{"id":"W1592771453","doi":"10.1002/ejic.201402895","title":"Influence of Ligand Substitution Pattern on Structure in Cobalt(II) Complexes of Bulky <i>N</i>,<i>N′</i>‐Diarylformamidinate <i>N</i>‐Oxides","year":2014,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Isomerization; Cobalt; Steric effects; Ligand (biochemistry); Crystallography; Substitution (logic); Oxide; Chelation; Stereochemistry; Tetrahedron; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008571162,0.0002177689,0.0006614826,0.00009117096,0.00004744711,0.00001094529,0.0003234044,0.00005189519,0.00008271513],"category_scores_gemma":[0.0004418449,0.0001629169,0.0001381011,0.0001964674,0.0001975151,0.0001113218,0.00009057846,0.0004255724,0.000004181248],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000444043,"about_ca_system_score_gemma":0.00008185361,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001021294,"about_ca_topic_score_gemma":0.000001608883,"domain_scores_codex":[0.9980206,0.000113659,0.001091739,0.0001639405,0.000412492,0.0001975668],"domain_scores_gemma":[0.9982965,0.000095732,0.0008704707,0.0003221306,0.0002953293,0.0001198678],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002890569,0.0001275865,0.01155348,0.0005590959,0.00004875177,0.00002879297,0.0002647022,0.000330158,0.9856004,0.00002202738,0.00009312345,0.001082892],"study_design_scores_gemma":[0.001194545,0.000549302,0.05489231,0.001342053,0.00005766057,0.0003054794,0.00005994207,0.00002416732,0.9404493,0.00004902518,0.0009425444,0.0001336456],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974355,0.0005164623,0.00003426054,0.0001303735,0.00004862596,0.00007548972,0.0000184907,0.0000084674,0.001732369],"genre_scores_gemma":[0.9993264,0.0001412523,0.0001134814,0.0001915154,0.000145798,1.930481e-7,0.000005979702,0.00002788608,0.00004749125],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04515101,"threshold_uncertainty_score":0.6643557,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0118314645859869,"score_gpt":0.2134877427459528,"score_spread":0.2016562781599659,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}