{"id":"W1588222590","doi":"10.1007/978-90-481-3433-5_11","title":"Ring-Closing Metathesis Synthesis of Medium and Large Rings: Challenges and Implications for Sustainable Synthesis","year":2009,"lang":"en","type":"book-chapter","venue":"NATO science for peace and security series. A, Chemistry and biology","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Ring-closing metathesis; Metathesis; Closing (real estate); Salt metathesis reaction; Ring (chemistry); Combinatorial chemistry; Selectivity; Chemistry; Nanotechnology; Materials science; Business; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00139796,0.0005175374,0.0009528302,0.00006974237,0.000565656,0.00007916649,0.0003861246,0.0008226414,0.0000616445],"category_scores_gemma":[0.002521155,0.0004989794,0.000122384,0.00006017158,0.001948166,0.0001957574,0.0003380878,0.0002830249,9.573564e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007331691,"about_ca_system_score_gemma":0.0002143584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006095703,"about_ca_topic_score_gemma":0.000005673824,"domain_scores_codex":[0.9974635,0.00001354352,0.0004974245,0.001223597,0.0001364336,0.0006655019],"domain_scores_gemma":[0.9969063,0.001553838,0.0004260159,0.0004930109,0.0003433076,0.0002775021],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002782258,0.0001291271,0.0001075442,0.01199589,0.0002982885,0.000004395432,0.001407992,3.215569e-8,0.8254116,0.05550804,0.00006377856,0.1047951],"study_design_scores_gemma":[0.0003695992,0.00005973035,0.00003336792,0.0003242935,0.0004235528,0.0001948017,0.002174312,0.00002463128,0.8478292,0.04734416,0.1005964,0.0006259237],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4277453,0.2180723,0.000341107,0.01552296,0.0001780913,0.002514185,0.005339017,0.0004950819,0.3297919],"genre_scores_gemma":[0.912132,0.06035649,0.005397239,0.00007381784,0.0004173939,0.000344176,0.00006382342,0.0001188495,0.02109619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4843867,"threshold_uncertainty_score":0.9997462,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02768844095362622,"score_gpt":0.2928882493739918,"score_spread":0.2651998084203656,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}