{"id":"W1562060445","doi":"10.1002/cem.2535","title":"Process analytical chemistry and chemometrics, Bruce Kowalski's legacy at The Dow Chemical Company","year":2013,"lang":"en","type":"article","venue":"Journal of Chemometrics","topic":"Spectroscopy and Chemometric Analyses","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dow Chemical (Canada)","funders":"","keywords":"Chemometrics; Chemistry; Process analytical technology; Industrial chemistry; Analytical Chemistry (journal); Graduate students; Process (computing); Engineering; Computer science; Chemical engineering; Biochemical engineering; Sociology; Organic chemistry; Chromatography; Bioprocess","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.01457485,0.001199031,0.001440181,0.005398532,0.001907871,0.008086345,0.00133059,0.003354463,0.004392443],"category_scores_gemma":[0.01907694,0.0008825605,0.0008697812,0.008268078,0.01117502,0.01181581,0.002859019,0.01257558,0.004781252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00411773,"about_ca_system_score_gemma":0.004759013,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004525146,"about_ca_topic_score_gemma":0.003459154,"domain_scores_codex":[0.985855,0.003773769,0.001044363,0.002000703,0.006990861,0.0003352803],"domain_scores_gemma":[0.9828111,0.008341943,0.001117937,0.001512011,0.005112092,0.001104931],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001116424,0.0001138418,0.001519599,0.0008107044,0.0001056908,0.0001495804,0.0008493407,0.001124035,0.001198513,0.3716775,0.2763028,0.3460368],"study_design_scores_gemma":[0.0000144891,0.00006720961,0.000842682,0.0005563189,0.00001925828,0.0004839767,0.0002099957,0.00116956,0.001026356,0.15403,0.841502,0.00007814943],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"other","genre_scores_codex":[0.00281308,0.4580438,0.1787871,0.2854755,0.01605527,0.0001021422,0.0004012002,0.0006802014,0.05764178],"genre_scores_gemma":[0.05527443,0.4840685,0.2447889,0.07865239,0.0323985,0.0002348347,0.0006983288,0.0008567697,0.1030273],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.01457485,"threshold_uncertainty_score":0.07708013,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01429513565368905,"score_gpt":0.2765323366603345,"score_spread":0.2622372010066454,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}