{"id":"W1575121515","doi":"10.1002/0470009403.ch6","title":"Kinetics and Mechanism of Electrodeposition","year":2005,"lang":"en","type":"other","venue":"","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Overpotential; Nernst equation; Kinetic energy; Kinetics; Thermodynamics; Current (fluid); Electrode; Mechanism (biology); Chemistry; Physics; Physical chemistry; Classical mechanics; Electrochemistry; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000005672522,0.00008345245,0.000136129,0.00002744632,0.000006048883,0.000003925021,0.00005427725,0.0001459373,0.006755954],"category_scores_gemma":[0.000001315735,0.00007226168,0.00003725409,0.00003966256,0.00001548472,0.000002941632,0.00001334005,0.00006644426,0.00001158455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007292912,"about_ca_system_score_gemma":0.000002818324,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002837688,"about_ca_topic_score_gemma":0.00004116918,"domain_scores_codex":[0.9996321,0.000001125584,0.00009820723,0.0001297507,0.00006553027,0.00007327685],"domain_scores_gemma":[0.9997478,0.000006052307,0.00007951759,0.0001339653,0.000007814757,0.00002481251],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[5.095344e-7,0.00003673768,7.420095e-7,0.00004265124,0.00003756251,4.648653e-8,0.000001127898,3.557051e-8,0.9557493,0.02004789,0.02279206,0.001291308],"study_design_scores_gemma":[0.00004923023,0.000005853572,1.695974e-7,0.00002441625,0.00007306521,0.000001619379,0.000001502331,0.00007194711,0.855309,0.0008880824,0.1434926,0.00008252133],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0001895148,0.0005766644,0.002858562,0.00007095429,0.000001166683,0.00001932649,0.00001027704,0.00005596135,0.9962175],"genre_scores_gemma":[0.0451602,0.0006722925,0.002647776,0.00003672748,0.0001688871,0.0000109985,0.00009910523,0.00009417237,0.9511098],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.1207005,"threshold_uncertainty_score":0.994152,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002961681426122379,"score_gpt":0.2037563775644156,"score_spread":0.2007946961382932,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}