0.0001235118,0.0002683762,0.000005176252,0.00003843211,0.00006542023,0.000003330264],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001288388,"about_ca_system_score_gemma":0.00003874087,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002447468,"about_ca_topic_score_gemma":0.000005008028,"domain_scores_codex":[0.9990907,0.00003616144,0.0001920061,0.0003082326,0.0001657194,0.0002071342],"domain_scores_gemma":[0.9994758,0.00001021203,0.0001038136,0.0003056651,0.00003815035,0.00006635713],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002277692,0.00005735251,0.002933359,0.00002762752,0.00004966973,0.00001157222,0.00005696985,0.0005217355,0.9941949,0.00009318416,0.0005012825,0.001324561],"study_design_scores_gemma":[0.001240698,0.0002375807,0.01603322,0.00002113368,0.00002659282,0.00005587599,0.00001147473,0.00006836205,0.9807616,0.000001704306,0.001349017,0.0001926855],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889246,0.006739626,0.003568803,0.0002947784,0.00003450442,0.0003069814,0.00002576633,0.0000204744,0.00008444376],"genre_scores_gemma":[0.996476,0.0001361857,0.002833285,0.0003326892,0.00004526166,0.00002097717,0.0001199673,0.00002101235,0.00001465404],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01343326,"threshold_uncertainty_score":0.5832844,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1992557022","doi":"10.1016/j.tetlet.2010.09.134","title":"The traceless Staudinger ligation with fluorine-18: a novel and versatile labeling technique for the synthesis of PET-radiotracers","year":2010,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Fluorine; Combinatorial chemistry; Ligation; Radiochemistry; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01213106333610688,"gpt":0.2414027682930477,"spread":0.2292717049569408,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002416466,0.000139316,0.0001274626,0.0000148647,0.0003302176,0.00004613623,0.0002457072,0.00005909089,0.00004513686],"category_scores_gemma":[0.0001164765,0.00008813335,0.00005254463,0.0000952109,0.0002791235,0.00005570777,0.0000200697,0.0002772755,4.798819e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002854513,"about_ca_system_score_gemma":0.0000264323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003087798,"about_ca_topic_score_gemma":0.00002514912,"domain_scores_codex":[0.9992453,0.000004054767,0.0001968419,0.0002151924,0.0001431625,0.0001954157],"domain_scores_gemma":[0.9980568,0.001314031,0.0001510325,0.0003908351,0.00004528488,0.00004206547],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000373069,0.00002758182,0.0002040861,0.00009211935,0.00004487354,3.779958e-7,0.0001206572,0.00004060871,0.9964484,0.0002471415,0.0003779899,0.002358885],"study_design_scores_gemma":[0.0002695892,0.000007072778,0.0001110125,0.00004542306,0.00007479775,0.00002382255,0.000424999,0.0004833172,0.9923285,0.00001894912,0.006087075,0.0001254758],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9888899,0.00004091037,0.004139155,0.006063909,0.00002967739,0.000299559,0.00005820721,0.00004956485,0.0004291239],"genre_scores_gemma":[0.9953151,0.0000246815,0.003757638,0.0000747778,0.0001175369,0.0005601787,0.00000724036,0.00002495773,0.0001178869],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006425209,"threshold_uncertainty_score":0.3593974,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2067016760","doi":"10.1016/s0040-4039(01)00264-7","title":"Novel chiral phosphines derived from limonene: the synthesis and structure of 4,8-dimethyl-2-phosphabicyclo[3.3.1]nonane","year":2001,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada; Brock University","keywords":"Nonane; Chemistry; Limonene; Oxide; Organic chemistry; Stereochemistry; Medicinal chemistry; Chromatography","retraction":null,"screen_n_in":null,"score":{"opus":0.007639070806378095,"gpt":0.1970407487753434,"spread":0.1894016779689653,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001152961,0.0005281243,0.0006178549,0.00007665187,0.0002252696,0.00008425346,0.0007732048,0.0002418514,0.002311768],"category_scores_gemma":[0.0002836856,0.0004087852,0.0001852693,0.0003072271,0.0005099676,0.0001807679,0.0001958447,0.0004163013,0.00001651095],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001017293,"about_ca_system_score_gemma":0.00003824609,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001719526,"about_ca_topic_score_gemma":0.0001504383,"domain_scores_codex":[0.9976529,0.00003799397,0.0005613493,0.0006685841,0.0005105668,0.000568587],"domain_scores_gemma":[0.9973415,0.001154838,0.0003212793,0.0009814351,0.00004918069,0.0001518023],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001351431,0.0000863731,0.02721762,0.00004809969,0.0002250776,0.00002059501,0.0003968386,0.00002933193,0.9636732,0.00002402238,0.0004755727,0.007668137],"study_design_scores_gemma":[0.0005944032,0.000015622,0.05531062,0.00009638311,0.0001906547,0.00004912619,0.0002244776,0.0001130784,0.9409363,0.0001890138,0.001809713,0.0004705701],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924222,0.001558141,0.0001189264,0.004591487,0.0002173227,0.0001401851,0.0002460361,0.0001612566,0.0005444251],"genre_scores_gemma":[0.9947827,0.0002308255,0.00338328,0.001016354,0.0002860402,0.00001693276,0.00002189761,0.0001055875,0.0001563348],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.028093,"threshold_uncertainty_score":0.9998364,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1977052508","doi":"10.1016/j.tetlet.2004.12.105","title":"An efficient strategy for the preparation of one-bead-one-peptide libraries on a new biocompatible solid support","year":2005,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":44,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"BC Innovation Council","funders":"Universidad de Buenos Aires","keywords":"Chemistry; Peptide; Linker; Biocompatible material; Combinatorial chemistry; Bead; Peptide synthesis; Solid-phase synthesis; Mass spectrometry; Chromatography; Sequence (biology); Biochemistry; Biomedical engineering","retraction":null,"screen_n_in":null,"score":{"opus":0.02474956596652084,"gpt":0.2959783849865245,"spread":0.2712288190200036,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001191379,0.000131823,0.0001684049,0.00003400734,0.00006882648,0.00004376284,0.0002222856,0.00007157008,0.00008696742],"category_scores_gemma":[0.0000245195,0.0001023347,0.0001521099,0.00007440679,0.00007709786,0.000008024416,0.0000209608,0.00005129057,0.000007227646],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001529093,"about_ca_system_score_gemma":0.00004982619,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003933154,"about_ca_topic_score_gemma":0.00004133773,"domain_scores_codex":[0.9990904,0.00002400016,0.000250245,0.0002820936,0.0001489541,0.000204302],"domain_scores_gemma":[0.9993846,0.00004351513,0.0001097993,0.0003642153,0.00002431293,0.00007350426],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001407687,0.0001908198,0.0001335223,0.00001244839,0.00009047349,1.040965e-7,0.00007209863,0.01812245,0.9687506,0.0001304085,0.006428548,0.005927757],"study_design_scores_gemma":[0.0003150056,0.0003973667,0.0006128508,0.00001290125,0.00006592037,5.57217e-7,0.00003990953,0.00248002,0.987599,0.00001891845,0.008316844,0.0001406846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896886,0.0001255129,0.0071038,0.002483597,0.00002202556,0.0002457306,0.00002336107,0.00001545534,0.0002919255],"genre_scores_gemma":[0.9967711,0.0000191372,0.001357207,0.001123549,0.000382251,0.00002264147,0.0001271264,0.00001674365,0.0001802474],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01884842,"threshold_uncertainty_score":0.417309,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2019227817","doi":"10.1016/j.tetlet.2010.10.065","title":"Ligand-promoted reaction on silver nanoparticles: phosphine-promoted, silver nanoparticle-catalyzed cyclization of 2-(1-hydroxy-3-arylprop-2-ynyl)phenols","year":2010,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"National Natural Science Foundation of China","keywords":"Chemistry; Phosphine; Catalysis; Ligand (biochemistry); Phenols; Toluene; Solvent; Nanoparticle; Silver nanoparticle; Organic chemistry; Combinatorial