{"id":"W1528352005","doi":"10.1063/1.3258646","title":"Isotope effects in liquid water by infrared spectroscopy. III. H2O and D2O spectra from 6000tocm−1","year":2009,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":307,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"","keywords":"Infrared spectroscopy; Absorbance; Analytical Chemistry (journal); Spectral line; Infrared; Liquid water; Heavy water; Spectroscopy; Water vapor; Isotope; Chemistry; Absorption spectroscopy; Refractive index; Absorption (acoustics); Materials science; Optics; Atomic physics; Physics; Deuterium; Chromatography; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003403575,0.0005003997,0.0002552694,0.0004203129,0.0002300998,0.0004599763,0.0005577533,0.0004457737,0.002318302],"category_scores_gemma":[0.0006017605,0.0002751618,0.0001664235,0.0005006104,0.0005031751,0.000652721,0.0004579487,0.0005716616,0.0005492886],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003442378,"about_ca_system_score_gemma":0.0001652251,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002004527,"about_ca_topic_score_gemma":0.002156894,"domain_scores_codex":[0.9996189,0.00007017156,0.00002603874,0.00009467269,0.0001227148,0.00006739985],"domain_scores_gemma":[0.9997528,0.00008473033,0.00004501376,0.00003093777,0.0000672381,0.00001923833],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001658072,0.000009887974,0.000364766,0.0001138666,0.000004861286,0.00004823917,0.00002776543,0.00009058156,0.9928973,0.0001771479,0.0001533988,0.005946411],"study_design_scores_gemma":[0.00001442614,0.00007769888,0.001716242,0.00001584187,0.0000130947,0.00009974156,0.00005088221,0.001311772,0.9921014,0.00022247,0.004364723,0.00001176653],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8698421,0.02088449,0.08548892,0.0005831795,0.0004145462,0.0002328284,0.001804859,0.001493488,0.01925548],"genre_scores_gemma":[0.9643785,0.005541832,0.02323027,0.000267129,0.00003865554,0.0001419245,0.0008851622,0.0002180738,0.005298535],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002318302,"threshold_uncertainty_score":0.007755458,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00439340617336185,"score_gpt":0.2266519628345107,"score_spread":0.2222585566611489,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}