{"id":"W1483397208","doi":"10.1002/9780470682531.pat0446","title":"Copper‐Mediated Asymmetric Allylic Alkylations","year":2011,"lang":"en","type":"other","venue":"","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Enantioselective synthesis; Allylic rearrangement; Copper; Chemistry; Combinatorial chemistry; Stereochemistry; Computer science; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003924671,0.001199085,0.0004235317,0.0005960572,0.0005367983,0.0004880783,0.0008230826,0.0003602794,0.007725604],"category_scores_gemma":[0.0002428436,0.0003026019,0.0002749903,0.0004731554,0.0004662359,0.000800553,0.0006489559,0.001123292,0.002009324],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006741446,"about_ca_system_score_gemma":0.0006198428,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001776002,"about_ca_topic_score_gemma":0.003483039,"domain_scores_codex":[0.9997141,0.00003213126,0.00001688271,0.00003177979,0.00008683429,0.0001181818],"domain_scores_gemma":[0.999921,0.000008379798,0.00001066232,0.00002079213,0.00002250907,0.00001677668],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006473802,0.0003734763,0.0004584042,0.00158573,0.0001232037,0.001350886,0.0006297748,0.003389551,0.7904425,0.03426688,0.01587905,0.1508531],"study_design_scores_gemma":[0.00006089105,0.0002413907,0.0004116114,0.000025574,0.00003248129,0.0002223787,0.00004960303,0.0012455,0.9605415,0.000862617,0.03627865,0.00002774211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.633771,0.00653379,0.05318274,0.001279134,0.0009604641,0.0004687718,0.001453247,0.001602179,0.3007487],"genre_scores_gemma":[0.9146012,0.006410631,0.008311979,0.0002102127,0.0001581911,0.0000999555,0.0006285796,0.0001322367,0.06944696],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.007725604,"threshold_uncertainty_score":0.02584469,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01645967585884303,"score_gpt":0.2189669805989304,"score_spread":0.2025073047400874,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}