chemistry; Nanotechnology","retraction":null,"screen_n_in":null,"score":{"opus":0.01008434134977568,"gpt":0.2305453797820914,"spread":0.2204610384323157,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003449797,0.0005526049,0.0005634166,0.0002423505,0.0002409872,0.00008593609,0.0004927532,0.0003658231,0.000977765],"category_scores_gemma":[0.0003962824,0.0005565991,0.0002871594,0.0007201087,0.0003698639,0.0006014449,0.00009960614,0.0008564113,0.000658486],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002923655,"about_ca_system_score_gemma":0.00009417907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004439263,"about_ca_topic_score_gemma":0.00009847533,"domain_scores_codex":[0.9965155,0.00003400875,0.0009542486,0.0008913244,0.0008371585,0.0007677273],"domain_scores_gemma":[0.9973444,0.0002256571,0.0005394861,0.001446017,0.0001542011,0.0002902317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001823813,0.0006422909,0.001150142,0.0001168952,0.0001347464,0.00002805754,0.0004743159,0.0001050473,0.993931,0.0002029732,0.0009952924,0.002036835],"study_design_scores_gemma":[0.001895237,0.00006957114,0.002103574,0.0001213538,0.0001900423,0.0000761968,0.0001377077,0.001389833,0.9913758,0.0001456634,0.001905767,0.0005892792],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941885,0.00003079701,0.0000591645,0.002172477,0.0005961324,0.0003968308,0.00005802319,0.0005235428,0.001974484],"genre_scores_gemma":[0.9981051,0.00001449879,0.0002619382,0.0003900657,0.0002555102,0.00006903613,0.0002337525,0.0001380363,0.0005320542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00391656,"threshold_uncertainty_score":0.9999354,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2950675278","doi":"10.1016/j.tetlet.2009.12.080","title":"Catalytic alkylation of benzylic C–H bonds with 1,3-dicarbonyl compounds utilizing oxygen as terminal oxidant","year":2009,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"Canada Research Chairs; McGill University","keywords":"Chemistry; Catalysis; Alkylation; Terminal (telecommunication); Oxygen; Medicinal chemistry; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01043128673356813,"gpt":0.2360109016705718,"spread":0.2255796149370036,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00009238303,0.0003144407,0.0003423434,0.00009647731,0.0001064611,0.00003814458,0.0003079332,0.0001207842,0.000354045],"category_scores_gemma":[0.00004182654,0.0003064742,0.00009100349,0.0003010386,0.0001913572,0.0001537576,0.00003307841,0.000361034,0.00003904654],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002922354,"about_ca_system_score_gemma":0.00008828205,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009572229,"about_ca_topic_score_gemma":0.000008457467,"domain_scores_codex":[0.9982536,0.00001262762,0.000413331,0.0004526037,0.0004658349,0.0004019603],"domain_scores_gemma":[0.9988381,0.00008084084,0.0002833203,0.0005938187,0.00005493735,0.000149001],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005507774,0.0001335609,0.001847185,0.00007736061,0.00006413536,0.00006475915,0.0002312396,0.0000291887,0.9955001,0.00005229014,0.0005716606,0.001373454],"study_design_scores_gemma":[0.001029017,0.0001164746,0.009208532,0.0001869157,0.0001412163,0.0005693036,0.0003837889,0.0003329646,0.9859582,0.00004985653,0.001556931,0.000466826],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9608429,0.00005619085,0.00006285831,0.001740715,0.00002655931,0.00007860364,0.00002321807,0.0001609895,0.03700794],"genre_scores_gemma":[0.9984205,0.000004199913,0.0004539975,0.000371683,0.000144797,0.000006668306,0.000126836,0.0000407558,0.0004305092],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03757763,"threshold_uncertainty_score":0.9999387,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2062307305","doi":"10.1016/j.tetlet.2010.06.129","title":"Synthesis of the human aldose reductase inhibitor rubrolide L","year":2010,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Aldose reductase; Butenolide; Aldose reductase inhibitor; Yield (engineering); Stereochemistry; Aldose; Biochemistry; Enzyme; Glycoside","retraction":null,"screen_n_in":null,"score":{"opus":0.00727436758997491,"gpt":0.2222618681518189,"spread":0.214987500561844,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001059885,0.0001603961,0.0001647501,0.00003582393,0.0001414866,0.00002194239,0.00037795,0.000134367,0.001967891],"category_scores_gemma":[0.0001728061,0.0001294887,0.000159373,0.0001020458,0.0002432635,0.00006039767,0.0000584687,0.0004008109,0.00002249462],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004222272,"about_ca_system_score_gemma":0.00003680379,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009454713,"about_ca_topic_score_gemma":0.00004597456,"domain_scores_codex":[0.9989591,0.00001171556,0.0002836494,0.0002395373,0.000262162,0.0002438521],"domain_scores_gemma":[0.9989823,0.00008516634,0.0001551413,0.0006500625,0.00003404737,0.00009332917],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000003713544,0.00004616702,0.002475853,0.00007542029,0.00002269653,0.000006584724,0.00007975554,0.000003401447,0.9866201,0.0001676161,0.01013696,0.0003617578],"study_design_scores_gemma":[0.0002035254,0.000001577834,0.001055152,0.00003076484,0.00003259882,0.0000253893,0.00005184961,0.000005243262,0.9910513,0.00005647262,0.007334417,0.0001517583],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9819388,0.00001098866,0.000001246134,0.003532678,0.0002334906,0.00003820873,0.0000518108,0.00005959225,0.01413318],"genre_scores_gemma":[0.9981393,0.000001053849,0.0001301686,0.0005265259,0.0004413025,0.00001647828,0.000011236,0.00002724196,0.0007066713],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01620052,"threshold_uncertainty_score":0.9989445,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2028632007","doi":"10.1016/s0040-4039(02)00896-1","title":"Novel sesterterpenoid and norsesterterpenoid RCE-protease inhibitors isolated from the marine sponge Hippospongia sp.","year":2002,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":39,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"National Institutes of Health","keywords":"Sponge; Chemistry; Protease; Stereochemistry; Terpenoid; Biochemistry; Enzyme; Botany","retraction":null,"screen_n_in":null,"score":{"opus":0.009180977587304762,"gpt":0.1980565580939695,"spread":0.1888755805066648,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001642755,0.0003804145,0.0002408758,0.00005362403,0.0001700319,0.0001055125,0.0003812768,0.0001682514,0.0003665991],"category_scores_gemma":[0.0000707056,0.0002834105,0.0001098342,0.0001549342,0.0001735176,0.00002225621,0.0003865374,0.000319668,0.00005474364],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002387648,"about_ca_system_score_gemma":0.0000103864,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005986774,"about_ca_topic_score_gemma":0.0001423907,"domain_scores_codex":[0.9982052,0.00008040683,0.0003229423,0.0007267469,0.0002119276,0.0004527511],"domain_scores_gemma":[0.9989167,0.00003883152,0.0001252385,0.0007175606,0.00004109824,0.000160593],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.000199925,0.0001003857,0.01754466,0.00002329147,0.00009956458,0.00003410511,0.0001439968,0.000006659448,0.9438979,0.000006460698,0.01152761,0.02641543],"study_design_scores_gemma":[0.009368991,0.002062563,0.5440857,0.0002018768,0.0004697453,0.0009627949,0.0002449644,0.003891123,0.1916431,0.00008813172,0.2430319,0.003949049],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885182,0.0007682442,0.0001480853,0.009246373,0.0004236987,0.0004618831,0.00004934334,0.00004712777,0.0003370363],"genre_scores_gemma":[0.9906504,0.0001699376,0.0004671178,0.006541236,0.0008506358,0.0000174352,0.0001989744,0.0000555891,0.001048729],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7522548,"threshold_uncertainty_score":0.9999618,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2011978216","doi":"10.1016/j.tetlet.2008.12.043","title":"Synthesis of betulinic acid acyl glucuronide for application in anticancer prodrug monotherapy","year":2008,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Natural product bioactivities and synthesis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":38,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Université