{"id":"W1548465062","doi":"10.1002/zaac.201400178","title":"C–H Bond Activation of Benzene, Toluene, 3,3‐Dimethyl‐1‐butene and Methane by Silica‐Supported Ta<sup>V</sup> Imido Amido Surface Complex","year":2014,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Toluene; Benzene; Tantalum; Chemistry; 1-Butene; Alkyl; Methane; Deuterium; Photochemistry; Medicinal chemistry; Catalysis; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000569205,0.0002171182,0.0001516815,0.00008339983,0.000125142,0.0001759176,0.0002418082,0.0001520383,0.001200891],"category_scores_gemma":[0.0001099105,0.00009424739,0.0001174443,0.00007901867,0.0001566746,0.0001384356,0.0001477076,0.0001513054,0.000174658],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000231984,"about_ca_system_score_gemma":0.0001144947,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001269212,"about_ca_topic_score_gemma":0.002052743,"domain_scores_codex":[0.9999257,0.000009757256,0.000002887137,0.00001177293,0.00001811836,0.00003171225],"domain_scores_gemma":[0.9999676,0.000007796965,0.000009869907,0.000003741552,0.000004493599,0.000006407538],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001233947,0.000004374698,0.0001414138,0.00002210089,0.000004306607,0.00002638658,0.00002953545,0.00005793812,0.9990668,0.00008912411,0.00001708675,0.000417648],"study_design_scores_gemma":[0.000005371272,0.00009593039,0.00108227,0.000001170846,0.000003588766,0.00003040121,0.00002120586,0.0004110872,0.9979646,0.0000125739,0.0003695981,0.000002282813],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986362,0.0002206134,0.0003119284,0.00001247594,0.000004414117,0.00000315926,0.00003645155,0.00001294896,0.0007619207],"genre_scores_gemma":[0.9992806,0.00008571003,0.0001694495,0.000004237016,0.000001184555,0.000001864859,0.00005994044,0.000003432366,0.0003934676],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001269212,"threshold_uncertainty_score":0.004017353,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01019761601525269,"score_gpt":0.2508820926381186,"score_spread":0.2406844766228659,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}