{"id":"W173010916","doi":"10.1016/s0167-2991(01)80331-1","title":"Site reactivity of Fischer-Tropsch synthesis catalysts studied by 12CO → 13CO isotope transients","year":2001,"lang":"en","type":"book-chapter","venue":"Studies in surface science and catalysis","topic":"Catalysts for Methane Reforming","field":"Chemical Engineering","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Fischer–Tropsch process; Catalysis; Chemistry; Selectivity; Syngas; Reactivity (psychology); Cobalt; Isotope; Methane; Dispersion (optics); Kinetic isotope effect; Inorganic chemistry; Organic chemistry; Deuterium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001798209,0.0002727482,0.0003325155,0.0003379464,0.000301895,0.0004878583,0.0006897351,0.0004452367,0.002075514],"category_scores_gemma":[0.0002836047,0.0002631545,0.0001932537,0.0004742943,0.0003102636,0.0003544021,0.0001780518,0.000612615,0.0003358247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007448483,"about_ca_system_score_gemma":0.0001615384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003186822,"about_ca_topic_score_gemma":0.00272405,"domain_scores_codex":[0.999874,0.000009628608,0.000003755029,0.00002436634,0.00005183958,0.00003634776],"domain_scores_gemma":[0.9999193,0.00004002753,0.000009197364,0.000009792925,0.00001604621,0.000005619127],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006105318,0.00006910885,0.0009205045,0.0001129833,0.00002491014,0.0001511415,0.0001629826,0.001397704,0.9865648,0.002047902,0.0005510786,0.007386499],"study_design_scores_gemma":[0.00001544753,0.000126711,0.002850871,0.00000578151,0.00001657421,0.000122841,0.00005687728,0.004079667,0.9898446,0.0003006012,0.002567996,0.0000120854],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865808,0.002574516,0.001487322,0.00008926742,0.00002439054,0.00001612219,0.0003161574,0.00007315232,0.008838412],"genre_scores_gemma":[0.9940737,0.0009801866,0.0004437886,0.0000169869,0.00000618025,0.000008559659,0.000374938,0.00004292142,0.00405276],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003186822,"threshold_uncertainty_score":0.006943345,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02751551066530304,"score_gpt":0.2800011142005794,"score_spread":0.2524856035352764,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}