{"id":"W1699197475","doi":"10.1139/cjc-2013-0586","title":"Significant effect of charge microenvironment on the redox potential of [Fe<sub>4</sub>Se<sub>4</sub>(SPh)<sub>4</sub>]<sup>2−</sup> in solution and inside film","year":2014,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Department of Science and Technology, Ministry of Science and Technology, India","keywords":"Redox; Chemistry; Pulmonary surfactant; Charge (physics); Electrode; Inorganic chemistry; Physical chemistry; Physics; Quantum mechanics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001435949,0.0003043401,0.0001610466,0.00009105958,0.0001755696,0.0003097503,0.0002500811,0.0002904925,0.001762456],"category_scores_gemma":[0.0004031447,0.0001628283,0.0000981475,0.00009317604,0.0003985247,0.0004293603,0.0002180337,0.0003961261,0.0001540196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001354944,"about_ca_system_score_gemma":0.0001136046,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003166627,"about_ca_topic_score_gemma":0.0007472938,"domain_scores_codex":[0.9999075,0.00001778774,0.000006411798,0.00002208313,0.00002952134,0.0000165784],"domain_scores_gemma":[0.9998139,0.00008968581,0.00002857824,0.00001156668,0.00003447719,0.00002185918],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009932483,0.000006904445,0.0003409692,0.00003831052,0.000005184785,0.00007162988,0.00005442256,0.0000423168,0.9980788,0.00006551629,0.00001524363,0.001181291],"study_design_scores_gemma":[0.000005675973,0.0001504762,0.002055084,0.000003621326,0.000011785,0.0001175248,0.00007623147,0.0002554091,0.9968855,0.00004337168,0.0003917494,0.000003549617],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975503,0.0005057865,0.0007454224,0.00007886019,0.0000148599,0.000005283254,0.00003725845,0.00001823113,0.001043981],"genre_scores_gemma":[0.9986143,0.000244638,0.0005812928,0.00002883006,0.000005184451,0.000003878981,0.00003326135,0.000005667362,0.0004829759],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001762456,"threshold_uncertainty_score":0.005895972,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004209967796749148,"score_gpt":0.1777458573795137,"score_spread":0.1735358895827646,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}