{"id":"W1490325333","doi":"10.1016/s0022-328x(03)00435-2","title":"Synthesis and characterization of methylbismuth(III) complexes containing dithio ligands: crystal and molecular structure of [MeBi{S2COMe}2] and transformation of [MeBi{S2COiPr}2] to Bi2S3","year":2003,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Square pyramidal molecular geometry; Anhydrous; Thermal decomposition; Crystallography; Benzene; Crystal structure; Pentagonal bipyramidal molecular geometry; Intermolecular force; Molecule; Bismuth; Potassium; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001206564,0.0001621373,0.0001356966,0.0001741171,0.0002058525,0.0002692827,0.0003020456,0.0002146005,0.001180533],"category_scores_gemma":[0.0002820666,0.0001846025,0.00006519333,0.000221454,0.0001194333,0.0001424767,0.0001192657,0.0001782572,0.0003184607],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003498223,"about_ca_system_score_gemma":0.0001951749,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002421309,"about_ca_topic_score_gemma":0.003734778,"domain_scores_codex":[0.9999145,0.00001173696,0.000009781267,0.0000134268,0.00003496132,0.00001559231],"domain_scores_gemma":[0.9998932,0.00001536398,0.00002093582,0.00001834879,0.00003068952,0.00002143212],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000066098,0.000009129039,0.0001134959,0.00001538085,0.000002005645,0.0000114538,0.0000127781,0.00004864005,0.9989787,0.0000655865,0.0000340171,0.0006426975],"study_design_scores_gemma":[0.000009187554,0.00003145857,0.00093986,9.043325e-7,0.00000429687,0.00005109148,0.000008031898,0.0003130954,0.9975373,0.00001259609,0.001090093,0.000002168549],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948357,0.0004714479,0.002315537,0.00005970843,0.000005710079,0.00002548252,0.0003985472,0.00008616903,0.001801616],"genre_scores_gemma":[0.9933408,0.0002061908,0.002877136,0.00001550675,0.000003181188,0.00002232502,0.0007309006,0.00004263358,0.002761306],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002421309,"threshold_uncertainty_score":0.004814446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006777349096267492,"score_gpt":0.203558434489287,"score_spread":0.1967810853930195,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}