{"id":"W1526076995","doi":"10.1002/psc.2711","title":"Solid‐phase synthesis of C‐terminal azapeptides","year":2014,"lang":"en","type":"article","venue":"Journal of Peptide Science","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Canadian Institutes of Health Research","keywords":"Regioselectivity; Solid-phase synthesis; Residue (chemistry); Peptide; Alkylation; Peptide synthesis; Combinatorial chemistry; Chemistry; Stereochemistry; Terminal (telecommunication); Biochemistry; Catalysis; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001616423,0.0003718249,0.0004377131,0.0001867509,0.0002098123,0.0002752812,0.0003302412,0.0002997046,0.003008775],"category_scores_gemma":[0.0001714544,0.0001915661,0.000196827,0.0002465434,0.0001742824,0.0002187773,0.0002410935,0.0008587709,0.001879289],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002917564,"about_ca_system_score_gemma":0.000321887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002456654,"about_ca_topic_score_gemma":0.0004426659,"domain_scores_codex":[0.99988,0.00001393039,0.00001082842,0.00001972916,0.00005078784,0.00002474786],"domain_scores_gemma":[0.9999026,0.00002214849,0.00001714378,0.00001120213,0.00002306708,0.00002370568],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009022892,0.00002096958,0.00001765515,0.00008806754,0.00000506019,0.00007142885,0.00001551765,0.0004164102,0.9958066,0.0006804732,0.0001606584,0.002626895],"study_design_scores_gemma":[0.00003264428,0.0001504058,0.0001348935,0.000004939811,0.000005921298,0.0001082192,0.00000687378,0.0008490722,0.9924981,0.0001524214,0.006049628,0.000006875917],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8944178,0.005527107,0.07256131,0.0003736587,0.0004056373,0.000676246,0.004441998,0.0005787014,0.02101775],"genre_scores_gemma":[0.9320975,0.005325786,0.04595189,0.0001232922,0.00007182344,0.0003232815,0.003430751,0.0001347922,0.0125409],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003008775,"threshold_uncertainty_score":0.01006538,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008231136319074949,"score_gpt":0.3148502532779613,"score_spread":0.3066191169588864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}