{"id":"W1483397208","doi":"10.1002/9780470682531.pat0446","title":"Copper‐Mediated Asymmetric Allylic Alkylations","year":2011,"lang":"en","type":"other","venue":"","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Enantioselective synthesis; Allylic rearrangement; Copper; Chemistry; Combinatorial chemistry; Stereochemistry; Computer science; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00008173058,0.0003814377,0.0005101293,0.000973059,0.00004796862,0.00003014995,0.0004698316,0.0006949583,0.1733456],"category_scores_gemma":[0.0002592996,0.0003277743,0.0002721023,0.001127586,0.00005726224,0.00002714456,0.0000918562,0.0002265169,0.009298603],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000569104,"about_ca_system_score_gemma":0.00006723583,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001236885,"about_ca_topic_score_gemma":0.0001527278,"domain_scores_codex":[0.9984685,0.00001372878,0.0003202773,0.0005017792,0.0003522025,0.0003434843],"domain_scores_gemma":[0.99848,0.000184367,0.0002830045,0.0008412431,0.00003909207,0.0001723073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000001743289,0.0001027997,0.0004204517,0.00004970677,0.0003834021,0.000005765673,0.0000118616,3.499055e-8,0.0000415484,0.0003677084,0.9479595,0.05065553],"study_design_scores_gemma":[0.0001861501,0.000004926636,0.00006276366,0.00004765407,0.0002240116,0.000003127123,0.00004903829,0.00001366162,0.001767714,0.00001830403,0.9971798,0.0004428387],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.00000341641,0.003162295,0.0001724785,0.00002766576,0.0001075655,0.00006569851,0.0001709109,0.0006666377,0.9956234],"genre_scores_gemma":[0.005234299,0.0007604723,0.0006464153,0.00009401918,0.0004170027,0.00004536808,0.0006174902,0.0006139183,0.991571],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.164047,"threshold_uncertainty_score":0.9999174,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01645967585884303,"score_gpt":0.2189669805989304,"score_spread":0.2025073047400874,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}