{"id":"W1683445286","doi":"10.1139/cjc-2013-0161","title":"Theoretical study on the OH-initiated atmospheric reaction of <i>N</i>-methyl perfluorobutane sulfonamidoethanol (C<sub>4</sub>F<sub>9</sub>SO<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>OH)","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Independent Innovation Foundation of Shandong University; National Natural Science Foundation of China","keywords":"Chemistry; Atmosphere (unit); Hydrogen; Carboxylate; Reaction mechanism; Stereochemistry; Medicinal chemistry; Analytical Chemistry (journal); Catalysis; Organic chemistry; Physics; Meteorology","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002818564,0.0008727529,0.0009440491,0.0006595671,0.001188983,0.0005909033,0.001467855,0.001305209,0.006400948],"category_scores_gemma":[0.0004511482,0.0003514535,0.001244213,0.0004623219,0.0009964928,0.0009848094,0.0007360893,0.0007796476,0.0004708006],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006466484,"about_ca_system_score_gemma":0.0009755967,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003820242,"about_ca_topic_score_gemma":0.002393883,"domain_scores_codex":[0.9998123,0.00003026007,0.000005342997,0.0000233304,0.00005512779,0.00007364078],"domain_scores_gemma":[0.9997984,0.0000923934,0.00002935336,0.00002068654,0.00003964241,0.00001958838],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0003581709,0.000356443,0.00417141,0.001773128,0.0001596065,0.002463583,0.0004772337,0.7637691,0.04274136,0.1673503,0.001909613,0.01446998],"study_design_scores_gemma":[0.00005173565,0.0001534401,0.001791184,0.00003001517,0.0000457448,0.0001760968,0.0002538226,0.9800808,0.003512064,0.0123687,0.001507095,0.00002937941],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.861707,0.004282852,0.06274574,0.0009861247,0.0002711115,0.0001569893,0.0007291035,0.0001811298,0.06894013],"genre_scores_gemma":[0.9865029,0.001803596,0.00647912,0.000146601,0.00005143155,0.0001566126,0.0003686534,0.00005934172,0.004431811],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006400948,"threshold_uncertainty_score":0.02141327,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01274977543352537,"score_gpt":0.2231539354029384,"score_spread":0.2104041599694131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}