du Québec à Chicoutimi","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Betulinic acid; Chemistry; Prodrug; Glucuronate; Glucuronide; In vitro; Hydrolysis; Bromide; Combinatorial chemistry; Organic chemistry; Biochemistry; Metabolism","retraction":null,"screen_n_in":null,"score":{"opus":0.01055821635615534,"gpt":0.2457909716092121,"spread":0.2352327552530568,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001684594,0.0001382668,0.0002077003,0.00006019284,0.00005001595,0.000004292194,0.0001775513,0.00009036163,0.000006612718],"category_scores_gemma":[0.00009491217,0.0001286949,0.0001107967,0.00009319067,0.0001354278,0.000007575085,0.00001953564,0.00006595904,0.000001984297],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002820961,"about_ca_system_score_gemma":0.00003517319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008514674,"about_ca_topic_score_gemma":0.00003312541,"domain_scores_codex":[0.9990421,0.00003514676,0.000244493,0.0003517733,0.0001037966,0.0002226682],"domain_scores_gemma":[0.9994476,0.00005093352,0.0001106558,0.0003322094,0.00002892972,0.00002967849],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002022987,0.0000609003,0.005734782,0.00003556001,0.00003491441,6.140823e-7,0.00005617462,0.00002744283,0.9755158,0.00001451852,0.0008798699,0.01743713],"study_design_scores_gemma":[0.0003541982,0.00007505242,0.008624987,0.00001201286,0.00001110095,0.000004025492,0.00002632239,0.00005298261,0.9835659,0.00002154105,0.007087868,0.0001640458],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942536,0.0006060512,0.001879104,0.002654623,0.00006683343,0.0004422224,0.000026284,0.00001099767,0.00006032762],"genre_scores_gemma":[0.9965497,0.000418964,0.001960428,0.0006406652,0.0001773749,0.0001468498,0.00002132949,0.00002549744,0.00005921164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01727309,"threshold_uncertainty_score":0.5248026,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2111061004","doi":"10.1016/j.tetlet.2004.05.072","title":"Convenient route to centro-substituted triquinacene skeletons via the interrupted Nazarov reaction","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Alberta","funders":"National Science Foundation","keywords":"Chemistry; Ozonolysis; Aldol reaction; Tandem; Organic chemistry; Trapping; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01281789504338475,"gpt":0.2199380949113545,"spread":0.2071201998679698,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000175341,0.0002765966,0.0002692674,0.00007774166,0.0002299848,0.00009290172,0.0004990709,0.00008536439,0.000428177],"category_scores_gemma":[0.00009257031,0.000203215,0.0001743465,0.0001971352,0.0001078312,0.0001382797,0.00008869315,0.000278093,0.0002842878],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005945316,"about_ca_system_score_gemma":0.00004412192,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006946326,"about_ca_topic_score_gemma":0.00008003144,"domain_scores_codex":[0.9983668,0.00003261707,0.0004069813,0.0003782744,0.0003483876,0.0004669033],"domain_scores_gemma":[0.9988689,0.0001095669,0.0001260802,0.0006957516,0.00003842101,0.0001612406],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001166878,0.0001052301,0.0002212157,0.0000349307,0.00009986255,0.00001910422,0.001074473,0.0002438312,0.9852042,0.00009242308,0.00288171,0.009906339],"study_design_scores_gemma":[0.002902852,0.0001287984,0.005191223,0.0004840671,0.0001773805,0.0001786267,0.001212359,0.0004278317,0.8034546,0.0003092472,0.1844849,0.001048082],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9611611,0.00007879621,0.001469467,0.03302979,0.0004605587,0.000201033,0.00001062702,0.0002312256,0.003357354],"genre_scores_gemma":[0.9957187,0.0000108723,0.0006002652,0.003026009,0.0002532057,0.00005873906,0.00002760498,0.00003840948,0.0002661626],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1817496,"threshold_uncertainty_score":0.8286867,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1980763553","doi":"10.1016/j.tetlet.2013.08.137","title":"Sydowiols A–C: Mycobacterium tuberculosis protein tyrosine phosphatase inhibitors from an East China Sea marine-derived fungus, Aspergillus sydowii","year":2013,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Protein Tyrosine Phosphatases","field":"Biochemistry, Genetics and Molecular Biology","cited_by":36,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of British Columbia","funders":"","keywords":"Pyrogallol; Chemistry; Fungus; Aspergillus fumigatus; China sea; Mycobacterium tuberculosis; Microbiology; Stereochemistry; Biochemistry; Botany; Tuberculosis; Biology","retraction":null,"screen_n_in":null,"score":{"opus":0.00530791728103838,"gpt":0.2076700821195081,"spread":0.2023621648384697,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001893164,0.000770312,0.0005131966,0.0001174681,0.0002336327,0.0002577999,0.0007368793,0.0003423654,0.001179227],"category_scores_gemma":[0.0001344267,0.0007576155,0.0002475967,0.0002572615,0.00029249,0.0001103811,0.0005462508,0.0003732045,0.0003022872],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001210168,"about_ca_system_score_gemma":0.00008007934,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006237112,"about_ca_topic_score_gemma":0.0001512671,"domain_scores_codex":[0.9964091,0.0002059795,0.0006495693,0.00130139,0.0004652726,0.0009686988],"domain_scores_gemma":[0.9976101,0.00001622211,0.0002575046,0.001489081,0.000112583,0.0005145014],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001764624,0.0002232537,0.007529807,0.00005480084,0.0001602766,0.00003788787,0.00005733397,0.00003818595,0.9711156,0.00005178276,0.01441074,0.0061438],"study_design_scores_gemma":[0.001326889,0.0004494506,0.07547425,0.00008228745,0.00006917219,0.00002089252,0.00004070614,0.00008321748,0.915284,0.00005819345,0.006144951,0.0009660193],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892533,0.003329059,0.0003154934,0.003487523,0.000495159,0.00173978,0.001071434,0.0001920301,0.0001161699],"genre_scores_gemma":[0.9843291,0.0000810236,0.002664492,0.003146854,0.001047398,0.0005881967,0.007850607,0.0001685609,0.0001237482],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06794444,"threshold_uncertainty_score":0.9997338,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2164131714","doi":"10.1016/s0040-4039(02)01273-x","title":"The rhodium(II)-catalyzed reaction of N-bis(trimethylsilylmethyl)diazoamides: steric, electronic and conformational effects","year":2002,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Regina","funders":"Natural Sciences and Engineering Research Council of Canada; University of Regina","keywords":"Chemistry; Regioselectivity; Steric effects; Amide; Electronic effect; Substituent; Alkyl; Rhodium; Stereochemistry; Catalysis; Medicinal chemistry; Transition state; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.007205055084142336,"gpt":0.2035143111082466,"spread":0.1963092560241042,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002497954,0.0002458012,0.0002588858,0.0001054915,0.0003109132,0.00004945499,0.0002224172,0.0001233755,0.0001688141],"category_scores_gemma":[0.00009397369,0.0002041403,0.0001095409,0.0001784569,0.0001575547,0.0002730551,0.0000637897,0.0003941602,0.00004177097],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002722819,"about_ca_system_score_gemma":0.00003139138,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006175148,"about_ca_topic_score_gemma":0.000007515784,"domain_scores_codex":[0.9983879,0.00004740687,0.0004192852,0.0002852599,0.0004117803,0.000448319],"domain_scores_gemma":[0.9986421,0.0004931153,0.0003096633,0.000410158,0.00005911703,0.00008580684],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003941658,0.0000378465,0.0000502399,0.0001674444,0.00006542614,0.000002346614,0.0004477176,0.000004055104,0.9638851,0.0006998445,0.0003449207,0.03425561],"study_design_scores_gemma":[0.001341077,0.00009031544,0.000683953,0.00005184034,0.00008584273,0.00008546346,0.0004505377,0.0004040548,0.9683827,0.0001064516,0.02799066,0.0003270636],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919847,0.001212291,0.0004034643,0.0008616766,0.0002039672,0.0002124184,0.000008116212,0.0001389424,0.004974438],"genre_scores_gemma":[0.9985303,0.0004043181,0.0001706359,0.0002206971,0.0001177624,0.00004533336,0.00003218263,0.00003357103,0.0004451888],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03392855,"threshold_uncertainty_score":0.83246,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2953063985","doi":"10.1016/j.tetlet.2010.08.083","title":"Facile