{"id":"W1590508524","doi":"10.1002/0470867833.ch1","title":"Thermodynamics of Solubility","year":2003,"lang":"en","type":"other","venue":"","topic":"Crystallization and Solubility Studies","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Thermodynamics; Solubility; Chemistry; Physical chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001669791,0.0001171708,0.0002649779,0.00004325721,0.00001844523,0.000008060356,0.0001250899,0.0001164362,0.06614788],"category_scores_gemma":[0.00005559612,0.0000921299,0.00005592904,0.00005880818,0.0001527126,0.00001056743,0.00004524992,0.00003278571,0.0001098094],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001682076,"about_ca_system_score_gemma":0.00003203064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002031963,"about_ca_topic_score_gemma":0.0009335912,"domain_scores_codex":[0.9993035,0.00004941624,0.0001809914,0.0002067015,0.0001489722,0.0001104454],"domain_scores_gemma":[0.9994499,0.00002143841,0.0001209274,0.0003480959,0.00003580321,0.00002384398],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000008914345,0.0002669561,0.0005092493,0.0005098229,0.00004724292,9.658987e-7,0.0002769419,0.000009894196,0.01510637,0.0307195,0.9520825,0.0004616542],"study_design_scores_gemma":[0.0001908188,0.00002576088,0.0001325609,0.00004643276,0.00002317984,6.748972e-7,0.0001653308,0.00008198666,0.001418506,0.001200688,0.9964398,0.0002742887],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.000321098,0.0002269706,0.004397183,0.00002164713,0.0003137857,0.000162556,0.00005653131,0.0001290427,0.9943712],"genre_scores_gemma":[0.003387972,0.00007812338,0.001808672,0.00006164756,0.00002320369,0.000005187767,0.000007397543,0.0001020148,0.9945258],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.06603806,"threshold_uncertainty_score":0.9347058,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01676365729824202,"score_gpt":0.2581923966087528,"score_spread":0.2414287393105108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}