{"id":"W1511996106","doi":"10.1002/3527606858.ch7","title":"Asymmetric Cross‐coupling and Mizoroki–Heck Reactions","year":2005,"lang":"en","type":"other","venue":"","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Palladium; Intramolecular force; Catalysis; Chemistry; Heck reaction; Coupling reaction; Quaternary carbon; Organic chemistry; Combinatorial chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001067972,0.000439314,0.0004177004,0.0004854404,0.0001869374,0.000289707,0.0002325757,0.0007432797,0.03287494],"category_scores_gemma":[0.0001904247,0.0004562412,0.0001714075,0.0003611065,0.000213938,0.00008600835,0.0001280968,0.0006430032,0.000914956],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001973382,"about_ca_system_score_gemma":0.00009655407,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002042886,"about_ca_topic_score_gemma":0.0005299586,"domain_scores_codex":[0.9981514,2.372687e-7,0.0004116167,0.0007155036,0.0003023784,0.0004189304],"domain_scores_gemma":[0.9984208,0.0001796762,0.0002875101,0.0008615612,0.00005426483,0.0001962046],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00003556743,0.0006123354,0.003193915,0.001407073,0.0009308791,0.00005510467,0.00006377148,0.0002583002,0.04192142,0.00165377,0.929133,0.02073489],"study_design_scores_gemma":[0.0004942024,0.000003948591,0.0001313919,0.0001788567,0.0001182855,0.0001059939,0.00004003862,0.0007463339,0.006041565,0.00001618621,0.9915969,0.0005262615],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.003901813,0.002378941,0.00007313116,0.00007081065,0.0003110029,0.0001135345,0.0001646476,0.001198212,0.9917879],"genre_scores_gemma":[0.01409419,0.0008373465,0.0003926748,0.00002813755,0.001395077,0.0000328377,0.000179017,0.0007215845,0.9823191],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.06246396,"threshold_uncertainty_score":0.999863,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01242407728243264,"score_gpt":0.2903573695909958,"score_spread":0.2779332923085631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}