route for N1-aryl benzotriazoles from diazoamino arynes via CuI-mediated intramolecular N-arylation","year":2010,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"","funders":"Canadian Institute of Steel Construction","keywords":"Intramolecular force; Chemistry; Aryne; Aryl; Combinatorial chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Alkyl","retraction":null,"screen_n_in":null,"score":{"opus":0.006528066206307819,"gpt":0.2281052911462317,"spread":0.2215772249399238,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001436991,0.0003692934,0.00035445,0.0001245307,0.0002310911,0.0001623413,0.0003846629,0.0003144221,0.000798115],"category_scores_gemma":[0.0003053361,0.0004055356,0.0002511558,0.0001733968,0.0002062699,0.0002914443,0.00005962938,0.0006185103,0.0002105012],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001463297,"about_ca_system_score_gemma":0.00005675368,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001192964,"about_ca_topic_score_gemma":0.0003176586,"domain_scores_codex":[0.9979577,0.000001349536,0.0005125296,0.0006409186,0.0003571761,0.0005303177],"domain_scores_gemma":[0.9981785,0.000566591,0.0002224942,0.000773297,0.00007542988,0.0001836862],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004893263,0.0000910385,0.005584103,0.00004477782,0.00009941548,0.00001460057,0.000232139,0.0001317781,0.9883979,0.00002770104,0.001919101,0.003408527],"study_design_scores_gemma":[0.001756151,0.00001842493,0.009978166,0.00003722344,0.000168388,0.00001762964,0.00008765946,0.007364445,0.9664518,0.0003419183,0.01311425,0.0006639768],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916217,0.00005786515,0.004059389,0.00165845,0.0008949892,0.0002786441,0.000857569,0.000446114,0.000125299],"genre_scores_gemma":[0.9940019,0.000006890217,0.0005505275,0.0005130772,0.0008240214,0.0001144304,0.003776754,0.00008784112,0.0001245291],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02194612,"threshold_uncertainty_score":0.9998397,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2085912475","doi":"10.1016/j.tetlet.2007.09.122","title":"Rapid syntheses of (±)-pterocarpans and isoflavones via the gold-catalyzed annulation of aldehydes and alkynes","year":2007,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":35,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"","keywords":"Annulation; Chemistry; Salicylaldehyde; Isoflavones; Catalysis; Organic chemistry; Combinatorial chemistry; Stereochemistry; Schiff base","retraction":null,"screen_n_in":null,"score":{"opus":0.01017869680895954,"gpt":0.2212761799134702,"spread":0.2110974831045106,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000183978,0.00009486825,0.0001226676,0.00004264924,0.00003167842,0.000004149143,0.00007437474,0.00004909538,0.00000506927],"category_scores_gemma":[0.00004344606,0.00006773703,0.00003871997,0.00004383218,0.0003492796,0.000007221078,0.00002606935,0.00004072687,3.362509e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000002881032,"about_ca_system_score_gemma":0.000007184378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005614722,"about_ca_topic_score_gemma":0.00002757129,"domain_scores_codex":[0.9994292,0.00001909748,0.0001768771,0.0001472544,0.0001103114,0.0001172661],"domain_scores_gemma":[0.9996283,0.00008952795,0.00008458294,0.0001258586,0.00003183158,0.00003991906],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001129232,0.00002824924,0.004840241,0.00005513868,0.00004976486,0.00000156396,0.0001413027,0.000004898935,0.9803761,0.000146023,0.0003492856,0.01389453],"study_design_scores_gemma":[0.0005304913,0.000384771,0.3337864,0.00008932658,0.00007766167,0.00007234723,0.0004383714,0.00002240973,0.6579946,0.0001634412,0.006246611,0.0001935298],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952897,0.001945718,0.00106238,0.001374379,0.00005240643,0.00009548223,0.00001748253,0.000005064393,0.0001574149],"genre_scores_gemma":[0.9987891,0.0003040351,0.0002950787,0.0004537854,0.00009956806,0.000002151859,0.00003118019,0.000008004272,0.00001709002],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3289462,"threshold_uncertainty_score":0.2762236,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2061138099","doi":"10.1016/j.tetlet.2009.09.095","title":"Pybox ligand-promoted copper(I)-catalyzed three-component tandem coupling-annulation of terminal alkynes, amines and ortho-alkynylaryl aldehydes","year":2009,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"National Natural Science Foundation of China","keywords":"Chemistry; Tandem; Annulation; Ligand (biochemistry); Catalysis; Copper; Imine; Combinatorial chemistry; Terminal (telecommunication); Medicinal chemistry; Organic chemistry; Receptor","retraction":null,"screen_n_in":null,"score":{"opus":0.01248865047687847,"gpt":0.238268449780178,"spread":0.2257797993032996,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001720231,0.0004009398,0.0005330887,0.0001874635,0.0001693606,0.00006320655,0.0002576214,0.0001980032,0.000116121],"category_scores_gemma":[0.00006735103,0.0004030451,0.0001664859,0.0002310052,0.000250391,0.0002879496,0.00005811606,0.0003189202,0.00002149353],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00017032,"about_ca_system_score_gemma":0.0000416274,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000244139,"about_ca_topic_score_gemma":0.00008256509,"domain_scores_codex":[0.9978401,0.000008421867,0.0006612295,0.0005639459,0.0004744179,0.0004518701],"domain_scores_gemma":[0.9986492,0.000158705,0.0003453766,0.0005966743,0.00008015507,0.0001698468],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005354795,0.0001942611,0.01759215,0.0001013197,0.00009101976,0.00005041153,0.0001788883,0.0001533486,0.9760197,0.00006106756,0.0003849534,0.005119328],"study_design_scores_gemma":[0.003783297,0.0001553105,0.186062,0.0004754545,0.0005543738,0.0006292055,0.0003267885,0.01059333,0.7932764,0.000276643,0.002523271,0.001343961],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957424,0.000431923,0.0003503654,0.002394221,0.00009720851,0.0002153856,0.00003393369,0.0002290866,0.000505437],"genre_scores_gemma":[0.9987315,0.00005446454,0.000343839,0.0001924765,0.000200615,0.00001322853,0.0003072994,0.00004526886,0.000111303],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1827433,"threshold_uncertainty_score":0.9998422,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2060422274","doi":"10.1016/s0040-4039(99)02131-0","title":"Total synthesis of (−)-eburnamonine and (+)-epi-eburnamonine from a chiral non-racemic 4,4-disubstituted γ-lactone","year":2000,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":34,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Regina","funders":"University of Saskatchewan","keywords":"Chemistry; Carbenoid; Lactone; Total synthesis; Stereochemistry; Organic chemistry; Catalysis; Rhodium","retraction":null,"screen_n_in":null,"score":{"opus":0.003565693292463517,"gpt":0.1980460813036118,"spread":0.1944803880111483,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007627977,0.0002303126,0.0002873406,0.00006030291,0.00006081237,0.0000128555,0.000156087,0.0001181079,0.0004110748],"category_scores_gemma":[0.00003435502,0.0002109662,0.0001106729,0.00008853945,0.0002759204,0.00001403809,0.00003091406,0.0001462327,0.00001975395],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001703223,"about_ca_system_score_gemma":0.00003266977,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002391741,"about_ca_topic_score_gemma":0.00001506071,"domain_scores_codex":[0.9988189,0.00002776352,0.0002925648,0.0003742201,0.0002083007,0.0002782865],"domain_scores_gemma":[0.999431,0.0000409473,0.0000877481,0.0002593641,0.00002690216,0.000154011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004934673,0.0001282177,0.002756238,0.00002872638,0.0001569076,0.00003545749,0.00006912716,0.0001286443,0.982129,0.00001337417,0.00368886,0.01037198],"study_design_scores_gemma":[0.003679059,0.0009797107,0.4445477,0.0003579199,0.0003042647,0.0002719428,0.0001150028,0.0002768504,0.5319538,0.00009733713,0.0164399,0.0009766136],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961013,0.0008596979,0.0001099093,0.001592675,0.0001079161,0.0001329009,0.0001477875,0.00002000968,0.0009277893],"genre_scores_gemma":[0.9967431,0.0003826751,0.0008124172,0.0008100887,0.000403308,0.00001564131,0.0002527247,0.00002645129,0.0005535412],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4501753,"threshold_uncertainty_score":0.8602952,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2089938799","doi":"10.1016/s0040-4039(99)01994-2","title":"Magnesium