{"id":"W1508367234","doi":"10.1016/s0167-2991(06)80468-4","title":"Kinetics of Propylene Bulk Polymerization with a Spherical Ziegler-Natta Catalyst","year":2006,"lang":"en","type":"book-chapter","venue":"Studies in surface science and catalysis","topic":"Polymer crystallization and properties","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"","keywords":"Polymerization; Natta; Materials science; Polymer; Kinetics; Monomer; Thermodynamics; Polymer chemistry; Bulk polymerization; Phase (matter); Ziegler–Natta catalyst; Chemistry; Radical polymerization; Composite material; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0003931094,0.0003374665,0.0006701911,0.0001605842,0.0001908132,0.0000713716,0.0004147722,0.0001032394,0.0001218492],"category_scores_gemma":[0.00008156101,0.0002438387,0.0000464038,0.0005793164,0.004467928,0.0002775278,0.0003330217,0.00011147,0.00001086511],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001240561,"about_ca_system_score_gemma":0.000174073,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003090886,"about_ca_topic_score_gemma":0.0002647338,"domain_scores_codex":[0.9973978,0.00002188947,0.0005302885,0.0006827679,0.001020103,0.00034718],"domain_scores_gemma":[0.9985619,0.00004749064,0.0003658217,0.0004396254,0.0005070925,0.00007812214],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001012013,0.0001144234,0.0004685797,0.0005015688,0.0001090923,0.00002317755,0.003252089,0.002345057,0.9895474,0.001108474,0.0003623614,0.00206658],"study_design_scores_gemma":[0.0006443809,0.0004297607,0.000164071,0.0007581456,0.0004016568,0.00002719092,0.001693345,0.0002752222,0.9831792,0.0004452912,0.01079714,0.001184584],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4848429,0.10053,0.002092192,0.001253657,0.001167938,0.002118034,0.0005397581,0.0003103733,0.4071452],"genre_scores_gemma":[0.9322947,0.001690257,0.0008743951,0.00006064893,0.00004286014,0.00001176816,0.00004653284,0.00004062696,0.06493816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4474519,"threshold_uncertainty_score":0.9982414,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0278242452301568,"score_gpt":0.2614849742069632,"score_spread":0.2336607289768064,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}