{"id":"W105587982","doi":"10.1021/om0341348","title":"Aminoalkyl-Substituted Indenylnickel(II) Complexes (<i>η</i><sup>3</sup>:<i>η</i><sup>0</sup>-Ind(CH<sub>2</sub>)<sub>2</sub>NMe<sub>2</sub>)Ni(PR<sub>3</sub>)X and [(<i>η</i><sup>3</sup>:<i>η</i><sup>1</sup>-Ind(CH<sub>2</sub>)<sub>2</sub>NMe<sub>2</sub>)Ni(PR<sub>3</sub>)][BPh<sub>4</sub>]:  Influence of the Phosphine in Ligand Exchange and Polymerization Reactions","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cationic polymerization; Ligand (biochemistry); Moiety; Nickel; Styrene; Phosphine; Medicinal chemistry; Hydrosilylation; Catalysis; Stereochemistry; Crystallography; Olefin fiber; Polymer chemistry; Copolymer; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.00876747,0.0157991,0.01593164,0.00849273,0.008974539,0.004808336,0.0107763,0.0096617,0.0007856115],"category_scores_gemma":[0.00681626,0.01697209,0.006678286,0.02354983,0.01003673,0.01010703,0.007865706,0.01354623,0.001879383],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.006026163,"about_ca_system_score_gemma":0.0054346,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000690061,"about_ca_topic_score_gemma":0.002494349,"domain_scores_codex":[0.9349083,0.004531654,0.01714921,0.01671118,0.01207561,0.01462409],"domain_scores_gemma":[0.9551632,0.005565927,0.01096082,0.01559951,0.004827599,0.007882891],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002396379,0.008003866,0.006110429,0.004005305,0.006364875,0.001066707,0.008845209,0.01252312,0.9060374,0.001242616,0.003392591,0.0400115],"study_design_scores_gemma":[0.01741443,0.00164513,0.007268461,0.003954399,0.007907414,0.002921773,0.005510171,0.01003279,0.9189909,0.001806754,0.006530324,0.0160175],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9573052,0.01445021,0.001230203,0.001811161,0.002243949,0.01015931,0.007724729,0.003711116,0.00136415],"genre_scores_gemma":[0.9377413,0.03961428,0.0004768456,0.00286399,0.003844526,0.003543041,0.007117629,0.004592683,0.0002057181],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02516408,"threshold_uncertainty_score":0.9988978,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0100340239919733,"score_gpt":0.2028138885159197,"score_spread":0.1927798645239465,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}