mediated carbometallation of propargyl alcohols: direct routes to dihydroxydienes and enediyne alcohols","year":2000,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Chemistry; Enediyne; Propargyl; Magnesium; Electrophile; Propargyl alcohol; Reagent; Organic chemistry; Alcohol; Chelation; Combinatorial chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.008296798099738625,"gpt":0.2197519881710447,"spread":0.211455190071306,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001553649,0.0002711435,0.0003757417,0.0001671914,0.00007514147,0.00003992853,0.0001910309,0.0001103512,0.001195367],"category_scores_gemma":[0.0001217541,0.0002680886,0.00009509287,0.000366109,0.0001408413,0.0002197677,0.00004546717,0.0001500442,0.00009317133],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00012711,"about_ca_system_score_gemma":0.00002993197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005400082,"about_ca_topic_score_gemma":0.00005023926,"domain_scores_codex":[0.9983432,0.00002113476,0.0004223382,0.0004660048,0.0003690328,0.0003782779],"domain_scores_gemma":[0.9989955,0.0002019609,0.0001155524,0.0004611342,0.00004232436,0.0001834685],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004739048,0.00007662306,0.006386699,0.0001258972,0.00007416019,0.00001546137,0.0004126211,0.0002465153,0.9835424,0.00001321655,0.0004645351,0.008594524],"study_design_scores_gemma":[0.002127036,0.0001377083,0.03654126,0.000183101,0.0004387624,0.0001286259,0.0002228876,0.001273601,0.9271233,0.00004293469,0.03053327,0.001247503],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9822934,0.0002094532,0.00001706372,0.002019074,0.0000745689,0.0002003911,0.00006588878,0.0001849188,0.01493525],"genre_scores_gemma":[0.9972555,0.0000435958,0.0002437023,0.0003578015,0.0001684727,0.00005164777,0.0001018812,0.00004833826,0.001729032],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05641905,"threshold_uncertainty_score":0.9999771,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2000016953","doi":"10.1016/j.tetlet.2008.06.020","title":"Rapid in situ synthesis of [11C]methyl azide and its application in 11C click-chemistry","year":2008,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Jewish General Hospital; McGill University; Montreal Neurological Institute and Hospital","funders":"","keywords":"Chemistry; Click chemistry; Azide; Acetonitrile; Methyl iodide; Solvent; Iodide; Triazole; In situ; Nuclear chemistry; Organic chemistry; Combinatorial chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.01482037866174818,"gpt":0.2331699191121732,"spread":0.218349540450425,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001479724,0.0002144535,0.0003179573,0.00005997882,0.00005592434,0.000007061745,0.0002644734,0.0001857836,0.0001845367],"category_scores_gemma":[0.0001311785,0.0002515556,0.00006885424,0.0002946728,0.0001485527,0.00008682355,0.00005595616,0.0003204708,0.00001229455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000111615,"about_ca_system_score_gemma":0.00002890754,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008871554,"about_ca_topic_score_gemma":0.00001799542,"domain_scores_codex":[0.998542,0.00001541292,0.0004980805,0.00046193,0.000187208,0.0002954126],"domain_scores_gemma":[0.9989844,0.0002944695,0.0001678339,0.0004418941,0.00002114543,0.00009024188],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002237659,0.0001407816,0.01001459,0.0002766797,0.0000108869,0.00001233785,0.0001787222,0.00003028803,0.9855418,0.00001705245,0.0001882656,0.003566224],"study_design_scores_gemma":[0.0004654991,0.000002527363,0.006866151,0.00007973826,0.00001334401,0.00003199549,0.00009763945,0.000136728,0.9897378,0.00002985993,0.002299129,0.000239586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991367,0.0002933686,0.00002336389,0.001349936,0.000006701449,0.0001134597,0.00002632081,0.00005444147,0.006765348],"genre_scores_gemma":[0.9989056,0.0002995351,0.0001247827,0.0001862848,0.00007368944,0.0001952173,0.00003709383,0.00002562481,0.0001521992],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007538513,"threshold_uncertainty_score":0.9999937,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2138529811","doi":"10.1016/s0040-4039(00)01790-1","title":"Total synthesis of (±)-6-deoxycastanospermine: an application of the addition of organoboronates to N-acyliminium ions","year":2000,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Indolizidine; Reductive amination; Ring (chemistry); Ion; Total synthesis; Amination; Combinatorial chemistry; Key (lock); Stereochemistry; Organic chemistry; Catalysis; Alkaloid","retraction":null,"screen_n_in":null,"score":{"opus":0.004110496263514832,"gpt":0.2130902693519117,"spread":0.2089797730883969,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006928333,0.000178726,0.0002894694,0.0000331971,0.00004228978,0.000003796831,0.0004123796,0.000100693,0.0042816],"category_scores_gemma":[0.0001241552,0.0001588979,0.0001116958,0.0002566839,0.0002226228,0.0000842946,0.00004543709,0.0001234845,0.0000120174],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008724834,"about_ca_system_score_gemma":0.00003557489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004799408,"about_ca_topic_score_gemma":0.000006465077,"domain_scores_codex":[0.9986774,0.00001875554,0.0004838766,0.0002939696,0.0003257093,0.0002003213],"domain_scores_gemma":[0.9986074,0.0001766738,0.0002394829,0.0008440342,0.00005792974,0.00007448147],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004160587,0.0001487973,0.000391675,0.0001275511,0.00002329754,5.423763e-7,0.0002337125,0.00033165,0.9792025,0.00002613322,0.0001582103,0.01931433],"study_design_scores_gemma":[0.0001649463,0.00001798266,0.002028396,0.00008957155,0.00005331913,0.00001515692,0.0002558886,0.00009261425,0.9966743,0.00002485413,0.0004330961,0.0001498679],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963092,0.00001471261,0.0002701132,0.0008344833,0.00002720973,0.000113078,0.0003378196,0.00004066812,0.00205274],"genre_scores_gemma":[0.998354,0.00000517641,0.001246401,0.0000815664,0.00006477179,0.00002807439,0.00002578398,0.00003764829,0.0001565493],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01916446,"threshold_uncertainty_score":0.9966286,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2173605271","doi":"10.1016/s0040-4039(02)01191-7","title":"Reactivity of the alkene component in the ruthenium-catalyzed [2+2] cycloaddition between an alkene and an alkyne: Part 2","year":2002,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Alkene; Alkyne; Norbornadiene; Ruthenium; Cycloaddition; Reactivity (psychology); Stereoselectivity; Catalysis; Bridged compounds; Medicinal chemistry; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.02776761147321264,"gpt":0.2449835896019694,"spread":0.2172159781287568,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003546358,0.0002467946,0.0003006504,0.00007599123,0.0001684901,0.00004889355,0.0004915581,0.0001198805,0.0003135067],"category_scores_gemma":[0.00005358053,0.0001790405,0.0001049789,0.0002480414,0.0003250128,0.000391704,0.00007146123,0.00046851,0.00001478448],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001484456,"about_ca_system_score_gemma":0.00001338159,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008676667,"about_ca_topic_score_gemma":0.0002135503,"domain_scores_codex":[0.9982855,0.0001263008,0.0003965583,0.0004164353,0.0004369422,0.0003382867],"domain_scores_gemma":[0.9982373,0.0003219331,0.0002289081,0.001093242,0.00002173647,0.00009685333],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00002731836,0.0006386528,0.01691535,0.00006457384,0.0000765134,0.00001479541,0.002336604,0.00003407363,0.965128,0.00006725544,0.002607995,0.01208889],"study_design_scores_gemma":[0.00443258,0.0001302377,0.558635,0.0003230821,0.0006271946,0.0003358636,0.002900116,0.00195445,0.3931283,0.0004476316,0.03556805,0.001517478],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934984,0.00005855102,0.00001855316,0.004442446,0.00008057619,0.0001901209,0.0001862927,0.00006238505,0.001462644],"genre_scores_gemma":[0.9989139,0.00002808982,0.00003955355,0.000334353,0.0003185864,0.00003528044,0.0002499881,0.00003136674,0.00004882019],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5719997,"threshold_uncertainty_score":0.7301059,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2072022540","doi":"10.1016/j.tetlet.2004.06.071","title":"Stereoselective