{"id":"W1588181711","doi":"10.1063/1.4921782","title":"Kinetic-freezing and unfreezing of local-region fluctuations in a glass structure observed by heat capacity hysteresis","year":2015,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Material Dynamics and Properties","field":"Materials Science","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Enthalpy; Thermodynamics; Relaxation (psychology); Glass transition; Endotherm; Heat capacity; Hysteresis; Atmospheric temperature range; Kinetic energy; Materials science; Alloy; Scattering; Chemistry; Condensed matter physics; Differential scanning calorimetry; Optics; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002988822,0.00009296945,0.0002401682,0.00001569363,0.00002322223,0.00003033073,0.0002243502,0.00004646783,0.000005485515],"category_scores_gemma":[0.00006503519,0.00005854651,0.00002934969,0.00008541704,0.0001838398,0.0001485645,0.00007465402,0.0001252179,4.264294e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004352978,"about_ca_system_score_gemma":0.00003266148,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002465253,"about_ca_topic_score_gemma":0.000008818314,"domain_scores_codex":[0.9991519,0.00009861563,0.0003361002,0.00006757614,0.000221988,0.0001237978],"domain_scores_gemma":[0.9993933,0.00007850377,0.0001841674,0.000132961,0.0001449432,0.00006610201],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001047957,0.00001927675,0.00007373805,0.00003965901,0.000005362682,5.546783e-7,0.0006663608,0.0005878729,0.9979575,0.0001809614,0.0001205495,0.000243365],"study_design_scores_gemma":[0.0004395266,0.00006004308,0.0001111944,0.000107585,0.00002685677,0.00001690797,0.0001507675,0.002572576,0.9818202,0.01459808,0.00002112691,0.00007508355],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975121,0.0001880615,0.001867508,0.0002175222,0.0001104981,0.00005257782,0.00001756061,0.000003554868,0.000030617],"genre_scores_gemma":[0.9994795,0.00001106091,0.0003668775,0.00003833383,0.000090678,3.9048e-7,0.000001558811,0.000008088427,0.000003462226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01613726,"threshold_uncertainty_score":0.2387458,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04164484701937284,"score_gpt":0.2247299834029902,"score_spread":0.1830851363836173,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}