{"id":"W1526076995","doi":"10.1002/psc.2711","title":"Solid‐phase synthesis of C‐terminal azapeptides","year":2014,"lang":"en","type":"article","venue":"Journal of Peptide Science","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Canadian Institutes of Health Research","keywords":"Regioselectivity; Solid-phase synthesis; Residue (chemistry); Peptide; Alkylation; Peptide synthesis; Combinatorial chemistry; Chemistry; Stereochemistry; Terminal (telecommunication); Biochemistry; Catalysis; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001166451,0.00009328626,0.0002492731,0.0001138036,0.00006888145,0.00002886652,0.0005149037,0.00004517237,0.00004581355],"category_scores_gemma":[0.00164001,0.00006960238,0.0002247638,0.0002276178,0.0004343752,0.00001479285,0.0000839092,0.00006893669,0.000003381281],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001411685,"about_ca_system_score_gemma":0.0001195153,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004994095,"about_ca_topic_score_gemma":0.000002567517,"domain_scores_codex":[0.9987972,0.00003599826,0.000421527,0.0001698263,0.0003816779,0.0001937959],"domain_scores_gemma":[0.9988272,0.00005979211,0.0004309434,0.0002276511,0.0003028546,0.0001516016],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003405644,0.00008896201,0.0007029433,0.000008964888,0.00001884144,0.000001772166,0.0000122764,0.00003392788,0.9820371,0.0000272221,0.0003332089,0.01670067],"study_design_scores_gemma":[0.000197278,0.0002666394,0.0009035028,0.00005362581,0.00004737677,0.00005002143,0.00004741138,0.0002509198,0.9944101,0.0001106628,0.003574016,0.00008847056],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966509,0.00008421366,0.001873112,0.0001238798,0.00005123816,0.00001680247,0.000002908292,0.000001326059,0.001195561],"genre_scores_gemma":[0.9968457,0.00006567929,0.002665197,0.00006406102,0.000247686,6.891445e-7,3.653891e-7,0.000005690804,0.0001048911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0166122,"threshold_uncertainty_score":0.2838303,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008231136319074949,"score_gpt":0.3148502532779613,"score_spread":0.3066191169588864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}