synthesis of the cis-decalin subunit of vinigrol via three pericyclic reactions in cascade","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pericyclic reaction; Decalin; Chemistry; Cascade; Cascade reaction; Tandem; Claisen rearrangement; Stereoselectivity; Ene reaction; Computational chemistry; Stereochemistry; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01025278722100397,"gpt":0.2232240005816932,"spread":0.2129712133606892,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001193679,0.0002259825,0.0003353974,0.000106712,0.00007393606,0.000008636436,0.0004332461,0.0001498066,0.0005934431],"category_scores_gemma":[0.0002276408,0.0001997058,0.0001871018,0.000663382,0.00029644,0.00008668497,0.00007000435,0.0004988954,0.00001143843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005433581,"about_ca_system_score_gemma":0.00009687507,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001777946,"about_ca_topic_score_gemma":0.0007431212,"domain_scores_codex":[0.9985153,0.00003363333,0.0005216575,0.0003195089,0.0003154314,0.0002944359],"domain_scores_gemma":[0.9985855,0.0003049556,0.000330287,0.0006645196,0.00005337647,0.00006139686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003278592,0.0002408651,0.00817546,0.0001058877,0.00008058721,0.000004989529,0.0003136402,0.0002328075,0.9899123,0.00003777465,0.000025408,0.000837543],"study_design_scores_gemma":[0.0005008403,0.00001124802,0.01901171,0.0002185184,0.00006050744,0.00004167412,0.0003603995,0.00003882714,0.9791775,0.0002605463,0.0001335411,0.0001847237],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944569,0.00002789715,0.0002270069,0.001363435,0.00005901543,0.0001184244,0.00004728542,0.00004562734,0.00365434],"genre_scores_gemma":[0.9995478,0.000009955465,0.0001423409,0.00007275169,0.00006768119,0.00003488543,0.000004443301,0.00003974717,0.00008037646],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01083625,"threshold_uncertainty_score":0.8143768,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2155328733","doi":"10.1016/j.tetlet.2005.10.008","title":"Electrogenerated cyanomethyl anion in organic synthesis: a simple diastereoselective synthesis of cis-3-alkyl-1-benzyl-4-ethoxycarbonyl-β-lactams","year":2005,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthesis of β-Lactam Compounds","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Alkyl; Medicinal chemistry; Electrolysis; Lactam; Organic synthesis; Combinatorial chemistry; Organic chemistry; Catalysis; Electrode","retraction":null,"screen_n_in":null,"score":{"opus":0.008667846682126041,"gpt":0.221052344869785,"spread":0.212384498187659,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007738751,0.0008245731,0.001229767,0.0007506558,0.0001316808,0.0000969502,0.001050275,0.0004447789,0.00332834],"category_scores_gemma":[0.001258141,0.0008904043,0.0003771665,0.001249578,0.0002310161,0.0004860193,0.0001483072,0.0007524401,0.0001203131],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001219503,"about_ca_system_score_gemma":0.0001910224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004314593,"about_ca_topic_score_gemma":0.0004610602,"domain_scores_codex":[0.995051,0.0003362006,0.001281444,0.001162008,0.0008108622,0.001358487],"domain_scores_gemma":[0.9955738,0.002274829,0.0005817224,0.001181144,0.0001228247,0.0002657054],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002831371,0.0004757245,0.007747305,0.0001381001,0.0002740268,0.00003370564,0.0004031085,0.0001725771,0.967276,0.00002868335,0.0004830541,0.02268452],"study_design_scores_gemma":[0.000764569,0.00005983766,0.003809594,0.0002233694,0.0001686547,0.00004423026,0.0003323014,0.001539954,0.99082,0.0000531404,0.001270496,0.0009138686],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9928918,0.0004752123,0.0002076,0.001750015,0.00008458754,0.0002711226,0.00005056204,0.0003433494,0.003925701],"genre_scores_gemma":[0.9969811,0.0000823265,0.001418509,0.0005431748,0.0004214474,0.0002111122,0.00002309468,0.0002290628,0.00009011936],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02354393,"threshold_uncertainty_score":0.9993547,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2028039936","doi":"10.1016/j.tetlet.2011.08.103","title":"Microwave-assisted synthesis of N1- and C3-substituted pyrazolo[3,4-d]pyrimidine libraries","year":2011,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":29,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Innovation Trust","keywords":"Chemistry; Alkylation; Mitsunobu reaction; Pyrimidine; Combinatorial chemistry; Combinatorial synthesis; Microwave; Stereochemistry; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01592974506210583,"gpt":0.1975604919232143,"spread":0.1816307468611085,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009540649,0.0001875178,0.0002793787,0.00006532705,0.00005391892,0.00001724177,0.0001981693,0.0001280489,0.0001262052],"category_scores_gemma":[0.0001135159,0.000167407,0.0001496816,0.0001258037,0.0003119549,0.000008929479,0.00009230701,0.00006788618,0.000005103426],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008413398,"about_ca_system_score_gemma":0.00001662433,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009592449,"about_ca_topic_score_gemma":0.00001806461,"domain_scores_codex":[0.9990076,0.00003287289,0.0002760034,0.0003495568,0.0001049,0.0002290031],"domain_scores_gemma":[0.9994041,0.0000367747,0.0001165648,0.0003218778,0.00002708695,0.00009358759],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006992768,0.0000747493,0.00423587,0.00003580661,0.0001553472,0.000005081746,0.00006121821,6.385945e-7,0.987265,0.00008481894,0.0009360685,0.007075482],"study_design_scores_gemma":[0.0001823841,0.00003038771,0.01181331,0.00002557982,0.000111651,0.00001020688,0.00005499817,0.000009620406,0.9858114,0.00003053369,0.001712384,0.0002076154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972129,0.000527413,0.0004184156,0.0003167219,0.00003510611,0.0000643009,0.00001698908,0.00002056986,0.001387551],"genre_scores_gemma":[0.9965025,0.0001189956,0.002809956,0.0003873309,0.00006302957,0.00001103681,0.00002926063,0.00002260776,0.00005532544],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007577443,"threshold_uncertainty_score":0.682666,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2951246593","doi":"10.1016/j.tetlet.2008.10.083","title":"Novel synthesis of 2,2-dialkyl-3-dialkylamino-2,3-dihydro-1H-naphtho[2,1-b]pyrans","year":2008,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthesis and pharmacology of benzodiazepine derivatives","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"Dalhousie University; Acadia University","funders":"Natural Sciences and Engineering Research Council of Canada; Acadia University","keywords":"Chemistry; Enamine; Aldol reaction; Amine gas treating; Formaldehyde; Aldol condensation; Quinone methide; Mannich reaction; Catalysis; Base (topology); Organic chemistry; Medicinal