{"id":"W174449483","doi":"10.1016/s0021-9673(01)00674-4","title":"Application of gas chromatography–tandem mass spectrometry to the analysis of inhibition of dimerisation of tributylphosphate under radiolysis","year":2001,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Moncton","funders":"","keywords":"Chemistry; Radiolysis; Isopropyl; Mass spectrometry; Deuterium; Solvent; Decomposition; Nuclear chemistry; Radiochemistry; Chromatography; Radical; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006970369,0.0002033163,0.0008765374,0.0009481867,0.00006213158,0.00001330419,0.0003036089,0.0001316947,0.0001888619],"category_scores_gemma":[0.00005099885,0.0001630129,0.0009976759,0.005089583,0.0001871293,0.0002104629,0.00002000153,0.0001912135,1.574505e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004560042,"about_ca_system_score_gemma":0.00006446395,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003452782,"about_ca_topic_score_gemma":0.000003688215,"domain_scores_codex":[0.9973592,0.00005469421,0.001474578,0.0001916643,0.0007250322,0.0001948067],"domain_scores_gemma":[0.9956096,0.0001865276,0.003199046,0.0003787489,0.0005358414,0.00009024376],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002229859,0.0002656847,0.1074653,0.0002773656,0.003206431,0.000001593119,0.0003125956,0.001451915,0.884904,0.00008114525,0.00004011583,0.001770844],"study_design_scores_gemma":[0.00074883,0.0001060204,0.03786419,0.0002378889,0.002176789,0.0000206315,0.0008554219,0.0004498195,0.956734,0.0005766893,0.00009518477,0.0001345446],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9597502,0.001711167,0.03767217,0.000110291,0.00002336964,0.00008563493,0.00005223528,0.000008349046,0.0005865242],"genre_scores_gemma":[0.9977884,0.0006055176,0.001467012,0.00001189978,0.00006985629,0.000006340055,0.0000325863,0.00001476446,0.00000361155],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07182998,"threshold_uncertainty_score":0.6647474,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008161223138833476,"score_gpt":0.2472250593264578,"score_spread":0.2390638361876243,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}