{"id":"W1497957100","doi":"","title":"Development of the Interrupted Nazarov Cyclization of Allenyl Vinyl Ketones, with Application to the Total Synthesis of the Cyclooctane Natural Product Roseadione","year":2011,"lang":"en","type":"article","venue":"Library and Archives Canada (Government of Canada)","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Cyclooctane; Natural product; Product (mathematics); Chemistry; Total synthesis; Organic chemistry; Catalysis; Mathematics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002063107,0.0005444667,0.000200336,0.0002941088,0.0001700049,0.0003426524,0.0003029364,0.0001947322,0.001314857],"category_scores_gemma":[0.0001655302,0.0001821072,0.0002680059,0.0001925974,0.0002644125,0.0005500207,0.0004870593,0.000680329,0.0005945955],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002760531,"about_ca_system_score_gemma":0.0004051532,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006042977,"about_ca_topic_score_gemma":0.001368704,"domain_scores_codex":[0.9998707,0.00001653634,0.00001335934,0.00003636109,0.00003183865,0.00003128913],"domain_scores_gemma":[0.9999166,0.000007257129,0.00002112665,0.00001591106,0.00001562097,0.00002361738],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001226882,0.00004856214,0.000446826,0.0002943692,0.00004318111,0.0004037142,0.0001635876,0.0008427511,0.9588997,0.002469201,0.00012704,0.03613846],"study_design_scores_gemma":[0.0000249491,0.001119518,0.00131191,0.00002763895,0.00005102758,0.0007284656,0.00007282159,0.001187695,0.9685367,0.0003936765,0.0265188,0.00002675627],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.871061,0.01229428,0.08499508,0.00026611,0.0002489934,0.0003725334,0.0005619577,0.0004089396,0.02979102],"genre_scores_gemma":[0.9588117,0.006585813,0.02577193,0.00005446891,0.00002919122,0.00009553157,0.0004976201,0.00004818178,0.008105592],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001314857,"threshold_uncertainty_score":0.004398584,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003519141280386202,"score_gpt":0.1395082102492598,"score_spread":0.1359890689688736,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}