{"id":"W1486309336","doi":"10.1002/047005042x.ch9","title":"Peptide Radical Cations","year":2006,"lang":"en","type":"other","venue":"","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Fragmentation (computing); Radical ion; Peptide; Chemistry; Metal; Ion; Hydroxyl radical; Radical; Combinatorial chemistry; Organic chemistry; Biochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001090764,0.0004879606,0.000236442,0.0002355096,0.0003155416,0.0003896501,0.0004358175,0.0003192018,0.02683771],"category_scores_gemma":[0.0001237128,0.0001723915,0.0002576063,0.0001715339,0.0001142925,0.0004395577,0.0003500454,0.0008924774,0.007594649],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002809777,"about_ca_system_score_gemma":0.0002087097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001660982,"about_ca_topic_score_gemma":0.0002508321,"domain_scores_codex":[0.9998999,0.000004786988,0.000003991307,0.00002757626,0.00004564477,0.00001817108],"domain_scores_gemma":[0.999961,0.000008232999,0.000007471251,0.000005237806,0.00001065865,0.000007359279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001203559,0.0001039371,0.00007211715,0.0006615264,0.00001024286,0.0001570003,0.0000836201,0.0002608984,0.9082914,0.004653632,0.01083213,0.07475311],"study_design_scores_gemma":[0.00002455937,0.000199504,0.0004172439,0.00004412039,0.0000141269,0.0003328674,0.00002503669,0.0002263858,0.7758895,0.0007863609,0.2220268,0.00001338101],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3074165,0.0837649,0.08611574,0.003185861,0.00676625,0.00131104,0.003976528,0.003896938,0.5035663],"genre_scores_gemma":[0.314076,0.03953819,0.02485504,0.00171133,0.0007947757,0.0004224266,0.004585399,0.0005980234,0.6134188],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.02683771,"threshold_uncertainty_score":0.08978105,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007958166455778458,"score_gpt":0.243874665139058,"score_spread":0.2359164986832795,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}