{"id":"W1724459657","doi":"10.1063/1.4929588","title":"Probing <i>cis-trans</i> isomerization in the S1 state of C2H2 via H-atom action and hot band-pumped IR-UV double resonance spectroscopies","year":2015,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Academia Sinica; U.S. Department of Energy","keywords":"Isomerization; Chemistry; Resonance-enhanced multiphoton ionization; Resonance (particle physics); Excited state; Ground state; Spectral line; Atomic physics; Quenching (fluorescence); Acetylene; Atom (system on chip); Ionization; Photoionization; Fluorescence; Ion; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001575965,0.0002901705,0.00009030777,0.000237202,0.000254128,0.0002126336,0.0003261673,0.0002993457,0.001464311],"category_scores_gemma":[0.0001929357,0.0001290429,0.0001465605,0.0002112616,0.0004570971,0.0003334644,0.000251114,0.0004598491,0.000165935],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001878945,"about_ca_system_score_gemma":0.0001349109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005816319,"about_ca_topic_score_gemma":0.001182675,"domain_scores_codex":[0.9999073,0.000009649318,0.000002906438,0.00002531534,0.00003005305,0.00002482323],"domain_scores_gemma":[0.9998994,0.00002397809,0.00003423084,0.00001076529,0.00001445437,0.0000171776],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009843674,0.00001954993,0.00119912,0.00003368123,0.000006719287,0.00004523647,0.00008412133,0.0001992461,0.9937614,0.0005328626,0.00005326896,0.003966371],"study_design_scores_gemma":[0.000008007699,0.0001639948,0.004589031,0.000003036954,0.000006576829,0.00009635516,0.00008001726,0.001023029,0.9930978,0.000167899,0.0007555355,0.000008555777],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942818,0.0002758779,0.003589248,0.00005537981,0.000008860109,0.000007730143,0.0000827453,0.00003289472,0.001665439],"genre_scores_gemma":[0.9956727,0.000227865,0.003289585,0.00002619212,0.000006313486,0.00001387626,0.0001144853,0.00001149807,0.0006374881],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001464311,"threshold_uncertainty_score":0.004898608,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02175067212107692,"score_gpt":0.271549678516502,"score_spread":0.2497990063954251,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}