{"id":"W1683732189","doi":"10.1039/c5nj01906k","title":"Ionic liquids as solvents for the Knoevenagel condensation: understanding the role of solvent–solute interactions","year":2015,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Kensington Health","funders":"European Social Fund","keywords":"Chemistry; Knoevenagel condensation; Ionic liquid; Solvation; Solvent; Hydrogen bond; Solvatochromism; Computational chemistry; Condensation; Solvent effects; Ionic bonding; Organic chemistry; Physical chemistry; Thermodynamics; Catalysis; Ion; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002539939,0.0000904492,0.0001355103,0.0000128004,0.0001167199,0.00002824278,0.0003413618,0.0000535902,0.0001131377],"category_scores_gemma":[0.0001681955,0.00005336001,0.0001690962,0.00008371515,0.00005624049,0.00009940928,0.00005032078,0.0002624264,0.000004135631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001882109,"about_ca_system_score_gemma":0.0002523085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001307799,"about_ca_topic_score_gemma":9.435521e-7,"domain_scores_codex":[0.9991735,0.000007381394,0.0003819022,0.00007227959,0.0002224352,0.0001425311],"domain_scores_gemma":[0.9990317,0.0001995374,0.0002838729,0.0001999826,0.0001840897,0.0001007796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002837218,0.0001121241,0.0000217766,0.00006668351,0.000426694,0.000001201163,0.001961965,0.01087204,0.9641546,0.009446207,0.0113213,0.001331709],"study_design_scores_gemma":[0.001480676,0.00008883981,0.000003804789,0.0002100701,0.0002140782,0.0001870651,0.009008421,0.01871171,0.8773057,0.02306374,0.06956895,0.0001569348],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.4229608,0.01119371,0.4935106,0.0311811,0.001849899,0.0009926617,0.00004010777,0.0001057033,0.0381654],"genre_scores_gemma":[0.9962794,0.00003707653,0.0002937075,0.00005951938,0.0006241096,0.000009931782,0.000002284491,0.00001515242,0.002678849],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5733185,"threshold_uncertainty_score":0.2175958,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04969888023311026,"score_gpt":0.2820671677924034,"score_spread":0.2323682875592932,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}