{"id":"W1568942929","doi":"10.1002/9783527639328.ch8","title":"Catalytic Additions of Allylic Boronates to Carbonyl and Imine Derivatives","year":2011,"lang":"en","type":"other","venue":"","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Imine; Allylic rearrangement; Catalysis; Chemistry; Organic chemistry; Medicinal chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00014711,0.0006625569,0.0003074387,0.000495732,0.0003196686,0.0004652024,0.0005080851,0.0002998858,0.01446503],"category_scores_gemma":[0.00008898405,0.0002677543,0.0002619045,0.0004009605,0.0002325478,0.0006369493,0.0005867318,0.0007578579,0.005532286],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006069414,"about_ca_system_score_gemma":0.0002782819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000676466,"about_ca_topic_score_gemma":0.002466237,"domain_scores_codex":[0.9998813,0.00000851558,0.000006118755,0.00001835845,0.00004915435,0.00003669244],"domain_scores_gemma":[0.9999807,0.000003181264,0.000003391182,0.000003097008,0.000004169165,0.000005535222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003852857,0.0002380242,0.0001352326,0.001928863,0.00003740933,0.0005145316,0.0005033404,0.00190985,0.7699255,0.03774819,0.01561727,0.1710565],"study_design_scores_gemma":[0.00002538269,0.0001912943,0.0002543805,0.00009205532,0.00001740304,0.0002212582,0.00006094032,0.0005713188,0.8015316,0.001341093,0.1956715,0.00002173284],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2163036,0.03472709,0.0218874,0.0008872952,0.001283037,0.000213249,0.00123134,0.0008672934,0.7225996],"genre_scores_gemma":[0.5189219,0.06699574,0.01623832,0.000620145,0.0003793579,0.0001873484,0.001876807,0.0004234062,0.3943571],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01446503,"threshold_uncertainty_score":0.04839039,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01256822142591682,"score_gpt":0.2142682486683222,"score_spread":0.2017000272424054,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}