{"id":"W1501991014","doi":"10.1002/3527607994.ch6","title":"Chiral Carbon‐rich Macrocycles and Cyclophanes","year":2006,"lang":"en","type":"other","venue":"","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Cyclophane; Chirality (physics); Asymmetric carbon; Carbon fibers; Chemistry; Stereochemistry; Crystallography; Materials science; Organic chemistry; Crystal structure; Physics; Optically active; Chiral symmetry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000111285,0.0001877131,0.000182526,0.00004435465,0.000008356295,0.00001649257,0.00006656345,0.0001912499,0.0004724542],"category_scores_gemma":[0.000001188052,0.0001765245,0.00003033142,0.00005922227,0.00002240991,0.000008189004,0.00001648655,0.00007973686,0.00001528144],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009540767,"about_ca_system_score_gemma":0.000002358232,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001450738,"about_ca_topic_score_gemma":0.00012721,"domain_scores_codex":[0.9995787,0.000001963119,0.00007603622,0.0001420986,0.00006511026,0.0001360749],"domain_scores_gemma":[0.9997909,0.000006766882,0.00001355638,0.000152267,0.000002487034,0.00003400905],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000001650623,0.0000153258,0.00110403,0.0007259861,0.0003133346,0.00003225202,0.00003377271,0.0004102341,0.008251334,0.00001507881,0.985813,0.003283964],"study_design_scores_gemma":[0.0003399694,0.000004420073,0.0002469753,0.0001085326,0.0001651968,0.00002563515,0.00006093989,0.0005805048,0.1030586,0.00009208118,0.8942179,0.001099189],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.01672044,0.005199918,0.000009994031,0.000004026885,0.00009175982,0.00003489525,0.00001808801,0.000666162,0.9772547],"genre_scores_gemma":[0.02939859,0.0003193867,0.0001807323,0.000005865354,0.0002398747,0.000007136867,0.00007418286,0.0002706602,0.9695036],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.0948073,"threshold_uncertainty_score":0.7198462,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002201812199801884,"score_gpt":0.1614784331650931,"score_spread":0.1592766209652912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}