{"id":"W165904355","doi":"10.1023/a:1010334818580","title":"Study of Aqueous Al2(SO4)3 Solution under Hydrothermal Conditions: Sulfate Ion Pairing, Hydrolysis, and Formation of Hydronium Alunite","year":2001,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Clay minerals and soil interactions","field":"Materials Science","cited_by":50,"is_retracted":false,"has_abstract":false,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Alunite; Raman spectroscopy; Aqueous solution; Hydronium; Sulfate; Denticity; Infrared spectroscopy; Hydrothermal circulation; Sulfur; Inorganic chemistry; Lamellar structure; Analytical Chemistry (journal); Ion; Crystallography; Physical chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005407152,0.0001364271,0.0003031996,0.0001116567,0.0001435561,0.00003069505,0.0001298164,0.00009832865,0.0002419522],"category_scores_gemma":[0.00005847007,0.0001264667,0.0001061191,0.000155226,0.0001092909,0.0006014887,0.00004386373,0.0001825389,0.00000364256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001225839,"about_ca_system_score_gemma":0.00005256693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001602965,"about_ca_topic_score_gemma":0.0000444792,"domain_scores_codex":[0.9983713,0.00008162124,0.0008711866,0.0001318779,0.0003626264,0.0001813825],"domain_scores_gemma":[0.9982816,0.00006591104,0.001080511,0.0001678499,0.0003203099,0.00008379825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001153704,0.0004851234,0.0004561463,0.00005816256,0.00003501527,0.000007447429,0.0004799093,0.004598235,0.9933206,0.00001209062,0.0002875898,0.0001443207],"study_design_scores_gemma":[0.001981729,0.000421577,0.00346725,0.0002394951,0.0001913449,0.0009191508,0.002098455,0.01346181,0.9763817,0.0003518941,0.0002822861,0.0002032791],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971825,0.000299644,0.001495571,0.0002214339,0.0001638848,0.0001118576,0.0000158688,0.00001410859,0.000495062],"genre_scores_gemma":[0.9993224,0.0001799234,0.0001003189,0.00001679275,0.0001522651,0.000005681627,0.00001124325,0.00001073431,0.0002006943],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01693886,"threshold_uncertainty_score":0.5157163,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0253251707129812,"score_gpt":0.2841185751181264,"score_spread":0.2587934044051453,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}