{"id":"W1564620461","doi":"10.1002/ejic.201500491","title":"NHC‐Stabilized Bis(trimethylsilyl)phosphido Complexes of Pd<sup>II</sup> and Ni<sup>II</sup>","year":2015,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Denticity; Trimethylsilyl; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Metal; Stereochemistry; Mass spectrum; Benzimidazole; Crystallography; Mass spectrometry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007435076,0.0002410367,0.0001447692,0.00007727127,0.0001201729,0.0002142106,0.0002821293,0.000187605,0.002570244],"category_scores_gemma":[0.0001185135,0.0001272567,0.00006051362,0.00006368006,0.0001344978,0.0001589645,0.0001683838,0.0002566582,0.0004396285],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002789026,"about_ca_system_score_gemma":0.0001235758,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000527679,"about_ca_topic_score_gemma":0.000742069,"domain_scores_codex":[0.9999347,0.000008239073,0.000002963533,0.00001321337,0.00002022548,0.00002060445],"domain_scores_gemma":[0.9999533,0.00000664176,0.00001255304,0.000004330854,0.000008758533,0.00001454465],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002380868,0.00001644933,0.00008314585,0.00005126699,0.00000691661,0.00003356552,0.00002309833,0.0001636155,0.9978361,0.0002261631,0.0001731593,0.001148497],"study_design_scores_gemma":[0.00002976726,0.0001198914,0.0006386422,0.000002781939,0.000005668869,0.00004268956,0.00001176616,0.0007368652,0.9962873,0.00002823142,0.002092256,0.000004053182],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910822,0.0006337244,0.001688312,0.00004493005,0.00003272274,0.00002137498,0.0001558718,0.0001639594,0.006176867],"genre_scores_gemma":[0.996371,0.0001766616,0.0007711824,0.00002875333,0.000006384759,0.00001161661,0.0002122694,0.00002788788,0.002394189],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002570244,"threshold_uncertainty_score":0.008598328,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01632772112005808,"score_gpt":0.2258742107309416,"score_spread":0.2095464896108835,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}