{"id":"W1500403405","doi":"10.1002/rcm.4967","title":"Characterization of a condensed‐phase membrane introduction mass spectrometry (CP‐MIMS) interface using a methanol acceptor phase coupled with electrospray ionization for the continuous on‐line quantitation of polar, low‐volatility analytes at trace levels in complex aqueous samples","year":2011,"lang":"en","type":"article","venue":"Rapid Communications in Mass Spectrometry","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vancouver Island University","funders":"Natural Sciences and Engineering Research Council of Canada; Vancouver Island University","keywords":"Chemistry; Electrospray ionization; Analyte; Analytical Chemistry (journal); Electrospray; Mass spectrometry; Aqueous solution; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008198645,0.0003498589,0.0006842531,0.0009662217,0.0001910242,0.00003373211,0.0007510687,0.0001601066,0.0003784882],"category_scores_gemma":[0.0001741945,0.0003274863,0.0001220221,0.002607455,0.0002744895,0.000254807,0.0000561072,0.0003967579,0.000001968148],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005681332,"about_ca_system_score_gemma":0.00008538462,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009273591,"about_ca_topic_score_gemma":0.0001315024,"domain_scores_codex":[0.997496,0.0002764106,0.001120258,0.0004143961,0.0002911738,0.0004017543],"domain_scores_gemma":[0.997053,0.0005442478,0.0005633329,0.001471687,0.0003110061,0.00005677521],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006511125,0.0008473013,0.000761505,0.0001292017,0.000211571,3.3447e-7,0.0006278127,0.0006246974,0.9940212,0.001734306,0.00002774805,0.0003631444],"study_design_scores_gemma":[0.002616429,0.0007276586,0.00439949,0.00004975203,0.0001287707,0.000008776815,0.0003977844,0.1739011,0.8171489,0.0002435762,0.0001005096,0.0002772468],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6230273,0.00320087,0.3722686,0.0001462828,0.00003116284,0.001039547,0.00020376,0.00005752219,0.00002495393],"genre_scores_gemma":[0.9678868,0.0067387,0.02443364,0.00001310944,0.00004497694,0.0001645643,0.0006342237,0.00007054961,0.0000134436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.347835,"threshold_uncertainty_score":0.9999177,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05822743322046332,"score_gpt":0.3064153800629464,"score_spread":0.2481879468424831,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}