{"id":"W1644944083","doi":"","title":"HIGH RESOLUTION INFRARED AND MICROWAVE SPECTRA OF NH$_{3}$-HCCH AND NH$_{3}$-OCS COMPLEXES: STUDIES OF WEAK C-H$\\cdots$N HYDROGEN BOND AND ELECTRIC MULTIPOLE INTERACTIONS","year":2011,"lang":"en","type":"article","venue":"66th International Symposium On Molecular Spectroscopy","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Multipole expansion; Microwave; Hydrogen bond; Infrared; Chemistry; Spectral line; Infrared spectroscopy; Analytical Chemistry (journal); Physical chemistry; Atomic physics; Physics; Molecule; Optics; Environmental chemistry; Organic chemistry; Quantum mechanics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001183152,0.0003052552,0.0004194598,0.0002038094,0.0001184036,0.00003405216,0.0002210508,0.0001428491,0.0000912887],"category_scores_gemma":[0.00004703023,0.0002974342,0.00009311862,0.0001636312,0.0002231184,0.0001245315,0.0001713436,0.0003452402,0.000003201763],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001579903,"about_ca_system_score_gemma":0.00003661044,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002512228,"about_ca_topic_score_gemma":0.0000191962,"domain_scores_codex":[0.9983116,0.00003306098,0.0005734328,0.0004703042,0.000327406,0.0002842092],"domain_scores_gemma":[0.9989845,0.00009079885,0.0003605587,0.0002824294,0.0001841247,0.00009760754],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003338467,0.0001976512,0.001117952,0.00009742101,0.0007086947,0.00001859098,0.0007044036,0.00001708195,0.9791597,0.01742152,0.0001316411,0.00009157202],"study_design_scores_gemma":[0.001228699,0.0003111593,0.0007948672,0.0001919358,0.0001450383,0.0001352231,0.0002700779,0.0008396522,0.9909465,0.004471173,0.000406843,0.0002588242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9829432,0.002494913,0.0003680543,0.0002893025,0.0002110877,0.0001625498,0.000044563,0.00004162721,0.01344474],"genre_scores_gemma":[0.9933128,0.001605786,0.004520708,0.00005529145,0.0000827664,0.00001521452,0.00003075489,0.00003946374,0.0003371976],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01310754,"threshold_uncertainty_score":0.9999478,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01236653858177175,"score_gpt":0.2510336634607805,"score_spread":0.2386671248790088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}