{"id":"W1607510719","doi":"10.1007/128_2015_657","title":"Rearrangements Induced by Hypervalent Iodine","year":2015,"lang":"en","type":"article","venue":"Topics in current chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Hypervalent molecule; Chemistry; Iodine; Reagent; Claisen rearrangement; Pinacol; Stereochemistry; Iodide; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001305224,0.0002625372,0.0002419797,0.00001753214,0.00004050121,0.00003412146,0.0003806535,0.0001882005,0.002221076],"category_scores_gemma":[0.0002467608,0.0002925796,0.00006500774,0.0001847631,0.00005526138,0.00006586612,0.0001699162,0.0006134764,0.00007735052],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005427108,"about_ca_system_score_gemma":0.000128723,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002149943,"about_ca_topic_score_gemma":0.000002453792,"domain_scores_codex":[0.9983839,0.000009053083,0.0003770275,0.0004588554,0.0004033662,0.00036783],"domain_scores_gemma":[0.9989211,0.00002805125,0.000128613,0.0005694192,0.00009189521,0.000260924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001693147,0.0004039865,0.007251933,0.0002413215,0.00002078265,0.000005764995,0.0001267813,0.000001930966,0.9756934,0.000006002559,0.01008105,0.00615013],"study_design_scores_gemma":[0.00137495,0.000003395349,0.00007161916,0.0001009334,0.00001755,0.000009465986,0.0002208188,0.0000684576,0.8525693,0.0001529131,0.1450911,0.0003194624],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9263489,0.0006931127,0.000008256247,0.0003655023,0.0002468658,0.00005156761,0.00006840291,0.0001116524,0.0721058],"genre_scores_gemma":[0.992798,0.00007609629,0.00007533401,0.00001741185,0.0006178481,0.00004685395,0.0002924979,0.00003604236,0.0060399],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1350101,"threshold_uncertainty_score":0.9999526,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0793922705411862,"score_gpt":0.3182686359437401,"score_spread":0.2388763654025539,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}