{"id":"W1629829734","doi":"10.1016/j.ica.2015.08.029","title":"Synthesis, characterization and biological studies of S-4-methylbenzyl-β-N-(2-furylmethylene)dithiocarbazate (S4MFuH) its Zn2+, Cu2+, Cd2+ and Ni2+ complexes","year":2015,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":25,"is_retracted":false,"has_abstract":false,"ca_institutions":"Cape Breton University","funders":"Ministério da Ciência, Tecnologia e Inovação; Universiti Malaya; Kementerian Sains, Teknologi dan Inovasi; Universiti Putra Malaysia; Ministry of Higher Education, Malaysia","keywords":"Chemistry; Deprotonation; Denticity; Stereochemistry; Ligand (biochemistry); Crystallography; Intramolecular force; Transition metal; Metal; Crystal structure; Receptor; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007468076,0.0003578884,0.001100252,0.0001549947,0.000128113,0.00004214507,0.000187558,0.0001891756,0.00007215731],"category_scores_gemma":[0.002652565,0.0002478862,0.00008220734,0.0002288503,0.0004620549,0.000183999,0.0003437581,0.0002298397,0.00001472515],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003888536,"about_ca_system_score_gemma":0.00007817876,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001458696,"about_ca_topic_score_gemma":0.000004646927,"domain_scores_codex":[0.9978572,0.0003016449,0.0006560987,0.0005248142,0.0003334687,0.0003267464],"domain_scores_gemma":[0.998103,0.0005853685,0.0002959478,0.0004070227,0.000329525,0.0002790877],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003304041,0.0001235679,0.005770964,0.0002381372,0.0002563514,0.000002286299,0.0008073832,3.311559e-8,0.9907408,0.000340615,0.0002562823,0.001133145],"study_design_scores_gemma":[0.001046358,0.0009340373,0.1169224,0.0004258071,0.0003849558,0.0001679238,0.0007532189,0.0001058788,0.8673906,0.0004450877,0.01093088,0.0004929012],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918515,0.004179822,0.00001952789,0.002871259,0.0001483325,0.0003900217,0.00006977484,0.00008906472,0.0003807005],"genre_scores_gemma":[0.9928508,0.005228265,0.001151351,0.0003625959,0.0001637586,0.00002417159,0.00003308897,0.00004427279,0.0001417222],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1233503,"threshold_uncertainty_score":0.9999973,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1413612385546765,"score_gpt":0.310683952595001,"score_spread":0.1693227140403245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}