{"id":"W1696264436","doi":"10.1002/chin.200246034","title":"Baeyer—Villiger Oxidations Catalyzed by Engineered Microorganisms: Enantioselective Synthesis of δ‐Valerolactones with Functionalized Chains.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Enzyme Catalysis and Immobilization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Chemistry; Enantioselective synthesis; Catalysis; Microorganism; Combinatorial chemistry; Organic chemistry; Chain (unit); Stereochemistry; Bacteria","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000680662,0.0001626999,0.0001850347,0.0000515123,0.00006042518,0.00001354471,0.0001183027,0.0001212836,0.0004360891],"category_scores_gemma":[0.0001206413,0.0001365144,0.00007981201,0.0002162452,0.00007360588,0.00001527366,0.00002736706,0.00004568206,0.00001382277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002258398,"about_ca_system_score_gemma":0.00002729833,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008518757,"about_ca_topic_score_gemma":0.000005841563,"domain_scores_codex":[0.9992441,0.000001599903,0.0002358328,0.0002220417,0.0001294778,0.0001669723],"domain_scores_gemma":[0.9993045,0.00002276469,0.0001366893,0.0002779,0.0002033377,0.0000548119],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004076073,0.00008947463,0.00008240615,0.00003105565,0.0001395314,1.386635e-7,0.0001011984,0.00000616835,0.9882923,0.00002310294,0.00835148,0.002842416],"study_design_scores_gemma":[0.000418272,0.00006098535,0.0001579804,0.00001563338,0.000058257,0.00000681678,0.0001136771,0.00004075886,0.9801157,0.00000134446,0.01883446,0.0001761242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9281502,0.003169897,0.003303571,0.0002195707,0.0001206213,0.0006668063,0.0003357711,0.00007648041,0.06395703],"genre_scores_gemma":[0.9909438,0.0003270958,0.0001499603,0.00005695994,0.00004636524,0.00006004076,0.0009540832,0.00002545613,0.007436163],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06279362,"threshold_uncertainty_score":0.5566895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005822438436302611,"score_gpt":0.1883340925469844,"score_spread":0.1825116541106818,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}