{"id":"W1486309336","doi":"10.1002/047005042x.ch9","title":"Peptide Radical Cations","year":2006,"lang":"en","type":"other","venue":"","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Fragmentation (computing); Radical ion; Peptide; Chemistry; Metal; Ion; Hydroxyl radical; Radical; Combinatorial chemistry; Organic chemistry; Biochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00001452932,0.0002067465,0.0002094891,0.00006649816,0.00002968275,0.00001973536,0.0002421673,0.0005356172,0.09829445],"category_scores_gemma":[0.00009504809,0.000189424,0.0001343449,0.00008415854,0.0001586039,0.00001169964,0.00003241216,0.0004190392,0.001401443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000993768,"about_ca_system_score_gemma":0.00007059499,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002580152,"about_ca_topic_score_gemma":0.0004464978,"domain_scores_codex":[0.9990263,0.00000387161,0.0001875659,0.0003128297,0.0002407918,0.0002286303],"domain_scores_gemma":[0.9991739,0.00007529277,0.00008008571,0.0004924447,0.00001021974,0.0001680697],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[6.033936e-7,0.00007738186,0.00001158574,0.0000356583,0.00002900848,0.000004307965,9.175435e-7,2.013246e-7,0.008610649,0.0009259076,0.9900446,0.000259192],"study_design_scores_gemma":[0.0001235696,0.000001069832,0.000003064486,0.00006109195,0.00003255109,0.000007042831,0.000002733382,0.00001284738,0.00484102,0.0003064721,0.9943926,0.000215975],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.00001165774,0.000144812,0.0002333581,0.0001981604,0.00006212854,0.00006575773,0.00009425379,0.0007692129,0.9984207],"genre_scores_gemma":[0.0002622615,0.00002008683,0.001473652,0.0001043188,0.0008621994,0.00007050434,0.0004374487,0.0004062994,0.9963632],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.09689301,"threshold_uncertainty_score":0.9993761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007958166455778458,"score_gpt":0.243874665139058,"score_spread":0.2359164986832795,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}