{"id":"W1487310067","doi":"10.1002/9780470098004.ch5","title":"Asymmetric Synthesis Based on Catalytic Activation of CH Bonds and CC Bonds","year":2006,"lang":"en","type":"other","venue":"","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Canada Research Chairs","keywords":"Catalysis; Bond; Chemistry; Stereochemistry; Organic chemistry; Business","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001798866,0.0006993522,0.0004218849,0.0005419548,0.0004094265,0.0005365389,0.000465825,0.0003837523,0.01423537],"category_scores_gemma":[0.0001320142,0.0002315504,0.0005115779,0.0005122711,0.0003875856,0.001059277,0.0005726959,0.00117784,0.003071595],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006357917,"about_ca_system_score_gemma":0.000425318,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005729844,"about_ca_topic_score_gemma":0.0009199866,"domain_scores_codex":[0.9998234,0.000013993,0.000009126925,0.00002747029,0.00008084346,0.00004516831],"domain_scores_gemma":[0.9999548,0.00001033118,0.000005516755,0.00001173936,0.00001030548,0.000007335466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002683745,0.0002214268,0.0001832116,0.00189,0.00004110325,0.0004663144,0.0002173566,0.003587466,0.6242516,0.1596837,0.01715267,0.1920368],"study_design_scores_gemma":[0.00003577773,0.000125119,0.0003627126,0.0000499616,0.00002178493,0.0003588029,0.00004305111,0.002605712,0.8243093,0.008967636,0.163085,0.00003521724],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"methods","genre_scores_codex":[0.1535131,0.02730945,0.07408085,0.001601949,0.003126938,0.0003854366,0.001396166,0.0009553213,0.7376308],"genre_scores_gemma":[0.7181743,0.04241451,0.03997948,0.0009458493,0.001005745,0.0003426286,0.00165116,0.000501512,0.1949848],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.01423537,"threshold_uncertainty_score":0.04762208,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007961907451320228,"score_gpt":0.2207975884055719,"score_spread":0.2128356809542516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}