{"id":"W1559799250","doi":"10.1016/s0022-328x(00)00654-9","title":"The reactions of CpRu(PPh3)2SR with the electrophiles HBF4, [MeSSMe2]BF4 and MeSphth where R=CMe3, CHMe2, 4-C6H4Me and phth=phthalimide","year":2001,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Phthalimide; Electrophile; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004558618,0.0003872108,0.0003643938,0.0002175436,0.0002351071,0.0002972522,0.0003534645,0.000402943,0.002862941],"category_scores_gemma":[0.000441021,0.0001453152,0.0003171485,0.0002347188,0.0003050434,0.0003447273,0.0002255034,0.000374332,0.0008474661],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000337037,"about_ca_system_score_gemma":0.0002106419,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008228477,"about_ca_topic_score_gemma":0.001050302,"domain_scores_codex":[0.9996527,0.00008237902,0.0000156709,0.00003439453,0.00006745049,0.0001472675],"domain_scores_gemma":[0.999826,0.0000583714,0.00003870567,0.00003154046,0.0000188733,0.00002651539],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008546626,0.00006876208,0.0004227158,0.000261615,0.0000476605,0.0003939034,0.0001498658,0.0005263834,0.9838731,0.002370388,0.0007581479,0.01027286],"study_design_scores_gemma":[0.00002640467,0.0003248845,0.0008763173,0.000004941138,0.00001140431,0.000285282,0.00001913813,0.0003253769,0.9954422,0.0001142245,0.002560686,0.000009140471],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9857031,0.002045395,0.002464603,0.0001635646,0.00007068168,0.00004449491,0.000284106,0.0001785517,0.009045512],"genre_scores_gemma":[0.9921067,0.0008041625,0.001412111,0.00004211951,0.0000199911,0.00001462598,0.0003560916,0.00002963356,0.005214537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002862941,"threshold_uncertainty_score":0.009577453,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004918645165639848,"score_gpt":0.2004721456722387,"score_spread":0.1955535005065989,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}