{"id":"W1182305893","doi":"10.1021/acs.jpca.5b04900","title":"Ultrafast Dynamics of <i>o</i>-Nitrophenol: An Experimental and Theoretical Study","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; National Research Council Canada","funders":"Deutsche Forschungsgemeinschaft; Natural Sciences and Engineering Research Council of Canada; Verband der Chemischen Industrie; Alexander von Humboldt-Stiftung","keywords":"Intersystem crossing; Conical intersection; Photodissociation; Excited state; Chemistry; Singlet state; Ultrafast laser spectroscopy; Photochemistry; Spectroscopy; Ground state; Relaxation (psychology); Internal conversion; Singlet fission; Atomic physics; Chemical physics; Spectral line; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002593097,0.0001909209,0.0003661596,0.000006730796,0.00006578654,0.0000157939,0.0003855093,0.00005021124,0.00005609327],"category_scores_gemma":[0.00005808613,0.0001260537,0.00009258567,0.0000698104,0.0005362694,0.00009280171,0.00006152593,0.0004200751,4.314907e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005604895,"about_ca_system_score_gemma":0.0000621973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004989582,"about_ca_topic_score_gemma":4.512731e-7,"domain_scores_codex":[0.9989179,0.00003911497,0.0003211791,0.0001258071,0.0003938772,0.0002021679],"domain_scores_gemma":[0.9991164,0.0001218168,0.0001595747,0.0002499117,0.0001467192,0.0002055337],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007328334,0.001659338,0.0001551132,0.00005751376,0.000131888,0.00001081606,0.004298361,0.00006224984,0.9925743,0.0002378637,0.00001056618,0.00006921216],"study_design_scores_gemma":[0.001237944,0.0005207809,0.0000168713,0.00002690978,0.0001543784,0.0001346104,0.01694759,0.000996692,0.9784956,0.001328833,0.000009303015,0.0001304691],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957227,0.0001308736,0.00004440715,0.00006877911,0.000006602093,0.00004049194,0.00001306642,0.0000111893,0.003961894],"genre_scores_gemma":[0.999625,0.000006491441,0.000007731174,0.000009627633,0.0002935592,0.000003473045,0.000002931984,0.00001566355,0.0000355057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01407863,"threshold_uncertainty_score":0.5140319,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0113978282495514,"score_gpt":0.2623800599888271,"score_spread":0.2509822317392757,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}