{"id":"W1718578311","doi":"10.1016/s0022-328x(00)00739-7","title":"Hypervalent tellurium compounds containing N→Te intramolecular interactions. Crystal and molecular structure of [2-(Me2NCH2)C6H4]2Te2, [2-(Me2NCH2)C6H4]TeS(S)PR2 (R=Me, Ph, OPri) and [2-(Me2NCH2)C6H4]Te–S–PPh2N–PPh2S","year":2001,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Hypervalent molecule; Tellurium; Crystallography; Intramolecular force; Crystal structure; Stereochemistry; Inorganic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001233701,0.0001998045,0.0002000657,0.0001259068,0.0002105046,0.0003950293,0.000449096,0.0003446632,0.001264096],"category_scores_gemma":[0.0002909384,0.0001632339,0.00006641342,0.0002311227,0.0002687984,0.0002825001,0.0002189923,0.0002646814,0.0001795249],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004010551,"about_ca_system_score_gemma":0.0002349973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00130489,"about_ca_topic_score_gemma":0.002380123,"domain_scores_codex":[0.9999036,0.0000197324,0.000006781896,0.00001621765,0.00003180947,0.00002186798],"domain_scores_gemma":[0.9998999,0.00002725447,0.00002510905,0.00001257412,0.00001263769,0.00002249857],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007586534,0.000073184,0.0006525958,0.0002309509,0.00004587794,0.0002331079,0.00007211538,0.001248608,0.9917135,0.001748739,0.0005975243,0.002625175],"study_design_scores_gemma":[0.0004229916,0.0009000491,0.004295633,0.00001780775,0.00005291434,0.0006520059,0.0001054714,0.00416828,0.9774556,0.0005026442,0.01140171,0.00002495492],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996686,0.0003994692,0.0002651813,0.00003947561,0.000008264963,0.00001214862,0.0001403888,0.00003099431,0.002418078],"genre_scores_gemma":[0.9962381,0.0003049939,0.0005825851,0.00002203498,0.000007778583,0.00001834905,0.0005659574,0.0000106286,0.002249621],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00130489,"threshold_uncertainty_score":0.00422883,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006643235528952742,"score_gpt":0.2083359354130778,"score_spread":0.2016926998841251,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}