{"id":"W1550432452","doi":"10.1111/j.1742-4658.2008.06739.x","title":"Catalyzing separation of carbon dioxide in thiamin diphosphate‐promoted decarboxylation","year":2008,"lang":"en","type":"review","venue":"FEBS Journal","topic":"Biochemical Acid Research Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Carbanion; Chemistry; Decarboxylation; Nucleophile; Catalysis; Protonation; Carbon dioxide; Trifluoroacetic acid; Photochemistry; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003118712,0.0002794084,0.0007642883,0.0001754683,0.00006328298,0.0000159371,0.0002730738,0.0004194498,0.000003634924],"category_scores_gemma":[0.0003647686,0.0002241652,0.0003036266,0.0002760121,0.000106788,0.000005011669,0.0001676052,0.0005683604,0.000002433179],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001020461,"about_ca_system_score_gemma":0.0003199552,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002939443,"about_ca_topic_score_gemma":0.00002086583,"domain_scores_codex":[0.9981753,0.0001941316,0.0007185015,0.000301204,0.0003029565,0.0003078552],"domain_scores_gemma":[0.999,0.00003142604,0.0004817686,0.0002424863,0.0001530582,0.00009126038],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000186552,0.0003572895,0.0008326743,0.006088043,0.001042696,0.0001648081,0.0002488669,0.00003117239,0.08928557,0.000009569302,0.001493842,0.9002589],"study_design_scores_gemma":[0.001343308,0.0007238843,0.0004890923,0.01062216,0.0003203766,0.001319048,0.00004010559,0.00004587796,0.125511,0.00007986918,0.8583608,0.001144414],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.01159129,0.9876168,0.00004399734,0.00001418104,0.0001246761,0.0002863964,0.00001416137,0.000004145867,0.0003043075],"genre_scores_gemma":[0.007320263,0.9918094,0.0001735457,0.000004437562,0.0003429117,0.00002197387,0.0001941359,0.00003230302,0.0001010484],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8991145,"threshold_uncertainty_score":0.9141192,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0302154161796361,"score_gpt":0.3493142488058525,"score_spread":0.3190988326262164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}