chemistry; Stereochemistry; Quinone","retraction":null,"screen_n_in":null,"score":{"opus":0.02648427443576583,"gpt":0.2424634864264955,"spread":0.2159792119907296,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002405476,0.0004692343,0.000749838,0.0002271163,0.0002406375,0.00001537425,0.0006622838,0.0002454617,0.004044402],"category_scores_gemma":[0.0002832084,0.0004775682,0.0004008558,0.0002742473,0.0007828785,0.0002198049,0.00008155544,0.0003720036,0.0001094737],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009374015,"about_ca_system_score_gemma":0.00007837907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001635398,"about_ca_topic_score_gemma":0.000006415224,"domain_scores_codex":[0.997438,0.00006181436,0.0007226789,0.0006227886,0.0004841876,0.0006705049],"domain_scores_gemma":[0.9977617,0.00100223,0.0003530885,0.0006188485,0.00006534909,0.0001987533],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008500794,0.0003450262,0.005439813,0.0001468516,0.000237051,0.00006669508,0.0006841441,0.0001023712,0.9817535,0.00006042175,0.00661084,0.004468306],"study_design_scores_gemma":[0.0009466581,0.00002883695,0.01250501,0.0000991882,0.0001102292,0.0001283156,0.0001281992,0.0001892999,0.9768971,0.00001462763,0.008381827,0.0005707191],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9814616,0.0003192123,0.0004104247,0.002171272,0.0002887503,0.0001272815,0.0001648296,0.0002126011,0.01484406],"genre_scores_gemma":[0.9956883,0.0001486718,0.001946492,0.001178968,0.000456464,0.00007492321,0.00002292278,0.00008278232,0.0004005264],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01444353,"threshold_uncertainty_score":0.9997676,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1973640189","doi":"10.1016/j.tetlet.2007.11.040","title":"Preparation of 3-substituted-2-pyridin-2-ylindoles: regioselectivity of Larock’s indole annulation with 2-alkynylpyridines","year":2007,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Boehringer Ingelheim (Canada)","funders":"","keywords":"Regioselectivity; Chemistry; Annulation; Steric effects; Indole test; Stereochemistry; Combinatorial chemistry; Organic chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01656273243253544,"gpt":0.2941567161458997,"spread":0.2775939837133643,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006596892,0.0002247463,0.000341846,0.0002338783,0.00007033108,0.0000138115,0.0001704364,0.0001418669,0.0001938187],"category_scores_gemma":[0.0002675969,0.0002203001,0.000102291,0.0006039161,0.0002010004,0.0002979935,0.00002865634,0.0001700021,0.000004733042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001722736,"about_ca_system_score_gemma":0.0001067719,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000119635,"about_ca_topic_score_gemma":0.00009779459,"domain_scores_codex":[0.9981719,0.00003755902,0.000591979,0.0003709991,0.0005626036,0.0002650109],"domain_scores_gemma":[0.9983282,0.000325475,0.0005638547,0.0004372881,0.000269589,0.00007560438],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006974507,0.0001822841,0.04576902,0.0003007015,0.00009378576,0.000005476539,0.0004880298,0.006193709,0.9428297,0.001091369,0.0006776779,0.001670829],"study_design_scores_gemma":[0.001204828,0.00006163785,0.02612823,0.000114625,0.00008036585,0.00003453861,0.0001457976,0.0009425928,0.9695849,0.0001346675,0.001294362,0.0002733881],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8676597,0.00005413034,0.129125,0.0001776074,0.0001055941,0.0001504491,0.00001674263,0.00009839854,0.002612286],"genre_scores_gemma":[0.9952596,0.000005310619,0.004099782,0.00009812271,0.0001893911,0.000009498071,0.0001404579,0.00003353398,0.0001642425],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1275999,"threshold_uncertainty_score":0.8983578,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1993896612","doi":"10.1016/j.tetlet.2009.04.137","title":"Facile and efficient access to 2,6,9-tri-substituted purines through sequential N9, N2 Mitsunobu reactions","year":2009,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Biochemical and Molecular Research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":29,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Regioselectivity; Combinatorial chemistry; Purine metabolism; Chemoselectivity; Mitsunobu reaction; Nucleophile; Electrophile; Allylic rearrangement; Organic chemistry; Catalysis; Enzyme","retraction":null,"screen_n_in":null,"score":{"opus":0.02571123766116009,"gpt":0.3149343357261614,"spread":0.2892230980650013,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008896521,0.0001975182,0.0001460939,0.0000666248,0.0001276275,0.0001005091,0.0002968574,0.0001312376,0.00002866176],"category_scores_gemma":[0.00007160891,0.0001848544,0.00008857313,0.0002069243,0.0001131979,0.000009940813,0.0001603487,0.0001616563,0.00002600201],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002794188,"about_ca_system_score_gemma":0.00003068357,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007106763,"about_ca_topic_score_gemma":0.000009000722,"domain_scores_codex":[0.9986091,0.00003979304,0.0001947208,0.0005163583,0.0002272767,0.0004128012],"domain_scores_gemma":[0.9993786,0.000008224164,0.00003708056,0.0003436526,0.00005192897,0.0001805484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007365557,0.00007664473,0.0001020789,0.00001501488,0.00002824637,0.00001996461,0.00002465498,0.0002199106,0.986944,0.0000578394,0.01033106,0.002106986],"study_design_scores_gemma":[0.0005241459,0.0001438359,0.002094195,0.00002188867,0.00001712922,0.00004574584,0.00001255951,0.00003100786,0.9062428,0.00003457518,0.09053612,0.0002960158],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9842219,0.0004144604,0.006216564,0.007644387,0.0001325958,0.0003431031,0.00002484376,0.0000402443,0.0009618452],"genre_scores_gemma":[0.9943115,0.00009839398,0.000862996,0.00411661,0.0002089972,0.00002517415,0.0001136251,0.00001676248,0.0002459803],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08070116,"threshold_uncertainty_score":0.7538143,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2952209052","doi":"10.1016/j.tetlet.2004.08.038","title":"Total synthesis of (±)-manzacidin D","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"TransCanada (Canada)","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Total synthesis; Yield (engineering); Thiourea; Hydrochloride; Glycine; Alkaloid; Organic chemistry; Combinatorial chemistry; Amino acid","retraction":null,"screen_n_in":null,"score":{"opus":0.01001311485422657,"gpt":0.237499226750472,"spread":0.2274861118962454,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000191633,0.0002175223,0.000310977,0.00004605238,0.00004060012,0.00001315146,0.0003193603,0.0001270305,0.003060321],"category_scores_gemma":[0.0004137418,0.0002261939,0.0001624504,0.0001444446,0.0001807418,0.00006109179,0.00006095636,0.0001940474,0.00006763116],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002068167,"about_ca_system_score_gemma":0.00004770291,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006806162,"about_ca_topic_score_gemma":0.000001017421,"domain_scores_codex":[0.9986341,0.00001724681,0.0003598667,0.0003383075,0.0003168246,0.0003336636],"domain_scores_gemma":[0.9988617,0.0002731553,0.0001376754,0.0006042458,0.00002017196,0.000103078],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001517138,0.00007465793,0.0003132278,0.0001382602,0.00004576258,0.00002189549,0.0001314033,0.00007587789,0.993984,0.00008628933,0.0001737046,0.004939719],"study_design_scores_gemma":[0.0004077323,0.00000595249,0.0002806514,0.0001054489,0.00004747722,0.00008985868,0.0001284507,0.0000066492,0.9981103,0.0001177831,0.0004650681,0.0002346242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9804233,0.00005404368,0.0009186823,0.001755872,0.0001086256,0.0000350126,0.0000207848,0.000150685,0.01653295],"genre_scores_gemma":[0.9900838,0.000004835259,0.009324114,0.0001501515,0.0001640284,0.00001303211,0.000003366567,0.00004613489,0.0002105128],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01632244,"threshold_uncertainty_score":0.997851,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W1982308167","doi":"10.1016/j.tetlet.2009.09.076","title":"Reductive amination agents: comparison of Na(CN)BH3 and Si-CBH","year":2009,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"SiliCycle (Canada)","funders":"Rochester Academy of Science; Niagara University","keywords":"Chemistry; Reductive amination; Sodium cyanoborohydride; Reagent; Hydride; Imine; Amine gas treating; Amination; Sodium hydride; Organic chemistry; Reducing agent; Medicinal chemistry; Combinatorial