{"id":"W1511952882","doi":"10.1002/9783527658947.ch3","title":"Protecting‐Group‐Free Glycoconjugate Synthesis: Hydrazide and Oxyamine Derivatives in <i>N</i> ‐Glycoside Formation","year":2013,"lang":"en","type":"other","venue":"","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Glycoconjugate; Hydrazide; Protecting group; Glycoside; Chemistry; Group (periodic table); Stereochemistry; Biochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001999435,0.0006199642,0.0007036292,0.0002035831,0.00007805839,0.0001300314,0.0004273686,0.0007018625,0.009066666],"category_scores_gemma":[0.0006497511,0.0005714095,0.0001143395,0.000168614,0.00014412,0.0002327369,0.0002290536,0.0005291594,0.00009106003],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001063954,"about_ca_system_score_gemma":0.00002649854,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001001156,"about_ca_topic_score_gemma":0.0005953535,"domain_scores_codex":[0.9979706,0.00005489643,0.0005745422,0.000656819,0.000263518,0.0004796601],"domain_scores_gemma":[0.998215,0.0003663738,0.0004126957,0.0008378765,0.00002519067,0.0001428328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000711817,0.000165502,0.0001743387,0.003900375,0.0001838791,0.00004858782,0.0004269581,0.000001555915,0.9207626,0.0001623255,0.06387287,0.01022981],"study_design_scores_gemma":[0.0007396419,0.00001207719,0.00001529655,0.00222696,0.00007462546,0.00004908566,0.0009530175,0.0004188703,0.9067892,0.0003025341,0.08742376,0.0009949647],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.02724151,0.0007647809,0.0001514616,0.0001936207,0.00004240814,0.0004865997,0.00008840353,0.0005012547,0.97053],"genre_scores_gemma":[0.2019302,0.0009687344,0.002669983,0.000163138,0.0006708646,0.002141772,0.0001381855,0.0009954963,0.7903216],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.1802083,"threshold_uncertainty_score":0.9996737,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009378541446405713,"score_gpt":0.197969600833315,"score_spread":0.1885910593869093,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}