{"id":"W1564620461","doi":"10.1002/ejic.201500491","title":"NHC‐Stabilized Bis(trimethylsilyl)phosphido Complexes of Pd<sup>II</sup> and Ni<sup>II</sup>","year":2015,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Denticity; Trimethylsilyl; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Metal; Stereochemistry; Mass spectrum; Benzimidazole; Crystallography; Mass spectrometry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001631147,0.001051466,0.001683139,0.0001168639,0.0003735976,0.0001412767,0.002068231,0.0004234083,0.004346768],"category_scores_gemma":[0.001855291,0.001019708,0.0005704284,0.0005869116,0.0008201281,0.000409643,0.001750392,0.001857839,0.00003933325],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005087667,"about_ca_system_score_gemma":0.0007943521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002668406,"about_ca_topic_score_gemma":6.211009e-7,"domain_scores_codex":[0.9936468,0.0001835095,0.002849239,0.0009740054,0.001375269,0.0009712006],"domain_scores_gemma":[0.9939978,0.0003079749,0.001973719,0.001591864,0.0009383758,0.001190234],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004014053,0.0005455174,0.001318335,0.0007046559,0.0004814576,0.0002781579,0.003139056,0.00007510281,0.978659,0.00001307929,0.01294372,0.001440481],"study_design_scores_gemma":[0.006635022,0.0002657245,0.0001081808,0.0005732357,0.0003871935,0.003341726,0.00604735,0.000138282,0.9528207,0.0001187089,0.02853807,0.001025823],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9569435,0.005572185,0.00005551989,0.000354565,0.0001989138,0.0001070503,0.0001258036,0.0001466547,0.03649582],"genre_scores_gemma":[0.991721,0.0006759739,0.0008279455,0.000146377,0.001763628,0.000002030585,0.00005653069,0.0002896803,0.004516813],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03477753,"threshold_uncertainty_score":0.9992253,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01632772112005808,"score_gpt":0.2258742107309416,"score_spread":0.2095464896108835,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}