chemistry; Catalysis","retraction":null,"screen_n_in":null,"score":{"opus":0.01498246173719385,"gpt":0.2782140068986044,"spread":0.2632315451614105,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009640387,0.0001361638,0.0002278497,0.0001678289,0.00005896083,0.000018523,0.0001323243,0.00007786904,0.0002858096],"category_scores_gemma":[0.00006983444,0.000141615,0.00007125272,0.0003439928,0.00008107999,0.0001348418,0.00001734732,0.0001342277,0.00001611196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009670154,"about_ca_system_score_gemma":0.000009516511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001907386,"about_ca_topic_score_gemma":0.000001136426,"domain_scores_codex":[0.9989693,0.00001823578,0.0002974109,0.0002469001,0.0002998573,0.0001683305],"domain_scores_gemma":[0.9994456,0.00004692932,0.0001824638,0.0002095925,0.00004624529,0.00006917912],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003815199,0.0004036818,0.007809343,0.00007801631,0.0001442612,0.000008831225,0.00286127,0.0001953748,0.7446718,0.0004979866,0.008428162,0.2348631],"study_design_scores_gemma":[0.001472389,0.00009936146,0.02614726,0.00005847969,0.0001907791,0.00001373559,0.002198389,0.005449677,0.9571977,0.0001336359,0.006501917,0.0005367194],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886603,0.0001845383,0.0008062845,0.00185836,0.00004235168,0.00005271141,0.00001040914,0.00006209646,0.008322934],"genre_scores_gemma":[0.9986191,0.00001361785,0.0003038366,0.0006454795,0.00005611189,0.000003598842,0.00007011567,0.00001037876,0.0002777116],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2343264,"threshold_uncertainty_score":0.577489,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2085984802","doi":"10.1016/s0040-4039(01)02065-2","title":"A novel way to prepare n-butylparaben under microwave irradiation","year":2002,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Microwave-Assisted Synthesis and Applications","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Microwave irradiation; Microwave; Catalysis; Preservative; Sulfuric acid; Irradiation; Chemical engineering; Nuclear chemistry; Organic chemistry","retraction":null,"screen_n_in":null,"score":{"opus":0.0261912242880427,"gpt":0.2304025337656103,"spread":0.2042113094775677,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00007352614,0.0002383694,0.000207079,0.0000862374,0.0001554011,0.00008376248,0.0003169086,0.0001206754,0.003343064],"category_scores_gemma":[0.00002890145,0.0002491892,0.0001263716,0.0002098517,0.00004472226,0.00009628328,0.00004475763,0.0001552642,0.0007883963],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002337516,"about_ca_system_score_gemma":0.000007492245,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004696558,"about_ca_topic_score_gemma":0.00005228449,"domain_scores_codex":[0.9985146,0.00001175665,0.0003260171,0.0005113248,0.0002242947,0.0004120251],"domain_scores_gemma":[0.9989716,0.00008546863,0.0001056019,0.0006290244,0.00003025774,0.0001780592],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004911615,0.0001285417,0.0001309621,0.00002672205,0.00003608214,0.000001846516,0.0003355827,0.0001503169,0.9415817,0.0002950424,0.04909153,0.008216763],"study_design_scores_gemma":[0.001294287,0.00003163021,0.009407703,0.0001564614,0.0001317293,0.00008150115,0.000495907,0.001934255,0.708667,0.00009716531,0.2763402,0.00136222],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9349277,0.0001371755,0.008929888,0.01560505,0.00008404577,0.0002368843,0.0001045097,0.0002774758,0.03969726],"genre_scores_gemma":[0.9888375,0.00001102745,0.003428018,0.004447805,0.0002055957,0.000105599,0.00004340983,0.00005151629,0.002869565],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2329147,"threshold_uncertainty_score":0.999996,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2090566920","doi":"10.1016/j.tetlet.2012.11.084","title":"New azaphilones from Chaetomium globosum isolated from the built environment","year":2012,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":28,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false},"ca_institutions":"Agriculture and Agri-Food Canada; Carleton University","funders":"","keywords":"Chaetomium globosum; Chemistry; Strain (injury); Chaetomium; Fermentation; Bacterial strain; Antimicrobial; Stereochemistry; Botany; Food science; Organic chemistry; Bacteria","retraction":null,"screen_n_in":null,"score":{"opus":0.01519675462860432,"gpt":0.2200199454502285,"spread":0.2048231908216242,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001389768,0.0002613095,0.0003116592,0.00003698457,0.0001056467,0.00002969203,0.0002263814,0.0001256465,0.003351828],"category_scores_gemma":[0.00004476059,0.000158768,0.0001406228,0.0001094659,0.00009687015,0.0001401738,0.00008477883,0.0003149215,0.0008551453],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000997991,"about_ca_system_score_gemma":0.00002144534,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003764753,"about_ca_topic_score_gemma":0.00003320369,"domain_scores_codex":[0.9985604,0.00006093689,0.0002725312,0.0003596334,0.0002779788,0.0004685006],"domain_scores_gemma":[0.9989095,0.0001414576,0.0000953471,0.0006152213,0.000008605729,0.0002298656],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0001747309,0.0000789406,0.013584,0.000009048157,0.0001631144,0.00001043752,0.0004428241,0.000001128012,0.8710195,0.000008453915,0.1033698,0.01113801],"study_design_scores_gemma":[0.002307483,0.0001642006,0.3712279,0.0004020319,0.0008024125,0.00004100194,0.0001633603,0.00003406992,0.3446852,0.00009554356,0.2792384,0.0008383545],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8863697,0.003549281,0.0003015958,0.1083696,0.0007233575,0.0004201274,0.0000635085,0.00009459499,0.0001081951],"genre_scores_gemma":[0.9776659,0.0001891466,0.001672301,0.01658126,0.003350494,0.000001314045,0.0001145764,0.00003559868,0.0003894019],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5263343,"threshold_uncertainty_score":0.9999228,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null},{"id":"W2014995239","doi":"10.1016/s0040-4039(01)00606-2","title":"Synthesis of N-protected N-methyl serine and threonine","year":2001,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":28,"is_retracted":false,"has_abstract":false,"routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false},"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Threonine; Serine; Stereochemistry; Biochemistry; Phosphorylation","retraction":null,"screen_n_in":null,"score":{"opus":0.005430598841690943,"gpt":0.21281264308628,"spread":0.207382044244589,"validation_status":"score_only:v0-immature-baseline"},"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009509977,0.0001177185,0.0001839516,0.00003945317,0.00002885142,0.000008244643,0.000105328,0.00006853617,0.00009935718],"category_scores_gemma":[0.0001169382,0.0001030974,0.00008862797,0.0001188982,0.00009290058,0.000002503109,0.00005260521,0.00005086771,0.000003228454],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000006806216,"about_ca_system_score_gemma":0.000005541481,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005812146,"about_ca_topic_score_gemma":0.00001236393,"domain_scores_codex":[0.9993085,0.0000262665,0.0001694385,0.0002399148,0.00009424545,0.0001616942],"domain_scores_gemma":[0.9996037,0.00002713565,0.00006225728,0.0002273224,0.0000212109,0.00005837017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003528061,0.00002770845,0.006161288,0.00001600097,0.00006720664,0.000003404243,0.000004907846,0.000008463946,0.9807576,0.000006072187,0.0003088273,0.01260322],"study_design_scores_gemma":[0.0001717927,0.00004083656,0.008890376,0.00001622839,0.00004517605,0.00001363668,0.00001435513,0.00004111249,0.9833999,0.00001162345,0.007211314,0.0001437011],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972321,0.0003013969,0.0005197279,0.001429009,0.00001435737,0.00005664457,0.000006839431,0.00001166008,0.000428298],"genre_scores_gemma":[0.9982747,0.0002699452,0.0009086656,0.0003247541,0.00008334694,0.00001110836,0.00001144572,0.00001433743,0.0001016552],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01245952,"threshold_uncertainty_score":0.4204188,"prediction_status":"machine_predicted_unvalidated"},"labels":[],"label_agreement":null}]}