{"id":"W1501991014","doi":"10.1002/3527607994.ch6","title":"Chiral Carbon‐rich Macrocycles and Cyclophanes","year":2006,"lang":"en","type":"other","venue":"","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Cyclophane; Chirality (physics); Asymmetric carbon; Carbon fibers; Chemistry; Stereochemistry; Crystallography; Materials science; Organic chemistry; Crystal structure; Physics; Optically active; Chiral symmetry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007403916,0.0003559513,0.0002460585,0.0003772184,0.0002107325,0.0002720073,0.0002082372,0.0001294489,0.01164129],"category_scores_gemma":[0.00006532919,0.0002017853,0.0001136897,0.0002656197,0.0001731011,0.0003197476,0.0003141222,0.0004333063,0.001803164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002601257,"about_ca_system_score_gemma":0.0001675252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003642515,"about_ca_topic_score_gemma":0.001006115,"domain_scores_codex":[0.9999405,0.000005895207,0.000002686644,0.00001154085,0.00002672073,0.00001255763],"domain_scores_gemma":[0.9999839,0.000003743598,0.000002908,0.000002785356,0.000002301609,0.00000446989],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000215268,0.00007044456,0.0001745956,0.0004673605,0.000009676401,0.0002398357,0.0001005086,0.001079109,0.9217245,0.02344718,0.001812109,0.05065944],"study_design_scores_gemma":[0.00002593123,0.0001893259,0.0006609592,0.00005586114,0.00000834182,0.0002234899,0.00003545218,0.0004298168,0.9013903,0.001537304,0.09542952,0.00001358854],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.5707126,0.04477744,0.04395945,0.0009059972,0.0004401841,0.0004703383,0.002175566,0.001121899,0.3354365],"genre_scores_gemma":[0.7767964,0.04956007,0.03154495,0.0003621996,0.0001444968,0.0002964331,0.001626363,0.0002237921,0.1394454],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.01164129,"threshold_uncertainty_score":0.03894401,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002201812199801884,"score_gpt":0.1614784331650931,"score_spread":0.1592766209652912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}