{"id":"W1531702795","doi":"10.1063/1.3194798","title":"Formation mechanisms of oxygen atoms in the O(D21) state from the 157nm photoirradiation of amorphous water ice at 90K","year":2009,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; Queen's University","keywords":"Photodissociation; Dissociation (chemistry); Chemistry; Photochemistry; Desorption; Radical; Excited state; Ionization; Oxygen; Vacuum ultraviolet; Hydrogen peroxide; Resonance-enhanced multiphoton ionization; Ultraviolet; Amorphous ice; Amorphous solid; Atomic physics; Physical chemistry; Photoionization; Materials science; Ion; Crystallography","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001104754,0.0002399526,0.0001889136,0.0002472685,0.0002502051,0.0001998227,0.0002838452,0.0002652323,0.002936496],"category_scores_gemma":[0.0001855933,0.0001715967,0.0002082023,0.0001596074,0.0003665364,0.0002723067,0.0002791338,0.0003999807,0.0002262145],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003215156,"about_ca_system_score_gemma":0.00009500064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007593011,"about_ca_topic_score_gemma":0.0007503054,"domain_scores_codex":[0.9999356,0.000003965313,0.000001606447,0.00002069512,0.00001544278,0.00002260359],"domain_scores_gemma":[0.9999229,0.00003021828,0.00002279884,0.000006621447,0.000009961853,0.000007529978],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001478178,0.00001270743,0.00181803,0.00006892625,0.00001136194,0.0001090012,0.0001461946,0.0001628306,0.9948238,0.0002462637,0.00006052578,0.002392635],"study_design_scores_gemma":[0.00001545155,0.0001053025,0.020988,0.000005798392,0.0000142742,0.0001323868,0.0001191007,0.0009549262,0.9766657,0.0001430188,0.000849231,0.000006645671],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973937,0.0003385775,0.0008260561,0.00002312767,0.000005531917,0.00001025456,0.0001299513,0.00002011874,0.001252441],"genre_scores_gemma":[0.9983413,0.000187622,0.0004451796,0.00002002036,0.000002506908,0.00001476561,0.0002119018,0.00001483016,0.0007618603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002936496,"threshold_uncertainty_score":0.009823501,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009252001584005512,"score_gpt":0.1916528892183853,"score_spread":0.1824008876343798,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}