{"id":"W1532247937","doi":"10.1016/j.molcata.2007.08.008","title":"Catalytic deoxygenation of terminal-diols under acidic aqueous conditions by the ruthenium complexes [(η6-arene)Ru(X)(N∩N)](OTf)n, X=H2O, H, η6-arene=p-Me-iPr-C6H4, C6Me6, N∩N=bipy, phen, 6,6′-diamino-bipy, 2,9-diamino-phen, n=1, 2)","year":2007,"lang":"en","type":"article","venue":"Journal of Molecular Catalysis A Chemical","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University; University of Waterloo; University of Guelph","funders":"Natural Resources Canada; Natural Sciences and Engineering Research Council of Canada; BIOCAP Canada","keywords":"Ruthenium; Chemistry; Catalysis; Medicinal chemistry; Deoxygenation; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001375652,0.0008367585,0.001488351,0.0008257297,0.0003215287,0.0001720105,0.001756372,0.0006396132,0.0004919695],"category_scores_gemma":[0.000882695,0.0007000676,0.001685369,0.001992524,0.0008540903,0.0004108634,0.0003250531,0.001133482,0.00006267889],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000725999,"about_ca_system_score_gemma":0.0003964163,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001689702,"about_ca_topic_score_gemma":0.00004272225,"domain_scores_codex":[0.9928536,0.0001570692,0.002830906,0.0008266297,0.002346872,0.0009849698],"domain_scores_gemma":[0.9934168,0.000732336,0.002526133,0.001334209,0.001295692,0.0006947897],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001406504,0.0008539555,0.0003786294,0.0001429237,0.001736048,0.0002241647,0.0005607117,0.0001847975,0.9866276,0.0002900884,0.004586042,0.004274362],"study_design_scores_gemma":[0.001895712,0.0000794514,0.0002074505,0.0001260318,0.002238967,0.001176455,0.001998445,0.0004450278,0.9883374,0.0008935853,0.001850705,0.0007507615],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9756174,0.004774353,0.01440649,0.0009994516,0.0001717334,0.0002637313,0.0003885258,0.00008173868,0.003296573],"genre_scores_gemma":[0.9956703,0.000155663,0.0005132444,0.000498298,0.0003819165,0.0000315522,0.002020771,0.000124971,0.0006032527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02005293,"threshold_uncertainty_score":0.999545,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00907040098979958,"score_gpt":0.2549414184162889,"score_spread":0.2458710174264893,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}