{"id":"W1249681237","doi":"10.1021/acs.analchem.5b02506","title":"Interactions of Hemoglobin and Myoglobin with Their Ligands CN<sup>–</sup>, CO, and O<sub>2</sub> Monitored by Electrospray Ionization-Mass Spectrometry","year":2015,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Myoglobin; Electrospray ionization; Mass spectrometry; Hemoglobin; Ionization; Electrospray; Analytical Chemistry (journal); Chromatography; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002076937,0.0002742619,0.0001648893,0.000103395,0.0001239818,0.0002239758,0.0002255944,0.0003509021,0.000876344],"category_scores_gemma":[0.0003467746,0.000102216,0.00007145457,0.000158201,0.0001702702,0.0002562917,0.0002538116,0.0002659832,0.0002457244],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002625946,"about_ca_system_score_gemma":0.0001562798,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004778536,"about_ca_topic_score_gemma":0.000634279,"domain_scores_codex":[0.9997337,0.00003466446,0.000008102449,0.00004525463,0.0001489056,0.00002931812],"domain_scores_gemma":[0.999856,0.00004797502,0.000041888,0.000007084784,0.00002514046,0.00002189883],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005175069,0.000008664458,0.0005251997,0.00002917922,0.000004654561,0.00002684079,0.00001293556,0.00005129662,0.9967183,0.00006691023,0.0000674039,0.00243686],"study_design_scores_gemma":[0.000006400775,0.0001145351,0.008354226,0.000005636169,0.000007197415,0.0001830042,0.00002086486,0.002081077,0.9866129,0.00007600387,0.002532756,0.000005549355],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826214,0.004028824,0.01030094,0.0001459051,0.00002696789,0.00004292856,0.0002273005,0.000111919,0.002494],"genre_scores_gemma":[0.9803893,0.001806161,0.0129573,0.0002415192,0.00002437711,0.00006873503,0.0004545455,0.00003159733,0.00402643],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000876344,"threshold_uncertainty_score":0.002931654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00783893442138246,"score_gpt":0.2382363731887714,"score_spread":0.230397438767389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}