{"id":"W1629829734","doi":"10.1016/j.ica.2015.08.029","title":"Synthesis, characterization and biological studies of S-4-methylbenzyl-β-N-(2-furylmethylene)dithiocarbazate (S4MFuH) its Zn2+, Cu2+, Cd2+ and Ni2+ complexes","year":2015,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":25,"is_retracted":false,"has_abstract":false,"ca_institutions":"Cape Breton University","funders":"Ministério da Ciência, Tecnologia e Inovação; Universiti Malaya; Kementerian Sains, Teknologi dan Inovasi; Universiti Putra Malaysia; Ministry of Higher Education, Malaysia","keywords":"Chemistry; Deprotonation; Denticity; Stereochemistry; Ligand (biochemistry); Crystallography; Intramolecular force; Transition metal; Metal; Crystal structure; Receptor; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001377762,0.0001382587,0.0001316146,0.0001270988,0.0001490426,0.0001328381,0.0001509761,0.0001685719,0.0007971172],"category_scores_gemma":[0.0001749395,0.00009136383,0.0001209219,0.00007978934,0.000125504,0.00009783941,0.00008834621,0.0001289521,0.0002536787],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001631699,"about_ca_system_score_gemma":0.0001628962,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001567998,"about_ca_topic_score_gemma":0.001118485,"domain_scores_codex":[0.9999518,0.000009728827,0.000004589896,0.00001186029,0.00001061911,0.00001128402],"domain_scores_gemma":[0.9999307,0.00001441182,0.0000140309,0.000007825849,0.00001862806,0.00001438395],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006016127,0.000007570959,0.00006506175,0.00001532217,0.000001481055,0.00001339317,0.00001298219,0.00002581556,0.9989575,0.00003300453,0.00001346015,0.0007943765],"study_design_scores_gemma":[0.000004151431,0.0001080825,0.0007928589,8.573518e-7,0.000005945364,0.00007198581,0.00000735961,0.0001961317,0.997772,0.00001108866,0.001027661,0.000001727423],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903211,0.002838987,0.004440362,0.00009540386,0.00001669147,0.00003604714,0.0002427177,0.00005739069,0.001951288],"genre_scores_gemma":[0.9940427,0.0006128153,0.001837443,0.00001973908,0.000007065612,0.00001733242,0.000230322,0.000009492997,0.003223084],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001567998,"threshold_uncertainty_score":0.0031178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1413612385546765,"score_gpt":0.310683952595001,"score_spread":0.1693227140403245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}