{"id":"W1608295400","doi":"10.3390/molecules200610748","title":"Oxidation of Disulfides to Thiolsulfinates with Hydrogen Peroxide and a Cyclic Seleninate Ester Catalyst","year":2015,"lang":"en","type":"article","venue":"Molecules","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Innovates","keywords":"Chemistry; Hydrogen peroxide; Catalysis; Organic chemistry; Aryl; Alkyl; Peroxide; Yield (engineering); Peroxidase; Combinatorial chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002307811,0.000201751,0.0002368952,0.00007577694,0.00006993821,0.00001779145,0.0001672721,0.0001772228,0.00005503357],"category_scores_gemma":[0.0000876993,0.0001682012,0.00003122002,0.0002010398,0.0001569886,0.00009333694,0.00009930264,0.0002041423,0.00004926636],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003107099,"about_ca_system_score_gemma":0.00006817156,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002834613,"about_ca_topic_score_gemma":0.00002013155,"domain_scores_codex":[0.998964,0.00009315171,0.0002282414,0.0002944071,0.0001519553,0.0002682713],"domain_scores_gemma":[0.9992239,0.00008467855,0.00009618659,0.0001823137,0.0001163447,0.0002965193],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002420484,0.00009852299,0.01017707,0.0000594079,0.00007894794,0.0000215799,0.001436489,0.00009153138,0.9861562,0.00007324601,0.0005718855,0.0009930953],"study_design_scores_gemma":[0.0009038807,0.0001691442,0.002726563,0.00001928795,0.0001156966,0.00004907511,0.0002480056,0.00005803272,0.9903606,0.0001435889,0.004992777,0.0002133621],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970069,0.00058773,0.0001742048,0.0009362783,0.00005505128,0.0001946766,0.00002490074,0.00005762694,0.0009626087],"genre_scores_gemma":[0.9981804,0.00004031808,0.0007122956,0.0005075005,0.00005670183,0.00001980631,0.00003284772,0.00002981573,0.0004202425],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007450508,"threshold_uncertainty_score":0.6859046,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05722663684602043,"score_gpt":0.3576880347760473,"score_spread":0.3004613979300269,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}