{"id":"W1135081455","doi":"10.20381/ruor-4698","title":"Part 1: Transition Metal Catalyzed Functionalization of Aromatic C-H Bonds / Part 2: New Methods in Enantioselective Synthesis","year":2011,"lang":"en","type":"dissertation","venue":"Library and Archives Canada (Government of Canada)","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Enantioselective synthesis; Surface modification; Catalysis; Transition metal; Combinatorial chemistry; Chemistry; Organic chemistry; Physical chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003179529,0.0008471616,0.0003721639,0.0006092817,0.0002694101,0.0005747632,0.0005723548,0.0004616114,0.01068551],"category_scores_gemma":[0.0001618219,0.0003687584,0.0004239254,0.0003825577,0.0003616868,0.0006277526,0.0004973372,0.001093877,0.005737845],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004477162,"about_ca_system_score_gemma":0.0003446719,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002868667,"about_ca_topic_score_gemma":0.0003597517,"domain_scores_codex":[0.9998184,0.00001946971,0.00001184598,0.00004322074,0.00007907939,0.00002810028],"domain_scores_gemma":[0.9999505,0.00001107689,0.0000120105,0.00001237737,0.000008065808,0.000005905373],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001517569,0.0003705608,0.0002625504,0.00225728,0.0000445305,0.0004091003,0.0001412675,0.002358513,0.6437056,0.0271446,0.02358414,0.2995701],"study_design_scores_gemma":[0.00004305943,0.0005218399,0.0008361148,0.0001311379,0.00002857595,0.001182386,0.00003057191,0.002282012,0.716813,0.002278705,0.275809,0.00004361336],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.1403538,0.2435139,0.3126124,0.002947102,0.00515961,0.001263181,0.002748897,0.003933823,0.2874673],"genre_scores_gemma":[0.4137874,0.2145926,0.1231031,0.001611783,0.002074358,0.001288989,0.002392348,0.0006956437,0.2404538],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01068551,"threshold_uncertainty_score":0.03574657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006531841165241884,"score_gpt":0.186447753071818,"score_spread":0.1799159119065761,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}