{"id":"W1656049656","doi":"10.1007/3-540-27213-5_125","title":"Heterodyne 2D-IR Photon Echo Spectroscopy of Multi-Level OH Stretching Coherences in Hydrogen Bonds","year":2005,"lang":"en","type":"book-chapter","venue":"Springer series in chemical physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Overtone; Fermi resonance; Femtosecond; Anharmonicity; Spectroscopy; Two-dimensional infrared spectroscopy; Atomic physics; Dimer; Infrared spectroscopy; Photon; Materials science; Molecular physics; Infrared; Nuclear magnetic resonance; Chemistry; Physics; Laser; Optics; Spectral line; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001048775,0.0007523977,0.00122733,0.00008278818,0.0000543474,0.00003271405,0.0005258984,0.0002926113,0.0003238822],"category_scores_gemma":[0.00001024634,0.0007704869,0.0003068057,0.0001271186,0.0004215582,0.0002219794,0.0004135052,0.001217019,0.00002096538],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002267277,"about_ca_system_score_gemma":0.00007247146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002399946,"about_ca_topic_score_gemma":0.00007021554,"domain_scores_codex":[0.9972748,0.00001563178,0.0008816577,0.0007989653,0.0003833231,0.0006456461],"domain_scores_gemma":[0.9988067,0.0001068654,0.0004284829,0.0004947683,0.00005491878,0.0001083191],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003125759,0.0009218022,0.01036657,0.0004374086,0.000503835,0.00001822071,0.001625457,0.0001381761,0.899657,0.0781389,0.0001171011,0.007763008],"study_design_scores_gemma":[0.0007633119,0.00006017867,0.00008095931,0.0004962275,0.00005522517,5.036638e-7,0.00008149998,0.0001403741,0.9228861,0.07360943,0.00104384,0.0007823505],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.865646,0.0007680175,0.0001189361,0.00007134112,0.000162611,0.0005248929,0.0003948384,0.00007097722,0.1322424],"genre_scores_gemma":[0.9915227,0.000124395,0.003513725,0.00002590846,0.0008239665,0.00005334184,0.0001330756,0.0001093674,0.00369357],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1285488,"threshold_uncertainty_score":0.9994746,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0278027322097786,"score_gpt":0.2702373927721855,"score_spread":0.2424346605624069,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}