{"id":"W1597684247","doi":"10.1063/1.1457440","title":"Coherent control of the CH2Br+I←CH2BrI→CH2I+Br branching photodissociation reaction","year":2002,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Weizmann Institute of Science","keywords":"Photodissociation; Branching fraction; Excited state; Branching (polymer chemistry); Quantum yield; Quantum; Excitation; Physics; Atomic physics; Laser; Fluorescence; Chemistry; Optics; Photochemistry; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004469676,0.0003151904,0.0002673479,0.000201422,0.0004121906,0.0006850848,0.0006240158,0.0002989678,0.001625954],"category_scores_gemma":[0.0009668045,0.0001947279,0.0002135253,0.0002787691,0.0006089961,0.0005405559,0.0006348719,0.000504074,0.0001026563],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006450114,"about_ca_system_score_gemma":0.000576899,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009120812,"about_ca_topic_score_gemma":0.001284932,"domain_scores_codex":[0.9998372,0.00002659034,0.000004863454,0.00003017336,0.00005624013,0.00004485],"domain_scores_gemma":[0.9995573,0.0002506448,0.00007081125,0.00004195451,0.00004040355,0.00003892307],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008996943,0.0004183993,0.003309824,0.000358128,0.00009696684,0.0003419087,0.0003458869,0.2051852,0.6660299,0.08504394,0.0006859176,0.03728429],"study_design_scores_gemma":[0.0003030798,0.0006920004,0.001710088,0.00001500343,0.00005962563,0.00007925523,0.00007719133,0.6918187,0.2980341,0.00591083,0.001225644,0.00007452415],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9507644,0.0002797574,0.03827281,0.0001786742,0.00003285245,0.0000454877,0.00004950426,0.0001694599,0.01020722],"genre_scores_gemma":[0.9957895,0.00006840592,0.003738017,0.00001972563,0.000003396198,0.00001738909,0.00002110318,0.00001715561,0.0003253541],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001625954,"threshold_uncertainty_score":0.005439341,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01142496721858758,"score_gpt":0.2287128966368302,"score_spread":0.2172879294182426,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}