{"id":"W174449483","doi":"10.1016/s0021-9673(01)00674-4","title":"Application of gas chromatography–tandem mass spectrometry to the analysis of inhibition of dimerisation of tributylphosphate under radiolysis","year":2001,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Moncton","funders":"","keywords":"Chemistry; Radiolysis; Isopropyl; Mass spectrometry; Deuterium; Solvent; Decomposition; Nuclear chemistry; Radiochemistry; Chromatography; Radical; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001064148,0.0009340958,0.0007095811,0.0007563146,0.0006664495,0.0005473121,0.000929021,0.001037804,0.0007872423],"category_scores_gemma":[0.001020063,0.0004869305,0.0004779163,0.000677984,0.0008579125,0.0003929027,0.0004038448,0.001887853,0.000660438],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007528458,"about_ca_system_score_gemma":0.001218846,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00245764,"about_ca_topic_score_gemma":0.003037899,"domain_scores_codex":[0.9992195,0.0001572161,0.00003106136,0.0001727787,0.0002996782,0.0001196952],"domain_scores_gemma":[0.999166,0.0003385812,0.0001198595,0.00008586234,0.0001800287,0.0001097358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007586221,0.00002179359,0.0000848245,0.00001561807,0.000009250956,0.0000209426,0.00001540215,0.00003622116,0.9985034,0.00006008594,0.00003463309,0.001121897],"study_design_scores_gemma":[0.000007679002,0.0000908371,0.0004947521,0.000002038128,0.000009185698,0.00008790055,0.000007596353,0.0008601153,0.9978361,0.00004271252,0.0005554267,0.000005684118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7311966,0.01190253,0.2467393,0.001041238,0.0004053646,0.0003574506,0.0009408261,0.001792417,0.005624145],"genre_scores_gemma":[0.9057474,0.005152151,0.08038191,0.0006721198,0.00008456416,0.0003317983,0.001607609,0.0002400766,0.005782404],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00245764,"threshold_uncertainty_score":0.005627811,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008161223138833476,"score_gpt":0.2472250593264578,"score_spread":0.2390638361876243,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}