{"id":"W118062614","doi":"10.1007/128_2012_392","title":"Frustrated Lewis Pair Mediated Hydrogenations","year":2012,"lang":"en","type":"article","venue":"Topics in current chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":134,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Frustrated Lewis pair; Chemistry; Lewis acids and bases; Stoichiometry; Catalysis; Substrate (aquarium); Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000282757,0.0004173596,0.0007169382,0.0002434537,0.0007875714,0.0009786894,0.001022549,0.0007049862,0.01418503],"category_scores_gemma":[0.0005053462,0.0002554888,0.0001860038,0.0002836023,0.0008208503,0.001657909,0.00157073,0.00122293,0.001033194],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004633125,"about_ca_system_score_gemma":0.000197847,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001875344,"about_ca_topic_score_gemma":0.0004800148,"domain_scores_codex":[0.9998012,0.00003175203,0.000005485665,0.00002214681,0.0000525387,0.00008685478],"domain_scores_gemma":[0.9998585,0.00005320132,0.00001655949,0.00003193168,0.00001190165,0.00002788742],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00129398,0.0003398945,0.0007242326,0.0008693045,0.0001473543,0.001316436,0.0008644027,0.02042512,0.1242795,0.7967947,0.02051973,0.03242536],"study_design_scores_gemma":[0.001192996,0.001495359,0.001846486,0.0001010291,0.0001024138,0.001503895,0.001097853,0.2938965,0.2233571,0.427436,0.04763062,0.0003396648],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8864437,0.000933925,0.02307894,0.001445351,0.0006404627,0.00008981328,0.0001519111,0.0004412486,0.0867746],"genre_scores_gemma":[0.9851966,0.000339853,0.001647032,0.0002155058,0.00006682931,0.00006210843,0.00008522921,0.00005852826,0.01232825],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01418503,"threshold_uncertainty_score":0.0474537,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02663879543940726,"score_gpt":0.2785766132547344,"score_spread":0.2519378178153271,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}