{"id":"W1747665470","doi":"10.1039/c5dt02364e","title":"Phosphane–ene chemistry: the reactivity of air-stable primary phosphines and their compatibility with the thiol–ene reaction","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Ontario Ministry of Research and Innovation","keywords":"Ene reaction; Chemistry; Thiol; Reactivity (psychology); Compatibility (geochemistry); Primary (astronomy); Organic chemistry; Chemical engineering; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003087573,0.0004324301,0.0002027291,0.0001544744,0.0001621721,0.000244487,0.0002433932,0.0003358817,0.002416474],"category_scores_gemma":[0.0004053902,0.0001693818,0.0001604639,0.0001696846,0.0002762121,0.0004596304,0.0002312629,0.0004497381,0.000444624],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001417298,"about_ca_system_score_gemma":0.0001735624,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003438659,"about_ca_topic_score_gemma":0.0007043211,"domain_scores_codex":[0.9997802,0.00003477279,0.00001616963,0.00006275825,0.00005228298,0.00005369022],"domain_scores_gemma":[0.9998083,0.00007597077,0.00003284019,0.00002516812,0.0000347066,0.00002304707],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008611398,0.000009354785,0.00006893351,0.00009030195,0.00000481911,0.00005469443,0.00003222487,0.00006878877,0.9977164,0.0001175021,0.00002415837,0.001726629],"study_design_scores_gemma":[0.000001702752,0.00007263196,0.0002279046,0.0000011555,0.000002498161,0.00004454152,0.000007546456,0.00008639295,0.9989746,0.00001223556,0.000567233,0.000001695879],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9858867,0.001444074,0.006967703,0.00006194931,0.00003514784,0.00006453878,0.0002526508,0.0001294046,0.005157901],"genre_scores_gemma":[0.9904625,0.0008151109,0.004262648,0.00002384802,0.000006609221,0.00002887009,0.0002922524,0.00003201576,0.004076184],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002416474,"threshold_uncertainty_score":0.00808388,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01320268678834225,"score_gpt":0.2015295387506744,"score_spread":0.1883268519623322,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}